Double-phase liquid membrane extraction for the analysis of pesticides

A simple and solvent minimized sample preparation technique based on two-phase hollow fiber-protected liquid-phase microextraction was investigated for HPLC analysis of selected pesticides in water samples. Four pesticides (procymidon, methidation, quinalphos, and vinclozolin) were considered a...

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Main Authors: Sanagi, Mohd. Marsin, Zainal Abidin, Nurul Auni, See, Hong Heng, Wan Ibrahim, Wan Aini
Format: Article
Published: Malaysian Society of Analytical Sciences 2008
Subjects:
Online Access:http://eprints.utm.my/430/
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author Sanagi, Mohd. Marsin
Zainal Abidin, Nurul Auni
See, Hong Heng
Wan Ibrahim, Wan Aini
author_facet Sanagi, Mohd. Marsin
Zainal Abidin, Nurul Auni
See, Hong Heng
Wan Ibrahim, Wan Aini
author_sort Sanagi, Mohd. Marsin
building UTeM Institutional Repository
collection Online Access
description A simple and solvent minimized sample preparation technique based on two-phase hollow fiber-protected liquid-phase microextraction was investigated for HPLC analysis of selected pesticides in water samples. Four pesticides (procymidon, methidation, quinalphos, and vinclozolin) were considered as target analytes. Parameters such as extraction solvent, salt concentration, stirring speed, extraction time, and pH value were optimized using spiked deionised water samples. The analytes were extracted from 12 mL water samples through organic solvent (n-hexane and isooctane) immobilized in the pores of a porous polypropylene hollow fiber into 50 µL acceptor phase present inside the hollow fiber. Excellent separations of analytes were obtained on C18 column using acetonitrile-water ratio of 55:45 v/v at elevated flow rate of 0.8 mL/min.
first_indexed 2025-11-15T20:33:49Z
format Article
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institution Universiti Teknologi Malaysia
institution_category Local University
last_indexed 2025-11-15T20:33:49Z
publishDate 2008
publisher Malaysian Society of Analytical Sciences
recordtype eprints
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spelling utm-4302012-11-19T07:11:26Z http://eprints.utm.my/430/ Double-phase liquid membrane extraction for the analysis of pesticides Sanagi, Mohd. Marsin Zainal Abidin, Nurul Auni See, Hong Heng Wan Ibrahim, Wan Aini QD Chemistry A simple and solvent minimized sample preparation technique based on two-phase hollow fiber-protected liquid-phase microextraction was investigated for HPLC analysis of selected pesticides in water samples. Four pesticides (procymidon, methidation, quinalphos, and vinclozolin) were considered as target analytes. Parameters such as extraction solvent, salt concentration, stirring speed, extraction time, and pH value were optimized using spiked deionised water samples. The analytes were extracted from 12 mL water samples through organic solvent (n-hexane and isooctane) immobilized in the pores of a porous polypropylene hollow fiber into 50 µL acceptor phase present inside the hollow fiber. Excellent separations of analytes were obtained on C18 column using acetonitrile-water ratio of 55:45 v/v at elevated flow rate of 0.8 mL/min. Malaysian Society of Analytical Sciences 2008 Article PeerReviewed Sanagi, Mohd. Marsin and Zainal Abidin, Nurul Auni and See, Hong Heng and Wan Ibrahim, Wan Aini (2008) Double-phase liquid membrane extraction for the analysis of pesticides. The Malaysian Journal of Analytical Sciences, 9 (3). pp. 570-574. ISSN 1394-2506 http://www.ukm.my/mjas/v12_n3/Mohd%20Marsin%20Sanagi1.pdf
spellingShingle QD Chemistry
Sanagi, Mohd. Marsin
Zainal Abidin, Nurul Auni
See, Hong Heng
Wan Ibrahim, Wan Aini
Double-phase liquid membrane extraction for the analysis of pesticides
title Double-phase liquid membrane extraction for the analysis of pesticides
title_full Double-phase liquid membrane extraction for the analysis of pesticides
title_fullStr Double-phase liquid membrane extraction for the analysis of pesticides
title_full_unstemmed Double-phase liquid membrane extraction for the analysis of pesticides
title_short Double-phase liquid membrane extraction for the analysis of pesticides
title_sort double-phase liquid membrane extraction for the analysis of pesticides
topic QD Chemistry
url http://eprints.utm.my/430/
http://eprints.utm.my/430/