Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya

A RAM cathode is composed of electronic manganese dioxide (EMD), graphite and additives whilst anode material which is based on zinc gel. Manganese dioxide, is a semiconductor which has conductivity range of 10-6 to 10-3 –1cm-1. This conductivity of EMD is expecting to increase by dopping nickel...

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Main Author: Ab. Rashid, Raizul Azita
Format: Thesis
Language:English
Published: 2005
Subjects:
Online Access:http://eprints.utm.my/3991/
http://eprints.utm.my/3991/1/RaizulAzitaAbRashidMFS2005.pdf
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author Ab. Rashid, Raizul Azita
author_facet Ab. Rashid, Raizul Azita
author_sort Ab. Rashid, Raizul Azita
building UTeM Institutional Repository
collection Online Access
description A RAM cathode is composed of electronic manganese dioxide (EMD), graphite and additives whilst anode material which is based on zinc gel. Manganese dioxide, is a semiconductor which has conductivity range of 10-6 to 10-3 –1cm-1. This conductivity of EMD is expecting to increase by dopping nickel using the electroless nickel doping technique. This study is based on preparation of EMD-Ni with used materials SnCl2, PdCl2 and NiSO4 with different ratio. EMD-Ni 9 gave the highest result which used SnCl2 : PdCl2 : NiSO4 with ratio 1 : 0.68 : 1. Energy despersive analysis X-ray (EDAX) showed that EMD-Ni 9 gave the highest percentage i.e 29.53 %. Surface morphology study using scanning electron microscopy (SEM) showed that electroless nickel doping gave the homogenous doping of nickel onto EMD-Ni 9. Conductivity measure measurement using the Van der Pauw method showed that EMD-Ni 9 gave the conductivity i.e 6.748 X 10-4 -1 cm-1. The crystallinites of the EMD-Ni 9 sample consisit of phosporus monoclinic and nickel cube. The crystallinites of the EMD-Ni 9 cause gave the highest conductivity and it is better than EMD before electroless nickel doping i.e 4.703 X 10-4 -1 cm-1 . From the gas hidrogen adsorption analysis, sample EMD-Ni 9 showed a meso porosity characteristics with the isothermal adsorption showing a Type IV.
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spelling utm-39912018-01-15T00:43:51Z http://eprints.utm.my/3991/ Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya Ab. Rashid, Raizul Azita QD Chemistry A RAM cathode is composed of electronic manganese dioxide (EMD), graphite and additives whilst anode material which is based on zinc gel. Manganese dioxide, is a semiconductor which has conductivity range of 10-6 to 10-3 –1cm-1. This conductivity of EMD is expecting to increase by dopping nickel using the electroless nickel doping technique. This study is based on preparation of EMD-Ni with used materials SnCl2, PdCl2 and NiSO4 with different ratio. EMD-Ni 9 gave the highest result which used SnCl2 : PdCl2 : NiSO4 with ratio 1 : 0.68 : 1. Energy despersive analysis X-ray (EDAX) showed that EMD-Ni 9 gave the highest percentage i.e 29.53 %. Surface morphology study using scanning electron microscopy (SEM) showed that electroless nickel doping gave the homogenous doping of nickel onto EMD-Ni 9. Conductivity measure measurement using the Van der Pauw method showed that EMD-Ni 9 gave the conductivity i.e 6.748 X 10-4 -1 cm-1. The crystallinites of the EMD-Ni 9 sample consisit of phosporus monoclinic and nickel cube. The crystallinites of the EMD-Ni 9 cause gave the highest conductivity and it is better than EMD before electroless nickel doping i.e 4.703 X 10-4 -1 cm-1 . From the gas hidrogen adsorption analysis, sample EMD-Ni 9 showed a meso porosity characteristics with the isothermal adsorption showing a Type IV. 2005-09 Thesis NonPeerReviewed application/pdf en http://eprints.utm.my/3991/1/RaizulAzitaAbRashidMFS2005.pdf Ab. Rashid, Raizul Azita (2005) Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya. Masters thesis, Universiti Teknologi Malaysia, Faculty of Science.
spellingShingle QD Chemistry
Ab. Rashid, Raizul Azita
Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title_full Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title_fullStr Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title_full_unstemmed Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title_short Pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
title_sort pendopan tanpa elektrod mangan dioksida elektrolitik dengan nikel dan penciriannya
topic QD Chemistry
url http://eprints.utm.my/3991/
http://eprints.utm.my/3991/1/RaizulAzitaAbRashidMFS2005.pdf