Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process

As a result of industrialization, Environmental pollution is becoming more and more serious. Heavy metals are often present industrial wastewaters and need to be removed before discharge. Adsorption is a commonly used method for heavy metal removal from aqueous solutions. Despite of the good efficie...

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Main Authors: Salamatinia, Babak, Zinatizadeh, Ali Akbar, Razali, Noraini, Harun@Kamaruddin, Azlina, Abdullah, Ahmad Zuhairi
Format: Conference or Workshop Item
Language:English
Published: 2006
Subjects:
Online Access:http://eprints.utm.my/365/
http://eprints.utm.my/365/1/BabakSalamatinia2006_Chemicalpre-treatmentsofoilpalm.pdf
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author Salamatinia, Babak
Zinatizadeh, Ali Akbar
Razali, Noraini
Harun@Kamaruddin, Azlina
Abdullah, Ahmad Zuhairi
author_facet Salamatinia, Babak
Zinatizadeh, Ali Akbar
Razali, Noraini
Harun@Kamaruddin, Azlina
Abdullah, Ahmad Zuhairi
author_sort Salamatinia, Babak
building UTeM Institutional Repository
collection Online Access
description As a result of industrialization, Environmental pollution is becoming more and more serious. Heavy metals are often present industrial wastewaters and need to be removed before discharge. Adsorption is a commonly used method for heavy metal removal from aqueous solutions. Despite of the good efficiencies for heavy metal removal still the process can be improved by chemical or physical improvement of the sorbent material. The effects of different pre-treatments on oil palm frond (OPF) with the objectives of improving the sorption of Zn and Cu have been investigated. Acid, base, steam and reactive dye treatment were investigated for improvement in the sorption process. Base treatment resulted in the highest improvement in the heavy metals sorption capacity of the sorbent (64%). In this study the sorption process was fitted with the Langmuir and Freundlich isotherm lines which resulted in high fitting with R2= 0.99. The response surface methodology was employed in order to optimize the conditions of the base pre-treatment of OPF. It resulted in two quadratic models, one for Zn and one For Cu, demonstrating the less effect of time of treatment against the high effect of the base solution concentration. The conditions for the optimized process were soaking the sorbent in a 1.0 M solution of NaOH for 45 min under normal room temperature of 25 °C.
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language English
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spelling utm-3652017-08-24T01:27:29Z http://eprints.utm.my/365/ Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process Salamatinia, Babak Zinatizadeh, Ali Akbar Razali, Noraini Harun@Kamaruddin, Azlina Abdullah, Ahmad Zuhairi TP Chemical technology As a result of industrialization, Environmental pollution is becoming more and more serious. Heavy metals are often present industrial wastewaters and need to be removed before discharge. Adsorption is a commonly used method for heavy metal removal from aqueous solutions. Despite of the good efficiencies for heavy metal removal still the process can be improved by chemical or physical improvement of the sorbent material. The effects of different pre-treatments on oil palm frond (OPF) with the objectives of improving the sorption of Zn and Cu have been investigated. Acid, base, steam and reactive dye treatment were investigated for improvement in the sorption process. Base treatment resulted in the highest improvement in the heavy metals sorption capacity of the sorbent (64%). In this study the sorption process was fitted with the Langmuir and Freundlich isotherm lines which resulted in high fitting with R2= 0.99. The response surface methodology was employed in order to optimize the conditions of the base pre-treatment of OPF. It resulted in two quadratic models, one for Zn and one For Cu, demonstrating the less effect of time of treatment against the high effect of the base solution concentration. The conditions for the optimized process were soaking the sorbent in a 1.0 M solution of NaOH for 45 min under normal room temperature of 25 °C. 2006-07 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/365/1/BabakSalamatinia2006_Chemicalpre-treatmentsofoilpalm.pdf Salamatinia, Babak and Zinatizadeh, Ali Akbar and Razali, Noraini and Harun@Kamaruddin, Azlina and Abdullah, Ahmad Zuhairi (2006) Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process. In: 1st International Conference on Natural Resources Engineering & Technology 2006, 24-25th July 2006, Putrajaya, Malaysia.
spellingShingle TP Chemical technology
Salamatinia, Babak
Zinatizadeh, Ali Akbar
Razali, Noraini
Harun@Kamaruddin, Azlina
Abdullah, Ahmad Zuhairi
Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title_full Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title_fullStr Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title_full_unstemmed Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title_short Chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
title_sort chemical pre-treatments of oil palm frond for improvement in the removal of zn and cu from wastewater by sorption process
topic TP Chemical technology
url http://eprints.utm.my/365/
http://eprints.utm.my/365/1/BabakSalamatinia2006_Chemicalpre-treatmentsofoilpalm.pdf