Application of sol gel technique for glucose oxidase immobilization in biosensor application

A sol gel based biosensor using 3-glycidoxypropyl dimethylethoxysilane, as a silane agent was developed as a novel method for biosensor enzyme immobilization. The key materials applied were tetra methyl orthosilicate (TMOS), and the cross link agent, 3-Glycidoxypropyl dimethylethoxysilane, (GDP). Th...

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Main Authors: Mohd. Nasir, Nashrul Fazli, Ying, Yang, Che Ahmad, Azlan, Kadri, Nahrizul Adib
Format: Conference or Workshop Item
Language:English
Published: 2006
Subjects:
Online Access:http://eprints.utm.my/209/
http://eprints.utm.my/209/1/NashrulFazliMohdNasir2006_Applicationofsolgeltechnique.pdf
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author Mohd. Nasir, Nashrul Fazli
Ying, Yang
Che Ahmad, Azlan
Kadri, Nahrizul Adib
author_facet Mohd. Nasir, Nashrul Fazli
Ying, Yang
Che Ahmad, Azlan
Kadri, Nahrizul Adib
author_sort Mohd. Nasir, Nashrul Fazli
building UTeM Institutional Repository
collection Online Access
description A sol gel based biosensor using 3-glycidoxypropyl dimethylethoxysilane, as a silane agent was developed as a novel method for biosensor enzyme immobilization. The key materials applied were tetra methyl orthosilicate (TMOS), and the cross link agent, 3-Glycidoxypropyl dimethylethoxysilane, (GDP). Three compositions with different amount of GDP and glucose oxidase were experimented with the amount of TMOS was kept constant. The first coating consisted of 2mg of glucose oxidase and 20µl of GDP. The second trial involved higher GDP composition which is 100µl. The final trial applied higher content of glucose oxidase which is 12 mg with 20µl of GDP. The result showed that sensors with high composition of crosslink agent coating was capable to exhibit reliable glucose detection. The crosslink agent insufficiency in the first composition failed to provide good attachment for the enzyme on the electrode. Thus, the test was halted after few readings due to the inability of the sensor to detect glucose increment. For the high amount glucose oxidase composition, failure happened due to the deficiency of GDP to retain the enzyme thus contributed to the glucose oxidase leaching. We conclude that adequate amount of crosslink agent is vital for a sol gel based biosensor to function successfully.
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format Conference or Workshop Item
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institution Universiti Teknologi Malaysia
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language English
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spelling utm-2092017-08-24T00:20:10Z http://eprints.utm.my/209/ Application of sol gel technique for glucose oxidase immobilization in biosensor application Mohd. Nasir, Nashrul Fazli Ying, Yang Che Ahmad, Azlan Kadri, Nahrizul Adib TP Chemical technology A sol gel based biosensor using 3-glycidoxypropyl dimethylethoxysilane, as a silane agent was developed as a novel method for biosensor enzyme immobilization. The key materials applied were tetra methyl orthosilicate (TMOS), and the cross link agent, 3-Glycidoxypropyl dimethylethoxysilane, (GDP). Three compositions with different amount of GDP and glucose oxidase were experimented with the amount of TMOS was kept constant. The first coating consisted of 2mg of glucose oxidase and 20µl of GDP. The second trial involved higher GDP composition which is 100µl. The final trial applied higher content of glucose oxidase which is 12 mg with 20µl of GDP. The result showed that sensors with high composition of crosslink agent coating was capable to exhibit reliable glucose detection. The crosslink agent insufficiency in the first composition failed to provide good attachment for the enzyme on the electrode. Thus, the test was halted after few readings due to the inability of the sensor to detect glucose increment. For the high amount glucose oxidase composition, failure happened due to the deficiency of GDP to retain the enzyme thus contributed to the glucose oxidase leaching. We conclude that adequate amount of crosslink agent is vital for a sol gel based biosensor to function successfully. 2006-07 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/209/1/NashrulFazliMohdNasir2006_Applicationofsolgeltechnique.pdf Mohd. Nasir, Nashrul Fazli and Ying, Yang and Che Ahmad, Azlan and Kadri, Nahrizul Adib (2006) Application of sol gel technique for glucose oxidase immobilization in biosensor application. In: 1st International Conference on Natural Resources Engineering & Technology 2006, 24-25th July 2006, Putrajaya, Malaysia.
spellingShingle TP Chemical technology
Mohd. Nasir, Nashrul Fazli
Ying, Yang
Che Ahmad, Azlan
Kadri, Nahrizul Adib
Application of sol gel technique for glucose oxidase immobilization in biosensor application
title Application of sol gel technique for glucose oxidase immobilization in biosensor application
title_full Application of sol gel technique for glucose oxidase immobilization in biosensor application
title_fullStr Application of sol gel technique for glucose oxidase immobilization in biosensor application
title_full_unstemmed Application of sol gel technique for glucose oxidase immobilization in biosensor application
title_short Application of sol gel technique for glucose oxidase immobilization in biosensor application
title_sort application of sol gel technique for glucose oxidase immobilization in biosensor application
topic TP Chemical technology
url http://eprints.utm.my/209/
http://eprints.utm.my/209/1/NashrulFazliMohdNasir2006_Applicationofsolgeltechnique.pdf