Gold nanoparticles embedded on the surface of polyvinyl alcohol layer

A novel method for synthesizing polyvinyl alcohol (PVA) embedded gold film is presented. Gold particles, in the size range of 20 to 180 nm, were first prepared by the conventional Turkevitch method by the reduction of gold, hydrogen tetrachloroaurate (HAuCl4) with sodium citrate in water. The result...

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Main Authors: Md. Nasir, Sasha, Nur, Hadi
Format: Article
Language:English
Published: Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia 2008
Subjects:
Online Access:http://eprints.utm.my/1615/
http://eprints.utm.my/1615/1/HadiNur2008_GoldNanoparticlesEmbeddedontheSurface.pdf
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author Md. Nasir, Sasha
Nur, Hadi
author_facet Md. Nasir, Sasha
Nur, Hadi
author_sort Md. Nasir, Sasha
building UTeM Institutional Repository
collection Online Access
description A novel method for synthesizing polyvinyl alcohol (PVA) embedded gold film is presented. Gold particles, in the size range of 20 to 180 nm, were first prepared by the conventional Turkevitch method by the reduction of gold, hydrogen tetrachloroaurate (HAuCl4) with sodium citrate in water. The resulting gold nanoparticles were characterized by ultra violet-visible (UV-Vis) absorption spectroscopy, dark-field microscopy, transmission electron microscopy (TEM) and field emission electron microscopy (FESEM). In the preparation of PVA embedded gold film, PVA was functionalized with (3-mercaptopropyl) trimethoxysilane (MPTMS) which produced a thiol functionality on the surface. Then, gold particles were embedded on the surface of partially dried functionalized PVA where the gold particles are chemisorbed onto the thiol groups. Their physical properties were studied using Fourier transform infra red spectroscopy (FTIR), FESEM, TEM and UV-Vis diffuse reflectance (UV-Vis DR). Considering that the gold nanoparticles in solution cannot possibly be recovered and reused, the PVA embedded gold film on the other hand, has potential to be reused multiple of times
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spelling utm-16152017-02-08T07:23:46Z http://eprints.utm.my/1615/ Gold nanoparticles embedded on the surface of polyvinyl alcohol layer Md. Nasir, Sasha Nur, Hadi Q Science (General) A novel method for synthesizing polyvinyl alcohol (PVA) embedded gold film is presented. Gold particles, in the size range of 20 to 180 nm, were first prepared by the conventional Turkevitch method by the reduction of gold, hydrogen tetrachloroaurate (HAuCl4) with sodium citrate in water. The resulting gold nanoparticles were characterized by ultra violet-visible (UV-Vis) absorption spectroscopy, dark-field microscopy, transmission electron microscopy (TEM) and field emission electron microscopy (FESEM). In the preparation of PVA embedded gold film, PVA was functionalized with (3-mercaptopropyl) trimethoxysilane (MPTMS) which produced a thiol functionality on the surface. Then, gold particles were embedded on the surface of partially dried functionalized PVA where the gold particles are chemisorbed onto the thiol groups. Their physical properties were studied using Fourier transform infra red spectroscopy (FTIR), FESEM, TEM and UV-Vis diffuse reflectance (UV-Vis DR). Considering that the gold nanoparticles in solution cannot possibly be recovered and reused, the PVA embedded gold film on the other hand, has potential to be reused multiple of times Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia 2008 Article PeerReviewed application/pdf en http://eprints.utm.my/1615/1/HadiNur2008_GoldNanoparticlesEmbeddedontheSurface.pdf Md. Nasir, Sasha and Nur, Hadi (2008) Gold nanoparticles embedded on the surface of polyvinyl alcohol layer. Journal of Fundamental Sciences, 4 (1). pp. 245-252. ISSN 1823-626X http://jfs.ibnusina.utm.my/index.php/jfs/article/view/33
spellingShingle Q Science (General)
Md. Nasir, Sasha
Nur, Hadi
Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title_full Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title_fullStr Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title_full_unstemmed Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title_short Gold nanoparticles embedded on the surface of polyvinyl alcohol layer
title_sort gold nanoparticles embedded on the surface of polyvinyl alcohol layer
topic Q Science (General)
url http://eprints.utm.my/1615/
http://eprints.utm.my/1615/
http://eprints.utm.my/1615/1/HadiNur2008_GoldNanoparticlesEmbeddedontheSurface.pdf