Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal

Water pollution is a major problem that impacts financial growth and socio-ecological sustainability of a country as well as health of the population. The presence of toxic heavy metals in wastewater such as chromium (Cr) (VI), copper, arsenic, lead, mercury, cadmium, etc. may lead to serious heal...

Full description

Bibliographic Details
Main Authors: Selimin, M. A., A. Latif, A. F., Lee, C. W., Muhamad, M. S., Basri, H., Lee, T. C.
Format: Conference or Workshop Item
Language:English
Published: 2022
Subjects:
Online Access:http://eprints.uthm.edu.my/7423/
http://eprints.uthm.edu.my/7423/1/P13908_2cf513c5eed79a02002f80348eda6263.pdf
_version_ 1848889097519628288
author Selimin, M. A.
A. Latif, A. F.
Lee, C. W.
Muhamad, M. S.
Basri, H.
Lee, T. C.
author_facet Selimin, M. A.
A. Latif, A. F.
Lee, C. W.
Muhamad, M. S.
Basri, H.
Lee, T. C.
author_sort Selimin, M. A.
building UTHM Institutional Repository
collection Online Access
description Water pollution is a major problem that impacts financial growth and socio-ecological sustainability of a country as well as health of the population. The presence of toxic heavy metals in wastewater such as chromium (Cr) (VI), copper, arsenic, lead, mercury, cadmium, etc. may lead to serious health issues. Therefore, this paper aims to synthesise natural hydroxyapatite (HAp) from black tilapia fish scales and investigate its efficiency as adsorbent for Cr (VI) removal. In this study, the black tilapia fish scales were soaked and washed thoroughly with distilled water to eliminate impurities such as dust and other particles, then dried in the oven before being alkaline treated for 1 h with a 50% NaOH at 100 �C. High purity HAp with an irregular rod-shape was successfully synthesised. The effectiveness of HAp from tila�pia fish to remove Cr (VI) was tested at various initial concentrations (30–70 mg/L) and HAp dosages ranging from 2 to 6 g. The results discovered that the synthesised adsorbent had a substantial impact on the removal effectiveness of the Cr (VI) for both manipulated parameters; initial concentration and Cr (VI) pH. The optimum result for Cr (VI) removal rate was achieved at 61.43% at 60 min by using 6 g of HAp. Freundlich isotherm model shows greater suitability with higher R2 = 0.995. Meanwhile, pseudo-second-order model is favourable for the adsorption process occurred in this study owing to its higher correlation coefficients. According to the findings of this study, black tilapia scale waste can be transformed into an effective adsorbent for Cr (VI) removal in wastewater treatment. This includes industries that may be exposed to Cr (VI), such as welding, coatings, plating, and textile production that use chromium-containing metals.
first_indexed 2025-11-15T20:20:46Z
format Conference or Workshop Item
id uthm-7423
institution Universiti Tun Hussein Onn Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T20:20:46Z
publishDate 2022
recordtype eprints
repository_type Digital Repository
spelling uthm-74232022-07-21T07:21:25Z http://eprints.uthm.edu.my/7423/ Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal Selimin, M. A. A. Latif, A. F. Lee, C. W. Muhamad, M. S. Basri, H. Lee, T. C. T Technology (General) Water pollution is a major problem that impacts financial growth and socio-ecological sustainability of a country as well as health of the population. The presence of toxic heavy metals in wastewater such as chromium (Cr) (VI), copper, arsenic, lead, mercury, cadmium, etc. may lead to serious health issues. Therefore, this paper aims to synthesise natural hydroxyapatite (HAp) from black tilapia fish scales and investigate its efficiency as adsorbent for Cr (VI) removal. In this study, the black tilapia fish scales were soaked and washed thoroughly with distilled water to eliminate impurities such as dust and other particles, then dried in the oven before being alkaline treated for 1 h with a 50% NaOH at 100 �C. High purity HAp with an irregular rod-shape was successfully synthesised. The effectiveness of HAp from tila�pia fish to remove Cr (VI) was tested at various initial concentrations (30–70 mg/L) and HAp dosages ranging from 2 to 6 g. The results discovered that the synthesised adsorbent had a substantial impact on the removal effectiveness of the Cr (VI) for both manipulated parameters; initial concentration and Cr (VI) pH. The optimum result for Cr (VI) removal rate was achieved at 61.43% at 60 min by using 6 g of HAp. Freundlich isotherm model shows greater suitability with higher R2 = 0.995. Meanwhile, pseudo-second-order model is favourable for the adsorption process occurred in this study owing to its higher correlation coefficients. According to the findings of this study, black tilapia scale waste can be transformed into an effective adsorbent for Cr (VI) removal in wastewater treatment. This includes industries that may be exposed to Cr (VI), such as welding, coatings, plating, and textile production that use chromium-containing metals. 2022 Conference or Workshop Item PeerReviewed text en http://eprints.uthm.edu.my/7423/1/P13908_2cf513c5eed79a02002f80348eda6263.pdf Selimin, M. A. and A. Latif, A. F. and Lee, C. W. and Muhamad, M. S. and Basri, H. and Lee, T. C. (2022) Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal. In: Materials Today: Proceedings. https://doi.org/10.1016/j.matpr.2021.10.008
spellingShingle T Technology (General)
Selimin, M. A.
A. Latif, A. F.
Lee, C. W.
Muhamad, M. S.
Basri, H.
Lee, T. C.
Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title_full Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title_fullStr Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title_full_unstemmed Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title_short Adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (VI) removal
title_sort adsorption efficiency of hydroxyapatite synthesised from black tilapia fish scales for chromium (vi) removal
topic T Technology (General)
url http://eprints.uthm.edu.my/7423/
http://eprints.uthm.edu.my/7423/
http://eprints.uthm.edu.my/7423/1/P13908_2cf513c5eed79a02002f80348eda6263.pdf