Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)

This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various te...

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Main Authors: Md Yasser, Mona Alis, Embong, Zaidi, Abd Rahim, Erween, Abdullah Sani, Amiril Sahab, Kamdani, Kamaruddin
Format: Article
Language:English
Published: Trans Tech Publications 2020
Subjects:
Online Access:http://eprints.uthm.edu.my/6108/
http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf
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author Md Yasser, Mona Alis
Embong, Zaidi
Abd Rahim, Erween
Abdullah Sani, Amiril Sahab
Kamdani, Kamaruddin
author_facet Md Yasser, Mona Alis
Embong, Zaidi
Abd Rahim, Erween
Abdullah Sani, Amiril Sahab
Kamdani, Kamaruddin
author_sort Md Yasser, Mona Alis
building UTHM Institutional Repository
collection Online Access
description This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various temperature of 200 ̊C, 300 ̊C and 400 ̊C heat treatment to determine the ability to exhibit corrosion and wear throughout the process. Fourier-Transform Infrared Spectroscopy (FTIR) analysis revealed prominent peaks of functional groups in these bio-lubricants; esters (C-O) and (C=O), alkanes (C-H), hydroxide (O-H), and nitrile groups deposited on the cutting tool surface. Initially, nitrile group is detected on cutting tool surface without lubricants at 2200 to 2300 absorption band reduced to lower intensity and most likely concealed by MJO+AIL10% compared to MJO+PIL1% where the nitrile group remains reflected in FTIR spectrum. In this work, it is proved that MJO+AIL10% has higher viscosity as compared to MJO+PIL1%. in the context of functional groups and supported the previous study on MJO+AIL10% as corrosion inhibitor.
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institution Universiti Tun Hussein Onn Malaysia
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spelling uthm-61082022-01-26T07:42:08Z http://eprints.uthm.edu.my/6108/ Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR) Md Yasser, Mona Alis Embong, Zaidi Abd Rahim, Erween Abdullah Sani, Amiril Sahab Kamdani, Kamaruddin TJ Mechanical engineering and machinery This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various temperature of 200 ̊C, 300 ̊C and 400 ̊C heat treatment to determine the ability to exhibit corrosion and wear throughout the process. Fourier-Transform Infrared Spectroscopy (FTIR) analysis revealed prominent peaks of functional groups in these bio-lubricants; esters (C-O) and (C=O), alkanes (C-H), hydroxide (O-H), and nitrile groups deposited on the cutting tool surface. Initially, nitrile group is detected on cutting tool surface without lubricants at 2200 to 2300 absorption band reduced to lower intensity and most likely concealed by MJO+AIL10% compared to MJO+PIL1% where the nitrile group remains reflected in FTIR spectrum. In this work, it is proved that MJO+AIL10% has higher viscosity as compared to MJO+PIL1%. in the context of functional groups and supported the previous study on MJO+AIL10% as corrosion inhibitor. Trans Tech Publications 2020 Article PeerReviewed text en http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf Md Yasser, Mona Alis and Embong, Zaidi and Abd Rahim, Erween and Abdullah Sani, Amiril Sahab and Kamdani, Kamaruddin (2020) Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR). Materials Science Forum, 981. pp. 98-103. ISSN 0255-5476 https://dx.doi.org/ 10.4028/www.scientific.net/MSF.981.98
spellingShingle TJ Mechanical engineering and machinery
Md Yasser, Mona Alis
Embong, Zaidi
Abd Rahim, Erween
Abdullah Sani, Amiril Sahab
Kamdani, Kamaruddin
Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_full Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_fullStr Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_full_unstemmed Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_short Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_sort study of ionic liquids (ail and pil) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (ftir)
topic TJ Mechanical engineering and machinery
url http://eprints.uthm.edu.my/6108/
http://eprints.uthm.edu.my/6108/
http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf