Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications

We demonstrate the structural reorganization of gold nanorods (GNRs) that could fine-tune localized surface plasmon resonance (LSPR) by using modified wet chemical synthesis on the solid substrate. Controlling the growth solution ageing time using the modifiable GNRs is an approach to overcome the l...

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Main Authors: Md Shah, Nur Zehan An’nisa, Morsin, Marlia, Sanudin, Rahmat, Razali, Nur Liyana, Nafisah, Suratun, Soon, Chin Fhong
Format: Article
Language:English
Published: Springer 2020
Subjects:
Online Access:http://eprints.uthm.edu.my/5259/
http://eprints.uthm.edu.my/5259/1/AJ%202020%20%28128%29.pdf
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author Md Shah, Nur Zehan An’nisa
Morsin, Marlia
Sanudin, Rahmat
Razali, Nur Liyana
Nafisah, Suratun
Soon, Chin Fhong
author_facet Md Shah, Nur Zehan An’nisa
Morsin, Marlia
Sanudin, Rahmat
Razali, Nur Liyana
Nafisah, Suratun
Soon, Chin Fhong
author_sort Md Shah, Nur Zehan An’nisa
building UTHM Institutional Repository
collection Online Access
description We demonstrate the structural reorganization of gold nanorods (GNRs) that could fine-tune localized surface plasmon resonance (LSPR) by using modified wet chemical synthesis on the solid substrate. Controlling the growth solution ageing time using the modifiable GNRs is an approach to overcome the limitations of rods formation due to inhomogeneous and uncontrollable size and aspect ratio. In this study, the suitable ageing time of GNRs was determined to produce optimum GNRs in terms of surface density and aspect ratio. As the ageing time was increased from 30 min to 24 h, the colour of the growth solution was changed from light to dark purple. The change is associated with the density of the nanorods formation. The optical spectral peaks of GNRs occur in a range between 500 nm and 800 nm in the visible and near-infrared region spectrum for transverse surface resonance (t-SPR) and longitudinal surface resonance (l-SPR), respectively. From the morphological analysis, it was found that 20 h ageing time resulting in high density and homogeneous GNRs with 74.81% surface density with 4.23 ± 0.04 aspect ratio. Hence, the growth ageing time of GNRs can be manipulated to control their shape evolution and dimension in terms of size and aspect ratio. The controllable aspect ratio and size GNRs can be potentially used as sensing material in plasmonic applications.
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institution Universiti Tun Hussein Onn Malaysia
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spelling uthm-52592022-01-06T08:12:42Z http://eprints.uthm.edu.my/5259/ Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications Md Shah, Nur Zehan An’nisa Morsin, Marlia Sanudin, Rahmat Razali, Nur Liyana Nafisah, Suratun Soon, Chin Fhong QC Physics T Technology (General) TA401-492 Materials of engineering and construction. Mechanics of materials We demonstrate the structural reorganization of gold nanorods (GNRs) that could fine-tune localized surface plasmon resonance (LSPR) by using modified wet chemical synthesis on the solid substrate. Controlling the growth solution ageing time using the modifiable GNRs is an approach to overcome the limitations of rods formation due to inhomogeneous and uncontrollable size and aspect ratio. In this study, the suitable ageing time of GNRs was determined to produce optimum GNRs in terms of surface density and aspect ratio. As the ageing time was increased from 30 min to 24 h, the colour of the growth solution was changed from light to dark purple. The change is associated with the density of the nanorods formation. The optical spectral peaks of GNRs occur in a range between 500 nm and 800 nm in the visible and near-infrared region spectrum for transverse surface resonance (t-SPR) and longitudinal surface resonance (l-SPR), respectively. From the morphological analysis, it was found that 20 h ageing time resulting in high density and homogeneous GNRs with 74.81% surface density with 4.23 ± 0.04 aspect ratio. Hence, the growth ageing time of GNRs can be manipulated to control their shape evolution and dimension in terms of size and aspect ratio. The controllable aspect ratio and size GNRs can be potentially used as sensing material in plasmonic applications. Springer 2020 Article PeerReviewed text en http://eprints.uthm.edu.my/5259/1/AJ%202020%20%28128%29.pdf Md Shah, Nur Zehan An’nisa and Morsin, Marlia and Sanudin, Rahmat and Razali, Nur Liyana and Nafisah, Suratun and Soon, Chin Fhong (2020) Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications. Plasmonics, 15. pp. 923-932. ISSN 1557-1955 https://doi.org/10.1007/s11468-019-01098-2
spellingShingle QC Physics
T Technology (General)
TA401-492 Materials of engineering and construction. Mechanics of materials
Md Shah, Nur Zehan An’nisa
Morsin, Marlia
Sanudin, Rahmat
Razali, Nur Liyana
Nafisah, Suratun
Soon, Chin Fhong
Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title_full Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title_fullStr Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title_full_unstemmed Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title_short Effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
title_sort effects of growth solutions ageing time to the formation of gold nanorods via two-step approach for plasmonic applications
topic QC Physics
T Technology (General)
TA401-492 Materials of engineering and construction. Mechanics of materials
url http://eprints.uthm.edu.my/5259/
http://eprints.uthm.edu.my/5259/
http://eprints.uthm.edu.my/5259/1/AJ%202020%20%28128%29.pdf