Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites

K doping in the compound of Nd0.75Na0.25-xKxMn1O3 (x = 0, 0.05 and 0.10) manganites have been investigated to study its effect on crystalline phase and surface morphology as well as electrical transport and magnetic properties. The structure properties of the Nd0.75Na0.25- xKxMnO3 manganite have bee...

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Main Authors: Razali, Sufia Aqilah, Ibrahim, Norazilah, Shamsuddin, Suhadir, Noh, Mohamad Zaky
Format: Article
Published: Science Publishing Corporation 2018
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Online Access:http://eprints.uthm.edu.my/4324/
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author Razali, Sufia Aqilah
Ibrahim, Norazilah
Shamsuddin, Suhadir
Noh, Mohamad Zaky
author_facet Razali, Sufia Aqilah
Ibrahim, Norazilah
Shamsuddin, Suhadir
Noh, Mohamad Zaky
author_sort Razali, Sufia Aqilah
building UTHM Institutional Repository
collection Online Access
description K doping in the compound of Nd0.75Na0.25-xKxMn1O3 (x = 0, 0.05 and 0.10) manganites have been investigated to study its effect on crystalline phase and surface morphology as well as electrical transport and magnetic properties. The structure properties of the Nd0.75Na0.25- xKxMnO3 manganite have been characterized using X-ray diffraction measurement and it proved that the crystalline phase of samples were essentially single phased and indexed as orthorhombic structure with space group of Pnma. The morphological study from scanning electron microscope showed there was an improvement on the grains boundaries and sizes as well as the compactness with K doping suggestively due to the difference of ionic radius. On the other hand, DC electrical resistivity measurement showed all samples exhibit insulating behavior. However, analysis of dlnρ/dT-1 vs. T revealed the clearly peaks could be observed at temperature 210K for x = 0 and the peaks were shifted to the lower temperature around 190 K and 165 K for x = 0.05 and x = 0.1 respectively, indicate the existence of charge ordering (CO) state in the compound. Meanwhile, the investigation on magnetic behavior showed all samples exhibit transition from paramagnetic phase to anti-ferromagnetic phase with decreasing temperature and the TN was observed to shift to lower temperature suggestively due to weakening of CO state
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spelling uthm-43242021-12-02T03:31:44Z http://eprints.uthm.edu.my/4324/ Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites Razali, Sufia Aqilah Ibrahim, Norazilah Shamsuddin, Suhadir Noh, Mohamad Zaky TP250-261 Industrial electrochemistry K doping in the compound of Nd0.75Na0.25-xKxMn1O3 (x = 0, 0.05 and 0.10) manganites have been investigated to study its effect on crystalline phase and surface morphology as well as electrical transport and magnetic properties. The structure properties of the Nd0.75Na0.25- xKxMnO3 manganite have been characterized using X-ray diffraction measurement and it proved that the crystalline phase of samples were essentially single phased and indexed as orthorhombic structure with space group of Pnma. The morphological study from scanning electron microscope showed there was an improvement on the grains boundaries and sizes as well as the compactness with K doping suggestively due to the difference of ionic radius. On the other hand, DC electrical resistivity measurement showed all samples exhibit insulating behavior. However, analysis of dlnρ/dT-1 vs. T revealed the clearly peaks could be observed at temperature 210K for x = 0 and the peaks were shifted to the lower temperature around 190 K and 165 K for x = 0.05 and x = 0.1 respectively, indicate the existence of charge ordering (CO) state in the compound. Meanwhile, the investigation on magnetic behavior showed all samples exhibit transition from paramagnetic phase to anti-ferromagnetic phase with decreasing temperature and the TN was observed to shift to lower temperature suggestively due to weakening of CO state Science Publishing Corporation 2018 Article PeerReviewed Razali, Sufia Aqilah and Ibrahim, Norazilah and Shamsuddin, Suhadir and Noh, Mohamad Zaky (2018) Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites. International Journal of Engineering and Technology, 7 (4.3). pp. 85-88. ISSN 2227-524X
spellingShingle TP250-261 Industrial electrochemistry
Razali, Sufia Aqilah
Ibrahim, Norazilah
Shamsuddin, Suhadir
Noh, Mohamad Zaky
Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title_full Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title_fullStr Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title_full_unstemmed Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title_short Observation of charge ordering signal in monovalent doped Nd0.75Na0.25-xKxMn1O3 (0 ≤ x ≤ 0.10) manganites
title_sort observation of charge ordering signal in monovalent doped nd0.75na0.25-xkxmn1o3 (0 ≤ x ≤ 0.10) manganites
topic TP250-261 Industrial electrochemistry
url http://eprints.uthm.edu.my/4324/