Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud

In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, a...

Full description

Bibliographic Details
Main Authors: A. Jalil, Aishah, Triwahyono, Sugeng, Adam, S. Hazirah, Rahim, N. Diana, A. Aziz, M. Arif, Hairom, Nur Hanis Hayati, M. Razali, N. Aini, A.Z. Abidin, Mahani, A. Mohamadiah, M. Khairul
Format: Article
Language:English
Published: Elsevier 2010
Subjects:
Online Access:http://eprints.uthm.edu.my/3364/
http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf
_version_ 1848888000298090496
author A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
author_facet A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
author_sort A. Jalil, Aishah
building UTHM Institutional Repository
collection Online Access
description In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, and temperature. The adsorption kinetics and equilibrium isotherms of the LVM were studied using pseudofirst- order and -second-order kinetic equations, as well as the Freundlich and Langmuir models. The experimental data obtained withLVMfits best to the Langmuir isotherm model and exhibited amaximum adsorption capacity (qmax) of 333.3mgg−1; the data followed the second-order equation. The intraparticle diffusion studies revealed that the adsorption rates were not controlled only by the diffusion step. The thermodynamic parameters, such as the changes in enthalpy, entropy, and Gibbs free energy, showed that the adsorption is endothermic, random and spontaneous at high temperature. The results indicate that LVM adsorbsMOefficiently and could be utilized as a low-cost alternative adsorbent for the removal of anionic dyes in wastewater treatment.
first_indexed 2025-11-15T20:03:19Z
format Article
id uthm-3364
institution Universiti Tun Hussein Onn Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T20:03:19Z
publishDate 2010
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling uthm-33642021-11-17T01:06:37Z http://eprints.uthm.edu.my/3364/ Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud A. Jalil, Aishah Triwahyono, Sugeng Adam, S. Hazirah Rahim, N. Diana A. Aziz, M. Arif Hairom, Nur Hanis Hayati M. Razali, N. Aini A.Z. Abidin, Mahani A. Mohamadiah, M. Khairul TP155-156 Chemical engineering In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, and temperature. The adsorption kinetics and equilibrium isotherms of the LVM were studied using pseudofirst- order and -second-order kinetic equations, as well as the Freundlich and Langmuir models. The experimental data obtained withLVMfits best to the Langmuir isotherm model and exhibited amaximum adsorption capacity (qmax) of 333.3mgg−1; the data followed the second-order equation. The intraparticle diffusion studies revealed that the adsorption rates were not controlled only by the diffusion step. The thermodynamic parameters, such as the changes in enthalpy, entropy, and Gibbs free energy, showed that the adsorption is endothermic, random and spontaneous at high temperature. The results indicate that LVM adsorbsMOefficiently and could be utilized as a low-cost alternative adsorbent for the removal of anionic dyes in wastewater treatment. Elsevier 2010 Article PeerReviewed text en http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf A. Jalil, Aishah and Triwahyono, Sugeng and Adam, S. Hazirah and Rahim, N. Diana and A. Aziz, M. Arif and Hairom, Nur Hanis Hayati and M. Razali, N. Aini and A.Z. Abidin, Mahani and A. Mohamadiah, M. Khairul (2010) Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud. Journal of Hazardous Materials, 181 (1-3). pp. 755-762. ISSN 0304-3894 https://doi.org/10.1016/j.jhazmat.2010.05.078
spellingShingle TP155-156 Chemical engineering
A. Jalil, Aishah
Triwahyono, Sugeng
Adam, S. Hazirah
Rahim, N. Diana
A. Aziz, M. Arif
Hairom, Nur Hanis Hayati
M. Razali, N. Aini
A.Z. Abidin, Mahani
A. Mohamadiah, M. Khairul
Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_full Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_fullStr Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_full_unstemmed Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_short Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud
title_sort adsorption of methyl orange from aqueous solution onto calcined lapindo volcanic mud
topic TP155-156 Chemical engineering
url http://eprints.uthm.edu.my/3364/
http://eprints.uthm.edu.my/3364/
http://eprints.uthm.edu.my/3364/1/AJ%202019%20%28122%29.pdf