Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction

In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission...

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Main Authors: Rosman, Nurafiqah, Wan Salleh, Wan Norharyati, Ismail, Ahmad Fauzi, Jaafar, Juhana, Harun, Zawati, Aziz, Farhana, Mohamed, Mohamad Azuwa, Ohtani, Bunsho, Takashima, Mai
Format: Article
Language:English
Published: Elsevier 2018
Subjects:
Online Access:http://eprints.uthm.edu.my/3336/
http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf
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author Rosman, Nurafiqah
Wan Salleh, Wan Norharyati
Ismail, Ahmad Fauzi
Jaafar, Juhana
Harun, Zawati
Aziz, Farhana
Mohamed, Mohamad Azuwa
Ohtani, Bunsho
Takashima, Mai
author_facet Rosman, Nurafiqah
Wan Salleh, Wan Norharyati
Ismail, Ahmad Fauzi
Jaafar, Juhana
Harun, Zawati
Aziz, Farhana
Mohamed, Mohamad Azuwa
Ohtani, Bunsho
Takashima, Mai
author_sort Rosman, Nurafiqah
building UTHM Institutional Repository
collection Online Access
description In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission electron microscopy along with energy-dispersive X-ray (TEM-EDX), Fourier transform infrared (FTIR), UV-Vis-NIR spectrophotometer to reveal their phase, morphology, purity, and optical properties. The photocatalytic activity of the obtained nanocomposites was measured by the degradation of phenol under visible light irradiation. The results demonstrated that, the heterojunction mixed phase of Ag2CO3/Ag2O over ZnO surfaces has major effect on establishing the performance of the phenol photodegradation process. It can be noted that the Ag2O crystal’s growth over Ag2CO3 heterojunction on ZnO lattice, effectively facilitate charge transfer and suppress recombination of photogenerated electrons and holes, leading to highest impact phenol degradation. The synthesized photocatalyst displayed excellent properties, showing a potential industrial application for the treatment of phenolic wastewater.
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institution Universiti Tun Hussein Onn Malaysia
institution_category Local University
language English
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publishDate 2018
publisher Elsevier
recordtype eprints
repository_type Digital Repository
spelling uthm-33362021-11-16T07:38:47Z http://eprints.uthm.edu.my/3336/ Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction Rosman, Nurafiqah Wan Salleh, Wan Norharyati Ismail, Ahmad Fauzi Jaafar, Juhana Harun, Zawati Aziz, Farhana Mohamed, Mohamad Azuwa Ohtani, Bunsho Takashima, Mai TA401-492 Materials of engineering and construction. Mechanics of materials In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission electron microscopy along with energy-dispersive X-ray (TEM-EDX), Fourier transform infrared (FTIR), UV-Vis-NIR spectrophotometer to reveal their phase, morphology, purity, and optical properties. The photocatalytic activity of the obtained nanocomposites was measured by the degradation of phenol under visible light irradiation. The results demonstrated that, the heterojunction mixed phase of Ag2CO3/Ag2O over ZnO surfaces has major effect on establishing the performance of the phenol photodegradation process. It can be noted that the Ag2O crystal’s growth over Ag2CO3 heterojunction on ZnO lattice, effectively facilitate charge transfer and suppress recombination of photogenerated electrons and holes, leading to highest impact phenol degradation. The synthesized photocatalyst displayed excellent properties, showing a potential industrial application for the treatment of phenolic wastewater. Elsevier 2018 Article PeerReviewed text en http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf Rosman, Nurafiqah and Wan Salleh, Wan Norharyati and Ismail, Ahmad Fauzi and Jaafar, Juhana and Harun, Zawati and Aziz, Farhana and Mohamed, Mohamad Azuwa and Ohtani, Bunsho and Takashima, Mai (2018) Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction. Journal of Photochemistry and Photobiology A: Chemistry, 364 (18). pp. 602-612. ISSN 1010-6030 https://doi.org/10.1016/j.jphotochem.2018.06.029
spellingShingle TA401-492 Materials of engineering and construction. Mechanics of materials
Rosman, Nurafiqah
Wan Salleh, Wan Norharyati
Ismail, Ahmad Fauzi
Jaafar, Juhana
Harun, Zawati
Aziz, Farhana
Mohamed, Mohamad Azuwa
Ohtani, Bunsho
Takashima, Mai
Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title_full Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title_fullStr Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title_full_unstemmed Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title_short Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
title_sort photocatalytic degradation of phenol over visible light active zno/ag2co3/ag2o nanocomposites heterojunction
topic TA401-492 Materials of engineering and construction. Mechanics of materials
url http://eprints.uthm.edu.my/3336/
http://eprints.uthm.edu.my/3336/
http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf