Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor

A massive growth of vertically-aligned single-walled carbon nanotubes (VA-SWCNTs) from aluminum oxide (Al-O)-supported Co catalyst and high purity ethanol was performed using alcohol catalytic chemical vapor deposition (ACCVD) technique. SWCNTs with 50-μm thickness were grown on the substrates via t...

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Main Author: Mohd Abid, Mohd Asyadi Azam
Format: Article
Language:English
Published: École Polytechnique de Montréal, Canada 2011
Subjects:
Online Access:http://eprints.utem.edu.my/id/eprint/4608/
http://eprints.utem.edu.my/id/eprint/4608/1/Final-_JNMES_14_%282011%29_173-178.pdf
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author Mohd Abid, Mohd Asyadi Azam
author_facet Mohd Abid, Mohd Asyadi Azam
author_sort Mohd Abid, Mohd Asyadi Azam
building UTeM Institutional Repository
collection Online Access
description A massive growth of vertically-aligned single-walled carbon nanotubes (VA-SWCNTs) from aluminum oxide (Al-O)-supported Co catalyst and high purity ethanol was performed using alcohol catalytic chemical vapor deposition (ACCVD) technique. SWCNTs with 50-μm thickness were grown on the substrates via this technique. The Al metal layer of 20 nm thickness was thermally-oxidized for the production of Al-O, and 0.5 nm cobalt (Co) thin films was used as catalyst for the CVD process. The CNT growth was optimized using SiO2/Si substrates, and similar experimental condition was applied to the conducting substrates. The as-grown CNTs were characterized using Raman spectroscopy and electron microscopies for growth confirmation and for quality level investigation. Development of the catalyst nanoparticles and Al-O support layer was observed using atomic force microscopy (AFM) and transmission electron microscopy (TEM). The electrodes were fabricated using directly-grown VA-SWCNTs on SUS 310S, and were successfully used as an electrochemical capacitor. Electrochemical analysis using KOH aqueous electrolyte was performed by cyclic voltammetric (CV) and galvanostatic chargedischarge measurements; a maximum 52 Fg-1 specific gravimetric capacitance was obtained from the VA-SWCNT electrodes.
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spelling utem-46082022-01-06T15:20:12Z http://eprints.utem.edu.my/id/eprint/4608/ Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor Mohd Abid, Mohd Asyadi Azam Q Science (General) TP Chemical technology QD Chemistry A massive growth of vertically-aligned single-walled carbon nanotubes (VA-SWCNTs) from aluminum oxide (Al-O)-supported Co catalyst and high purity ethanol was performed using alcohol catalytic chemical vapor deposition (ACCVD) technique. SWCNTs with 50-μm thickness were grown on the substrates via this technique. The Al metal layer of 20 nm thickness was thermally-oxidized for the production of Al-O, and 0.5 nm cobalt (Co) thin films was used as catalyst for the CVD process. The CNT growth was optimized using SiO2/Si substrates, and similar experimental condition was applied to the conducting substrates. The as-grown CNTs were characterized using Raman spectroscopy and electron microscopies for growth confirmation and for quality level investigation. Development of the catalyst nanoparticles and Al-O support layer was observed using atomic force microscopy (AFM) and transmission electron microscopy (TEM). The electrodes were fabricated using directly-grown VA-SWCNTs on SUS 310S, and were successfully used as an electrochemical capacitor. Electrochemical analysis using KOH aqueous electrolyte was performed by cyclic voltammetric (CV) and galvanostatic chargedischarge measurements; a maximum 52 Fg-1 specific gravimetric capacitance was obtained from the VA-SWCNT electrodes. École Polytechnique de Montréal, Canada 2011-05-05 Article PeerReviewed application/pdf en http://eprints.utem.edu.my/id/eprint/4608/1/Final-_JNMES_14_%282011%29_173-178.pdf Mohd Abid, Mohd Asyadi Azam (2011) Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor. Journal of New Materials for Electrochemical Systems, 14 (3). pp. 173-178. ISSN 1480-2422 http://www.groupes.polymtl.ca/jnmes/
spellingShingle Q Science (General)
TP Chemical technology
QD Chemistry
Mohd Abid, Mohd Asyadi Azam
Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title_full Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title_fullStr Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title_full_unstemmed Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title_short Direct Growth of Vertically-Aligned Single-Walled Carbon Nanotubes on Conducting Substrates using Ethanol for Electrochemical Capacitor
title_sort direct growth of vertically-aligned single-walled carbon nanotubes on conducting substrates using ethanol for electrochemical capacitor
topic Q Science (General)
TP Chemical technology
QD Chemistry
url http://eprints.utem.edu.my/id/eprint/4608/
http://eprints.utem.edu.my/id/eprint/4608/
http://eprints.utem.edu.my/id/eprint/4608/1/Final-_JNMES_14_%282011%29_173-178.pdf