Optimisation of Kaolin bioleaching using surface, chemical and structural studies

Kaolin, a valuable clay mineral used in ceramics, whiteware manufacturing, and refractories, faces challenges due to iron impurities affecting its properties and colouration. Conventional methods for iron removal are not sustainable, necessitating eco-friendly alternatives like bioleaching with Ba...

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Main Author: Pang, Jun Hao
Format: Final Year Project / Dissertation / Thesis
Published: 2024
Subjects:
Online Access:http://eprints.utar.edu.my/6761/
http://eprints.utar.edu.my/6761/1/ME_2000910_FYP_report_%2D_JUN_HAO_PANG.pdf
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author Pang, Jun Hao
author_facet Pang, Jun Hao
author_sort Pang, Jun Hao
building UTAR Institutional Repository
collection Online Access
description Kaolin, a valuable clay mineral used in ceramics, whiteware manufacturing, and refractories, faces challenges due to iron impurities affecting its properties and colouration. Conventional methods for iron removal are not sustainable, necessitating eco-friendly alternatives like bioleaching with Bacillus Cereus. This study focuses on exploring how nutrients, particularly yeast and yeast with glucose solution, impact bioleaching efficiency within 10 days of the experiment. This study investigates the morphological, chemical, and structural alterations of kaolin during bioleaching using Bacillus cereus. By analyzing experimental outcomes, it was determined that a combination of yeast extract and glucose solution serves as the optimal nutrient source for enhancing bioleaching efficiency. Phenanthroline analysis revealed a significant increase in Fe (II) concentration from 1.06 µg/ml on day 0 to 3.78 µg/ml on day 10. Energy-dispersive X-ray spectroscopy (EDS) further demonstrated a bioleaching efficiency of 54.88% in batch 1 and 51.55% in batch 2, surpassing previous studies, likely attributable to the selected nutrient types. Surface analysis via scanning electron microscopy (SEM) indicated heightened crystallinity in the kaolin structure post-bioleaching. Remarkably, the chemical composition and bonds of kaolin remained unaltered, as confirmed by X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). This study successfully achieves its objectives and suggests further laboratory-scale optimization to facilitate scale-up. Future investigations will delve into optimizing nutrient types using various Bacillus species to maximize bioleaching efficiency, thereby contributing to the sustainable utilization of kaolin resources. While the nutrient source can be the catalyst to accelerate the progress, different bacteria will have their optimum condition. To further increase the efficiency, other bacteria types rather than Bacillus species can be investigated because the rate of metabolism rate for each bacteria is different, then the duration of bioleaching is also different.
first_indexed 2025-11-15T19:43:41Z
format Final Year Project / Dissertation / Thesis
id utar-6761
institution Universiti Tunku Abdul Rahman
institution_category Local University
last_indexed 2025-11-15T19:43:41Z
publishDate 2024
recordtype eprints
repository_type Digital Repository
spelling utar-67612024-08-23T07:30:14Z Optimisation of Kaolin bioleaching using surface, chemical and structural studies Pang, Jun Hao QD Chemistry T Technology (General) TJ Mechanical engineering and machinery Kaolin, a valuable clay mineral used in ceramics, whiteware manufacturing, and refractories, faces challenges due to iron impurities affecting its properties and colouration. Conventional methods for iron removal are not sustainable, necessitating eco-friendly alternatives like bioleaching with Bacillus Cereus. This study focuses on exploring how nutrients, particularly yeast and yeast with glucose solution, impact bioleaching efficiency within 10 days of the experiment. This study investigates the morphological, chemical, and structural alterations of kaolin during bioleaching using Bacillus cereus. By analyzing experimental outcomes, it was determined that a combination of yeast extract and glucose solution serves as the optimal nutrient source for enhancing bioleaching efficiency. Phenanthroline analysis revealed a significant increase in Fe (II) concentration from 1.06 µg/ml on day 0 to 3.78 µg/ml on day 10. Energy-dispersive X-ray spectroscopy (EDS) further demonstrated a bioleaching efficiency of 54.88% in batch 1 and 51.55% in batch 2, surpassing previous studies, likely attributable to the selected nutrient types. Surface analysis via scanning electron microscopy (SEM) indicated heightened crystallinity in the kaolin structure post-bioleaching. Remarkably, the chemical composition and bonds of kaolin remained unaltered, as confirmed by X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). This study successfully achieves its objectives and suggests further laboratory-scale optimization to facilitate scale-up. Future investigations will delve into optimizing nutrient types using various Bacillus species to maximize bioleaching efficiency, thereby contributing to the sustainable utilization of kaolin resources. While the nutrient source can be the catalyst to accelerate the progress, different bacteria will have their optimum condition. To further increase the efficiency, other bacteria types rather than Bacillus species can be investigated because the rate of metabolism rate for each bacteria is different, then the duration of bioleaching is also different. 2024 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/6761/1/ME_2000910_FYP_report_%2D_JUN_HAO_PANG.pdf Pang, Jun Hao (2024) Optimisation of Kaolin bioleaching using surface, chemical and structural studies. Final Year Project, UTAR. http://eprints.utar.edu.my/6761/
spellingShingle QD Chemistry
T Technology (General)
TJ Mechanical engineering and machinery
Pang, Jun Hao
Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title_full Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title_fullStr Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title_full_unstemmed Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title_short Optimisation of Kaolin bioleaching using surface, chemical and structural studies
title_sort optimisation of kaolin bioleaching using surface, chemical and structural studies
topic QD Chemistry
T Technology (General)
TJ Mechanical engineering and machinery
url http://eprints.utar.edu.my/6761/
http://eprints.utar.edu.my/6761/1/ME_2000910_FYP_report_%2D_JUN_HAO_PANG.pdf