Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications

Greywater contains dyes, pathogenic bacteria and microorganism, making its treatment essential for addressing potential future water crises. Heterogeneous photocatalysis with semiconductor material is proved highly efficient in removing organic contaminants which is well-suited in Malaysia as this c...

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Main Author: Goy, Chien Kai
Format: Final Year Project / Dissertation / Thesis
Published: 2024
Subjects:
Online Access:http://eprints.utar.edu.my/6752/
http://eprints.utar.edu.my/6752/1/Goy_Chien_Kai_1903586.pdf
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author Goy, Chien Kai
author_facet Goy, Chien Kai
author_sort Goy, Chien Kai
building UTAR Institutional Repository
collection Online Access
description Greywater contains dyes, pathogenic bacteria and microorganism, making its treatment essential for addressing potential future water crises. Heterogeneous photocatalysis with semiconductor material is proved highly efficient in removing organic contaminants which is well-suited in Malaysia as this country is located in a tropical latitude with consistent sunlight. In this study, a novel 7.5wt%- SnFe2O4/Bi2WO6/HAp ternary nanocomposite material was fabricated via solvothermal-deposition method. The morphological structure, energy bandgap, charge transfer properties, recombination of photoexcited electron-hole pairs, crystallinity, and crystal orientation of as-fabricated photocatalyst are determined via different analytical techniques. The result displayed that visible-light absorption range of composite materials has extended to longer wavelength that covered the visible light spectrum in addition to 7.5wt%-SnFe2O4/Bi2WO6/HAp with 1wt% HAp loading has the greatest visible light photosensitivity. The photocatalytic capabilities are assessed through decomposition of MG under sunlight illumination for 180 minutes. This ternary nanocomposite has demonstrated the highest photocatalytic activity where removal efficiency of 84.63% MG (kapp = 0.0088 min -1 ) and 99.59% MG (kapp = 0.0211 min-1 ) in greywater were achieved separately. The phytotoxicity studies revealed toxicity level of MG-containing greywater was greatly reduced after being treated with 7.5wt%-SnFe2O4/Bi2WO6/HAp-1wt%. The E. coli inactivation experiment showed that this photocatalyst has the highest anti-microorganism ability and largely restrained bacterial activity. This present work manifests multifunction of 7.5wt%-SnFe2O4/Bi2WO6/HAp-1wt% in photodecomposition of organic dyes and antibacterial application under sunlight irradiation.
first_indexed 2025-11-15T19:43:40Z
format Final Year Project / Dissertation / Thesis
id utar-6752
institution Universiti Tunku Abdul Rahman
institution_category Local University
last_indexed 2025-11-15T19:43:40Z
publishDate 2024
recordtype eprints
repository_type Digital Repository
spelling utar-67522024-10-22T02:24:10Z Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications Goy, Chien Kai TD Environmental technology. Sanitary engineering TP Chemical technology Greywater contains dyes, pathogenic bacteria and microorganism, making its treatment essential for addressing potential future water crises. Heterogeneous photocatalysis with semiconductor material is proved highly efficient in removing organic contaminants which is well-suited in Malaysia as this country is located in a tropical latitude with consistent sunlight. In this study, a novel 7.5wt%- SnFe2O4/Bi2WO6/HAp ternary nanocomposite material was fabricated via solvothermal-deposition method. The morphological structure, energy bandgap, charge transfer properties, recombination of photoexcited electron-hole pairs, crystallinity, and crystal orientation of as-fabricated photocatalyst are determined via different analytical techniques. The result displayed that visible-light absorption range of composite materials has extended to longer wavelength that covered the visible light spectrum in addition to 7.5wt%-SnFe2O4/Bi2WO6/HAp with 1wt% HAp loading has the greatest visible light photosensitivity. The photocatalytic capabilities are assessed through decomposition of MG under sunlight illumination for 180 minutes. This ternary nanocomposite has demonstrated the highest photocatalytic activity where removal efficiency of 84.63% MG (kapp = 0.0088 min -1 ) and 99.59% MG (kapp = 0.0211 min-1 ) in greywater were achieved separately. The phytotoxicity studies revealed toxicity level of MG-containing greywater was greatly reduced after being treated with 7.5wt%-SnFe2O4/Bi2WO6/HAp-1wt%. The E. coli inactivation experiment showed that this photocatalyst has the highest anti-microorganism ability and largely restrained bacterial activity. This present work manifests multifunction of 7.5wt%-SnFe2O4/Bi2WO6/HAp-1wt% in photodecomposition of organic dyes and antibacterial application under sunlight irradiation. 2024-01 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/6752/1/Goy_Chien_Kai_1903586.pdf Goy, Chien Kai (2024) Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications. Final Year Project, UTAR. http://eprints.utar.edu.my/6752/
spellingShingle TD Environmental technology. Sanitary engineering
TP Chemical technology
Goy, Chien Kai
Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title_full Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title_fullStr Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title_full_unstemmed Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title_short Bovine bone-based hydroxyapatite decorated with SnFe2O4/Bi2WO6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
title_sort bovine bone-based hydroxyapatite decorated with snfe2o4/bi2wo6 composite for photocatalytic malachite green containing greywater effluent treatment and antibacterial applications
topic TD Environmental technology. Sanitary engineering
TP Chemical technology
url http://eprints.utar.edu.my/6752/
http://eprints.utar.edu.my/6752/1/Goy_Chien_Kai_1903586.pdf