Optimisation of bioleaching of Malaysian and Chinese Kaolin

Kaolin has impurities such as iron which led to reduced quality, brightness and viability in industrial applications. Therefore, iron extraction was developed to increase the quality of kaolin. The bioleaching method could be an alternative to produce good quality kaolin as bacteria, being an organi...

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Main Author: Lee, Wei Sheong
Format: Final Year Project / Dissertation / Thesis
Published: 2023
Subjects:
Online Access:http://eprints.utar.edu.my/5903/
http://eprints.utar.edu.my/5903/1/ME_1804847_WEI_SHEONG_LEE.pdf
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author Lee, Wei Sheong
author_facet Lee, Wei Sheong
author_sort Lee, Wei Sheong
building UTAR Institutional Repository
collection Online Access
description Kaolin has impurities such as iron which led to reduced quality, brightness and viability in industrial applications. Therefore, iron extraction was developed to increase the quality of kaolin. The bioleaching method could be an alternative to produce good quality kaolin as bacteria, being an organic compound is environmental friendly. But before bioleaching can be implemented as an alternative, it needs to be optimised to a feasible efficiency of at least 80 %. Hence, optimisation of bioleaching of kaolin is necessary. It was found that the optimum nutrients condition for bioleaching kaolin with B. cereus is 8 g/L of glucose concentration while for B. megaterium and B. aryabhattai the optimum glucose concentration is 10 g/L. Iron reduction ability of Bacillus bacteria was measured and reduction of iron was clearly visible in phenanthroline analysis and ICP-OES analysis whereby the Fe(II) concentration increased during the period of 10 days of bioleaching. The EDX analysis revealed that a slightly higher bioleaching efficiency was achieved as compared to the previous studies. Malaysian kaolin treated with B. cereus, B. megaterium and B. aryabhattai was found to be 57.4 %, 60.3 % and 65.9 % respectively. Whereas for Chinese kaolin treated with B. cereus, B. megaterium and B. aryabhattai, the bioleaching efficiency was found to be 41.6 %, 54.7 % and 62.8 % respectively. Optimum glucose concentration used for the bioleaching experiment could be the contributing factor to the small increase in the bioleaching efficiency. Malaysian and Chinese kaolin experienced changes in terms of structure and surface morphology after bioleaching with Bacillus spp. bacteria based on the SEM analysis. The surface structure of both Malaysian and Chinese kaolin changed from amorphous to a more crystalline structure while the chemical composition and bonds of both Malaysian and Chinese kaolin remains unchanged after bioleaching as determined in the XRD and FTIR analysis. The results showed improvements in the bioleaching efficiency, contributing to the studies of implementing bioleaching in the industrial scale. With more laboratory scale experiments of optimisation, bioleaching will be able to replace chemical leaching with a lower cost and sustain and protect the environment.
first_indexed 2025-11-15T19:40:01Z
format Final Year Project / Dissertation / Thesis
id utar-5903
institution Universiti Tunku Abdul Rahman
institution_category Local University
last_indexed 2025-11-15T19:40:01Z
publishDate 2023
recordtype eprints
repository_type Digital Repository
spelling utar-59032023-10-05T16:54:21Z Optimisation of bioleaching of Malaysian and Chinese Kaolin Lee, Wei Sheong TJ Mechanical engineering and machinery Kaolin has impurities such as iron which led to reduced quality, brightness and viability in industrial applications. Therefore, iron extraction was developed to increase the quality of kaolin. The bioleaching method could be an alternative to produce good quality kaolin as bacteria, being an organic compound is environmental friendly. But before bioleaching can be implemented as an alternative, it needs to be optimised to a feasible efficiency of at least 80 %. Hence, optimisation of bioleaching of kaolin is necessary. It was found that the optimum nutrients condition for bioleaching kaolin with B. cereus is 8 g/L of glucose concentration while for B. megaterium and B. aryabhattai the optimum glucose concentration is 10 g/L. Iron reduction ability of Bacillus bacteria was measured and reduction of iron was clearly visible in phenanthroline analysis and ICP-OES analysis whereby the Fe(II) concentration increased during the period of 10 days of bioleaching. The EDX analysis revealed that a slightly higher bioleaching efficiency was achieved as compared to the previous studies. Malaysian kaolin treated with B. cereus, B. megaterium and B. aryabhattai was found to be 57.4 %, 60.3 % and 65.9 % respectively. Whereas for Chinese kaolin treated with B. cereus, B. megaterium and B. aryabhattai, the bioleaching efficiency was found to be 41.6 %, 54.7 % and 62.8 % respectively. Optimum glucose concentration used for the bioleaching experiment could be the contributing factor to the small increase in the bioleaching efficiency. Malaysian and Chinese kaolin experienced changes in terms of structure and surface morphology after bioleaching with Bacillus spp. bacteria based on the SEM analysis. The surface structure of both Malaysian and Chinese kaolin changed from amorphous to a more crystalline structure while the chemical composition and bonds of both Malaysian and Chinese kaolin remains unchanged after bioleaching as determined in the XRD and FTIR analysis. The results showed improvements in the bioleaching efficiency, contributing to the studies of implementing bioleaching in the industrial scale. With more laboratory scale experiments of optimisation, bioleaching will be able to replace chemical leaching with a lower cost and sustain and protect the environment. 2023 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/5903/1/ME_1804847_WEI_SHEONG_LEE.pdf Lee, Wei Sheong (2023) Optimisation of bioleaching of Malaysian and Chinese Kaolin. Final Year Project, UTAR. http://eprints.utar.edu.my/5903/
spellingShingle TJ Mechanical engineering and machinery
Lee, Wei Sheong
Optimisation of bioleaching of Malaysian and Chinese Kaolin
title Optimisation of bioleaching of Malaysian and Chinese Kaolin
title_full Optimisation of bioleaching of Malaysian and Chinese Kaolin
title_fullStr Optimisation of bioleaching of Malaysian and Chinese Kaolin
title_full_unstemmed Optimisation of bioleaching of Malaysian and Chinese Kaolin
title_short Optimisation of bioleaching of Malaysian and Chinese Kaolin
title_sort optimisation of bioleaching of malaysian and chinese kaolin
topic TJ Mechanical engineering and machinery
url http://eprints.utar.edu.my/5903/
http://eprints.utar.edu.my/5903/1/ME_1804847_WEI_SHEONG_LEE.pdf