Nanofrabication and characterization of silver nanoparticles

Owing to small size effect and large surface area, silver nanoparticle (AgNPs) exhibits special physical properties and is widely used in different applications. One of the significant applications is that AgNPs are coated on the surface of solar cell to increase the light harvesting efficiency of s...

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Main Author: Tay, Bing Yuan
Format: Final Year Project / Dissertation / Thesis
Published: 2019
Subjects:
Online Access:http://eprints.utar.edu.my/3957/
http://eprints.utar.edu.my/3957/1/CE%2D2019%2D15ADB03106.pdf
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author Tay, Bing Yuan
author_facet Tay, Bing Yuan
author_sort Tay, Bing Yuan
building UTAR Institutional Repository
collection Online Access
description Owing to small size effect and large surface area, silver nanoparticle (AgNPs) exhibits special physical properties and is widely used in different applications. One of the significant applications is that AgNPs are coated on the surface of solar cell to increase the light harvesting efficiency of solar cell due to its localized surface plasmon resonance (LSPR) effect. AgNPs could be synthesized through chemical reduction method using silver nitrate as metal precursor, sodium borohydride as reducing agent while 1-dodecanthiol as capping agent. In this study, the effects of the concentration of reducing agent, the concentration of capping agent and reaction temperature on the formation of AgNPs in term of size and shape had been studied and investigated. The synthesized AgNPs were characterized using UV/Vis spectroscopy, Fourier-transform infrared spectroscopy spectrophotometry (FTIR), and X-ray diffraction (XRD), while the surface morphology of AgNPs was studied using scanning electron microscopy (SEM), atomic force microscopy (AFM) and light microscope (LM). The smaller AgNPs with average size of 20-70 nm could be synthesized with an optimum concentration of NaBH4 of 0.36 M (R value = 18), the concentration of DDT of 0.052 M (S value = 0.5) and at 0 oC. The coupling agent, 3-(Trimethoxysilyl)-1-propanethiol (MPTMS) was used as the adhesion promoter to deposit the AgNPs on the surface of solar cell. By coating AgNPs on the surface of solar cell, the greatest improvement of light harvesting efficiency was 108.8 % with 0.136 W.
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format Final Year Project / Dissertation / Thesis
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institution Universiti Tunku Abdul Rahman
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publishDate 2019
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spelling utar-39572021-01-20T06:35:48Z Nanofrabication and characterization of silver nanoparticles Tay, Bing Yuan QD Chemistry Owing to small size effect and large surface area, silver nanoparticle (AgNPs) exhibits special physical properties and is widely used in different applications. One of the significant applications is that AgNPs are coated on the surface of solar cell to increase the light harvesting efficiency of solar cell due to its localized surface plasmon resonance (LSPR) effect. AgNPs could be synthesized through chemical reduction method using silver nitrate as metal precursor, sodium borohydride as reducing agent while 1-dodecanthiol as capping agent. In this study, the effects of the concentration of reducing agent, the concentration of capping agent and reaction temperature on the formation of AgNPs in term of size and shape had been studied and investigated. The synthesized AgNPs were characterized using UV/Vis spectroscopy, Fourier-transform infrared spectroscopy spectrophotometry (FTIR), and X-ray diffraction (XRD), while the surface morphology of AgNPs was studied using scanning electron microscopy (SEM), atomic force microscopy (AFM) and light microscope (LM). The smaller AgNPs with average size of 20-70 nm could be synthesized with an optimum concentration of NaBH4 of 0.36 M (R value = 18), the concentration of DDT of 0.052 M (S value = 0.5) and at 0 oC. The coupling agent, 3-(Trimethoxysilyl)-1-propanethiol (MPTMS) was used as the adhesion promoter to deposit the AgNPs on the surface of solar cell. By coating AgNPs on the surface of solar cell, the greatest improvement of light harvesting efficiency was 108.8 % with 0.136 W. 2019-05-08 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/3957/1/CE%2D2019%2D15ADB03106.pdf Tay, Bing Yuan (2019) Nanofrabication and characterization of silver nanoparticles. Final Year Project, UTAR. http://eprints.utar.edu.my/3957/
spellingShingle QD Chemistry
Tay, Bing Yuan
Nanofrabication and characterization of silver nanoparticles
title Nanofrabication and characterization of silver nanoparticles
title_full Nanofrabication and characterization of silver nanoparticles
title_fullStr Nanofrabication and characterization of silver nanoparticles
title_full_unstemmed Nanofrabication and characterization of silver nanoparticles
title_short Nanofrabication and characterization of silver nanoparticles
title_sort nanofrabication and characterization of silver nanoparticles
topic QD Chemistry
url http://eprints.utar.edu.my/3957/
http://eprints.utar.edu.my/3957/1/CE%2D2019%2D15ADB03106.pdf