Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique

Pens have been used as tools to make alterations on documents during the act of forgery. The emergence of hybrid pen inks which exhibits both characteristics of gel pen and ballpoint pen inks has imposed challenges to ink discrimination. Therefore, this study aims to compare the physical and chem...

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Main Author: Gannetion, Linthini
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2016
Subjects:
Online Access:http://eprints.usm.my/62621/
http://eprints.usm.my/62621/1/LINTHINI%20GANNETION%20-%20e.pdf
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author Gannetion, Linthini
author_facet Gannetion, Linthini
author_sort Gannetion, Linthini
building USM Institutional Repository
collection Online Access
description Pens have been used as tools to make alterations on documents during the act of forgery. The emergence of hybrid pen inks which exhibits both characteristics of gel pen and ballpoint pen inks has imposed challenges to ink discrimination. Therefore, this study aims to compare the physical and chemical characteristics of blue ballpoint pen inks and gel pen inks of similar hue through their ink profiles generated by four different techniques, namely microscopy, video spectral comparator (VSC), ATR-FTIR and thin layer chromatography (TLC). Ten blue ballpoint pens and ten blue gel pen inks were chosen randomly regardless of brands. Optical examination using stereomicroscope and VSC-6000, ATR-FTIR spectroscopy as well as thin layer chromatography using two different solvent systems were employed to analyse all ink samples. Results of ATR-FTIR and VSC microspectroscopy were statistically analysed using principal component analysis (PCA) and hierarchical cluster analysis (HCA) respectively to ease comparison and discrimination. The results show that the ink profiles of the pens which were created by combining the microscopical characteristics, fluorescent characteristics, FTIR spectra, ink solubility and combination of colourants used (dye or pigments) in gel pens and ballpoint pens vary despite the fact that all the pens visually appear to be of the same colour. This indicated that a combination of techniques provided better discrimination among the samples tested.
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institution Universiti Sains Malaysia
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language English
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spelling usm-626212025-09-07T07:51:43Z http://eprints.usm.my/62621/ Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique Gannetion, Linthini R Medicine (General) RA Public aspects of medicine Pens have been used as tools to make alterations on documents during the act of forgery. The emergence of hybrid pen inks which exhibits both characteristics of gel pen and ballpoint pen inks has imposed challenges to ink discrimination. Therefore, this study aims to compare the physical and chemical characteristics of blue ballpoint pen inks and gel pen inks of similar hue through their ink profiles generated by four different techniques, namely microscopy, video spectral comparator (VSC), ATR-FTIR and thin layer chromatography (TLC). Ten blue ballpoint pens and ten blue gel pen inks were chosen randomly regardless of brands. Optical examination using stereomicroscope and VSC-6000, ATR-FTIR spectroscopy as well as thin layer chromatography using two different solvent systems were employed to analyse all ink samples. Results of ATR-FTIR and VSC microspectroscopy were statistically analysed using principal component analysis (PCA) and hierarchical cluster analysis (HCA) respectively to ease comparison and discrimination. The results show that the ink profiles of the pens which were created by combining the microscopical characteristics, fluorescent characteristics, FTIR spectra, ink solubility and combination of colourants used (dye or pigments) in gel pens and ballpoint pens vary despite the fact that all the pens visually appear to be of the same colour. This indicated that a combination of techniques provided better discrimination among the samples tested. Universiti Sains Malaysia 2016 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/62621/1/LINTHINI%20GANNETION%20-%20e.pdf Gannetion, Linthini (2016) Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique. Project Report. Universiti Sains Malaysia. (Submitted)
spellingShingle R Medicine (General)
RA Public aspects of medicine
Gannetion, Linthini
Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title_full Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title_fullStr Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title_full_unstemmed Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title_short Comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
title_sort comparison between blue ballpoint pen and blue gel pen inks using stereomicroscopy, video spectral comparator, atr-ftir, thin layer chromatography and chemometrics technique
topic R Medicine (General)
RA Public aspects of medicine
url http://eprints.usm.my/62621/
http://eprints.usm.my/62621/1/LINTHINI%20GANNETION%20-%20e.pdf