Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System

TiO2 nanotube arrays (TNTs) and ZrO2 nanotube arrays (ZNTs) were NH4F at 60 V for 30 min. For the formation of nanotubes; oxidation and dissolution have been identified as two most important processes. The dissolution process occurs at the surface of the oxide, inside the pores and in between por...

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Main Author: Anwar, Dede Miftahul
Format: Thesis
Language:English
Published: 2014
Subjects:
Online Access:http://eprints.usm.my/62528/
http://eprints.usm.my/62528/1/24%20Pages%20from%2000001780805.pdf
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author Anwar, Dede Miftahul
author_facet Anwar, Dede Miftahul
author_sort Anwar, Dede Miftahul
building USM Institutional Repository
collection Online Access
description TiO2 nanotube arrays (TNTs) and ZrO2 nanotube arrays (ZNTs) were NH4F at 60 V for 30 min. For the formation of nanotubes; oxidation and dissolution have been identified as two most important processes. The dissolution process occurs at the surface of the oxide, inside the pores and in between pores. Comparing TNT and ZNT; it appears ZNTs are longer with smaller diameter and thinner wall compared to TNT. Even though the anodic layer on Zr has higher value of polarization resistance (~3.92 kQ) than TNTs (-7.82 kQ) the dissolution rate of Z1O2 is lower (0.11 mm/year) compared to TNTs (0.416 mm/year), making TNTs are shorter. The dissolution rate of oxide on Ti and Zr is also different resulting in different dimensions. Photocurrent and charge distribution measurement exhibited excellent ability of photogenerated free charge-carriers flow in TNTs but low for ZNTs. Therefore TNTs was need as a cathode to electrodeposit iron oxide. The formation of TNTs was further studied by the use of was suitable to be used as a template for the electrodeposition of iron oxide. For the electrodeposition lectrolyte consisting of 0.02 M FeCh bFhO + DI water was used. Parameters studied for this process included voltage, concentration of electrolyte and the effect of additives in the electrolyte.
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format Thesis
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institution Universiti Sains Malaysia
institution_category Local University
language English
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publishDate 2014
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spelling usm-625282025-06-19T07:04:05Z http://eprints.usm.my/62528/ Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System Anwar, Dede Miftahul TK1-9971 Electrical engineering. Electronics. Nuclear engineering TiO2 nanotube arrays (TNTs) and ZrO2 nanotube arrays (ZNTs) were NH4F at 60 V for 30 min. For the formation of nanotubes; oxidation and dissolution have been identified as two most important processes. The dissolution process occurs at the surface of the oxide, inside the pores and in between pores. Comparing TNT and ZNT; it appears ZNTs are longer with smaller diameter and thinner wall compared to TNT. Even though the anodic layer on Zr has higher value of polarization resistance (~3.92 kQ) than TNTs (-7.82 kQ) the dissolution rate of Z1O2 is lower (0.11 mm/year) compared to TNTs (0.416 mm/year), making TNTs are shorter. The dissolution rate of oxide on Ti and Zr is also different resulting in different dimensions. Photocurrent and charge distribution measurement exhibited excellent ability of photogenerated free charge-carriers flow in TNTs but low for ZNTs. Therefore TNTs was need as a cathode to electrodeposit iron oxide. The formation of TNTs was further studied by the use of was suitable to be used as a template for the electrodeposition of iron oxide. For the electrodeposition lectrolyte consisting of 0.02 M FeCh bFhO + DI water was used. Parameters studied for this process included voltage, concentration of electrolyte and the effect of additives in the electrolyte. 2014-06 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/62528/1/24%20Pages%20from%2000001780805.pdf Anwar, Dede Miftahul (2014) Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System. Masters thesis, Perpustakaan Hamzah Sendut.
spellingShingle TK1-9971 Electrical engineering. Electronics. Nuclear engineering
Anwar, Dede Miftahul
Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title_full Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title_fullStr Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title_full_unstemmed Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title_short Dispersion Of Iron Oxide Nanoparticles On Oxide Nanotube For Nanocatalyst System
title_sort dispersion of iron oxide nanoparticles on oxide nanotube for nanocatalyst system
topic TK1-9971 Electrical engineering. Electronics. Nuclear engineering
url http://eprints.usm.my/62528/
http://eprints.usm.my/62528/1/24%20Pages%20from%2000001780805.pdf