Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent

Diabetes mellitus is a chronic metabolic disorder that affects millions of people worldwide, leading to severe complications such as cardiovascular disease, obesity, and retinopathy. Despite advances in treatment, effective management of diabetes remains a significant challenge due to the limitation...

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Main Author: Phongphane, Lacksany
Format: Thesis
Language:English
Published: 2024
Subjects:
Online Access:http://eprints.usm.my/62064/
http://eprints.usm.my/62064/1/LACKSANY%20PHONGPHANE%20-%20TESIS24.pdf
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author Phongphane, Lacksany
author_facet Phongphane, Lacksany
author_sort Phongphane, Lacksany
building USM Institutional Repository
collection Online Access
description Diabetes mellitus is a chronic metabolic disorder that affects millions of people worldwide, leading to severe complications such as cardiovascular disease, obesity, and retinopathy. Despite advances in treatment, effective management of diabetes remains a significant challenge due to the limitations of current therapeutic options, including side effects and limited efficacy in controlling blood glucose levels. Hence, in our effort to develop anti-hyperglycemic agents that potentially inhibiting α-amylase and α-glucosidase enzymes, a series of new quinoxaline-isoxazole hybrids were successfully synthesised via five-step cyclisation. The new quinoxaline-isoxazole derivatives (84a-84v) were successful synthesised and obtained twenty-two compounds in a good yield within the range of 54% to 95%. Subsequently, these synthesised compounds were characterised and elucidated by several spectroscopies methods consisting of Fourier transform-infrared (FT-IR), and nuclear magnetic resonance (1D and 2D-NMR) including high-resolution mass spectrometry (HRMS). The synthesised compounds were further evaluated for the in vitro -amylase and -glucosidase inhibitory activities using acarbose as a positive control. Among 22 synthesised compounds, the results revealed that compound 84j showed dual inhibitory towards -amylase and -glucosidase with promising IC50 values of 17.0 and 40.1 μM, respectively. Moreover, compound 84c was also displayed the good dual activity for the inhibition of -amylase (IC50 = 24.0 μM) and -glucosidase (IC50 = 41.7 μM).
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spelling usm-620642025-03-26T01:51:57Z http://eprints.usm.my/62064/ Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent Phongphane, Lacksany QD1-65 General Including alchemy Diabetes mellitus is a chronic metabolic disorder that affects millions of people worldwide, leading to severe complications such as cardiovascular disease, obesity, and retinopathy. Despite advances in treatment, effective management of diabetes remains a significant challenge due to the limitations of current therapeutic options, including side effects and limited efficacy in controlling blood glucose levels. Hence, in our effort to develop anti-hyperglycemic agents that potentially inhibiting α-amylase and α-glucosidase enzymes, a series of new quinoxaline-isoxazole hybrids were successfully synthesised via five-step cyclisation. The new quinoxaline-isoxazole derivatives (84a-84v) were successful synthesised and obtained twenty-two compounds in a good yield within the range of 54% to 95%. Subsequently, these synthesised compounds were characterised and elucidated by several spectroscopies methods consisting of Fourier transform-infrared (FT-IR), and nuclear magnetic resonance (1D and 2D-NMR) including high-resolution mass spectrometry (HRMS). The synthesised compounds were further evaluated for the in vitro -amylase and -glucosidase inhibitory activities using acarbose as a positive control. Among 22 synthesised compounds, the results revealed that compound 84j showed dual inhibitory towards -amylase and -glucosidase with promising IC50 values of 17.0 and 40.1 μM, respectively. Moreover, compound 84c was also displayed the good dual activity for the inhibition of -amylase (IC50 = 24.0 μM) and -glucosidase (IC50 = 41.7 μM). 2024-09 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/62064/1/LACKSANY%20PHONGPHANE%20-%20TESIS24.pdf Phongphane, Lacksany (2024) Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent. PhD thesis, Universiti Sains Malaysia.
spellingShingle QD1-65 General Including alchemy
Phongphane, Lacksany
Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title_full Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title_fullStr Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title_full_unstemmed Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title_short Synthesis, Characterisation And Molecular Docking Of Quinoxaline-isoxazole Hybrids As Potential Anti-hyperglycemic Agent
title_sort synthesis, characterisation and molecular docking of quinoxaline-isoxazole hybrids as potential anti-hyperglycemic agent
topic QD1-65 General Including alchemy
url http://eprints.usm.my/62064/
http://eprints.usm.my/62064/1/LACKSANY%20PHONGPHANE%20-%20TESIS24.pdf