Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes

The aim of this research is to develop a novel bifunctional photocatalyst composed of nitrogen-doped titania (N-doped TiO2) and phosphorylated chitosan (PCS) nanocomposite for the removal of Acid Red 88 (AR 88) and Methylene Blue (MB) from aqueous solutions. Phosphorylation of chitosan was successfu...

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Main Author: Subramaniam, Sumaliny
Format: Thesis
Language:English
Published: 2024
Subjects:
Online Access:http://eprints.usm.my/62049/
http://eprints.usm.my/62049/1/SUMALINY%20AP%20SUBRAMANIAM%20-%20TESIS%20cut.pdf
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author Subramaniam, Sumaliny
author_facet Subramaniam, Sumaliny
author_sort Subramaniam, Sumaliny
building USM Institutional Repository
collection Online Access
description The aim of this research is to develop a novel bifunctional photocatalyst composed of nitrogen-doped titania (N-doped TiO2) and phosphorylated chitosan (PCS) nanocomposite for the removal of Acid Red 88 (AR 88) and Methylene Blue (MB) from aqueous solutions. Phosphorylation of chitosan was successfully modified through solvothermal treatment using phosphoric acid in a closed Teflon-lined stainless-steel autoclave. Subsequently, the obtained PCS was incorporated with N-doped TiO2 to synthesize the N-doped TiO2-phosphorylated chitosan (NTP) nanocomposite via solvothermal treatment. The synthesized photocatalyst was thoroughly characterized using various analytical techniques, including scanning electron microscopy with electron dispersive X-ray spectroscopy (SEM-EDX), Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (UV-Vis DRS), Brunauer-Emmett-Teller (BET) analysis, X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). Results indicated that the nanocomposite exhibited enhanced surface area and functional groups. The photocatalytic activity of NTP towards MB and AR 88 dyes were best described by the Langmuir-Hinshelwood kinetic model.
first_indexed 2025-11-15T19:13:39Z
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institution Universiti Sains Malaysia
institution_category Local University
language English
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publishDate 2024
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spelling usm-620492025-03-24T08:39:04Z http://eprints.usm.my/62049/ Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes Subramaniam, Sumaliny LC5800-5808 Distance education. The aim of this research is to develop a novel bifunctional photocatalyst composed of nitrogen-doped titania (N-doped TiO2) and phosphorylated chitosan (PCS) nanocomposite for the removal of Acid Red 88 (AR 88) and Methylene Blue (MB) from aqueous solutions. Phosphorylation of chitosan was successfully modified through solvothermal treatment using phosphoric acid in a closed Teflon-lined stainless-steel autoclave. Subsequently, the obtained PCS was incorporated with N-doped TiO2 to synthesize the N-doped TiO2-phosphorylated chitosan (NTP) nanocomposite via solvothermal treatment. The synthesized photocatalyst was thoroughly characterized using various analytical techniques, including scanning electron microscopy with electron dispersive X-ray spectroscopy (SEM-EDX), Fourier-transform infrared spectroscopy (FTIR), UV–Vis diffuse reflectance spectroscopy (UV-Vis DRS), Brunauer-Emmett-Teller (BET) analysis, X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). Results indicated that the nanocomposite exhibited enhanced surface area and functional groups. The photocatalytic activity of NTP towards MB and AR 88 dyes were best described by the Langmuir-Hinshelwood kinetic model. 2024-07 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/62049/1/SUMALINY%20AP%20SUBRAMANIAM%20-%20TESIS%20cut.pdf Subramaniam, Sumaliny (2024) Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes. Masters thesis, Universiti Sains Malaysia.
spellingShingle LC5800-5808 Distance education.
Subramaniam, Sumaliny
Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title_full Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title_fullStr Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title_full_unstemmed Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title_short Nitrogen Doped Titania-Phosphorylated Chitosan For The Photocatalytic Decontamination Of Synthetic Dyes
title_sort nitrogen doped titania-phosphorylated chitosan for the photocatalytic decontamination of synthetic dyes
topic LC5800-5808 Distance education.
url http://eprints.usm.my/62049/
http://eprints.usm.my/62049/1/SUMALINY%20AP%20SUBRAMANIAM%20-%20TESIS%20cut.pdf