Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets

Tannin extracted from mangrove bark, Rhizophora apiculata (R. apiculata) was used as a natural-origin source to be complexed with copper(U) salt. The copper-tannate (Cu-T) produced was used as an antifoulant in antifouling paint. Mangrove bark was extracted using 70% (v/v) aqueous acetone and giv...

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Main Author: Usol Ghafli, Nurul Azwin
Format: Thesis
Language:English
Published: 2014
Subjects:
Online Access:http://eprints.usm.my/61088/
http://eprints.usm.my/61088/1/24%20Pages%20from%2000001780519.pdf
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author Usol Ghafli, Nurul Azwin
author_facet Usol Ghafli, Nurul Azwin
author_sort Usol Ghafli, Nurul Azwin
building USM Institutional Repository
collection Online Access
description Tannin extracted from mangrove bark, Rhizophora apiculata (R. apiculata) was used as a natural-origin source to be complexed with copper(U) salt. The copper-tannate (Cu-T) produced was used as an antifoulant in antifouling paint. Mangrove bark was extracted using 70% (v/v) aqueous acetone and gives 31.1 % extraction yield. The total phenolic content (TPC) of mangrove tannin extract (MT) was 186.0 mg gallic acid equivalent per gram sample, total flavonoid content (TFC) was 96.0 mg catechin equivalent per gram sample and condensed tannin content (CTC) was 95.5% weight content. The optimum condition of copper-tannate complexes (Cu-T) was studied using precipitation curve on varies parameters which were copper dosage, reaction temperature, reaction time and pH of Cu-T solution. The optimum conditions were taking into account of Cu-T percentage yield and IR spectrum analysis. Three derivatives ofCu-T at different pH, which were Cu-T pH 3.5, Cu-T pH 5.0 and Cu-T pH 8.0, were chosen for further analysis. The concentration of copper element in CuT and commercialized antifoulant, Cu-Oma was measured using AAS analysis and shown that Cu-T complexes had lower amount of copper content which are almost 50% lower than Cu-Oma.
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language English
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spelling usm-610882024-09-11T02:08:27Z http://eprints.usm.my/61088/ Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets Usol Ghafli, Nurul Azwin TP1-1185 Chemical technology Tannin extracted from mangrove bark, Rhizophora apiculata (R. apiculata) was used as a natural-origin source to be complexed with copper(U) salt. The copper-tannate (Cu-T) produced was used as an antifoulant in antifouling paint. Mangrove bark was extracted using 70% (v/v) aqueous acetone and gives 31.1 % extraction yield. The total phenolic content (TPC) of mangrove tannin extract (MT) was 186.0 mg gallic acid equivalent per gram sample, total flavonoid content (TFC) was 96.0 mg catechin equivalent per gram sample and condensed tannin content (CTC) was 95.5% weight content. The optimum condition of copper-tannate complexes (Cu-T) was studied using precipitation curve on varies parameters which were copper dosage, reaction temperature, reaction time and pH of Cu-T solution. The optimum conditions were taking into account of Cu-T percentage yield and IR spectrum analysis. Three derivatives ofCu-T at different pH, which were Cu-T pH 3.5, Cu-T pH 5.0 and Cu-T pH 8.0, were chosen for further analysis. The concentration of copper element in CuT and commercialized antifoulant, Cu-Oma was measured using AAS analysis and shown that Cu-T complexes had lower amount of copper content which are almost 50% lower than Cu-Oma. 2014-05 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/61088/1/24%20Pages%20from%2000001780519.pdf Usol Ghafli, Nurul Azwin (2014) Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets. Masters thesis, Perpustakaan Hamzah Sendut.
spellingShingle TP1-1185 Chemical technology
Usol Ghafli, Nurul Azwin
Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title_full Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title_fullStr Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title_full_unstemmed Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title_short Copper-Tannate Complexes As Antifoulant In Antifouling Paint For Fish-Cage Nets
title_sort copper-tannate complexes as antifoulant in antifouling paint for fish-cage nets
topic TP1-1185 Chemical technology
url http://eprints.usm.my/61088/
http://eprints.usm.my/61088/1/24%20Pages%20from%2000001780519.pdf