Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques

One of the important areas in forensic questioned document is the ink analysis. It is performs not to identify the writing implement used to write the document under scrutiny but the ink deposited on the document. Through proper analysis, the ink deposited can be linked to the writing implement u...

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Main Author: Razali, Nor Fathin Mohd
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2015
Subjects:
Online Access:http://eprints.usm.my/60137/
http://eprints.usm.my/60137/1/NOR%20FATHIN%20BINTI%20MOHD%20RAZALI%20-%20e.pdf
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author Razali, Nor Fathin Mohd
author_facet Razali, Nor Fathin Mohd
author_sort Razali, Nor Fathin Mohd
building USM Institutional Repository
collection Online Access
description One of the important areas in forensic questioned document is the ink analysis. It is performs not to identify the writing implement used to write the document under scrutiny but the ink deposited on the document. Through proper analysis, the ink deposited can be linked to the writing implement used to write the document. In ink analysis, techniques such as Thin Layer Chromatography (TLC), Ultra Violet and Visible (UV-Vis) Spectroscopy and direct visual examination are considered as common. These techniques although have helped to solve crimes involving document, their outcomes are very subjective and depend on the knowledge, skill and most important experience of the examiner. This study purposes the use of chemometrics techniques of principle component analysis (PCA) and hierarchical cluster analysis (HCA) for ink analysis in conjunction with UV-Vis spectroscopy to produce more objective outcomes. In this study, twenty four (24) red ballpoint pen inks from four different brands were analysed using TLC and UVVis spectrometer. The thin layer chromatogram and the UV-Vis spectra obtained from the red ballpoint pen inks were manually examined for features that can be used to successfully differentiate and group the inks according to their brands. The manual examinations proved to be a time consuming and daunting task and more importantly were unable to differentiate the red ballpoint pen inks. On the other hand, PCA and HCA had successfully differentiated and grouped the red ballpoint pen inks according to their brands. The results demonstrated the potential use of PCA and HCA to differentiate and group red ballpoint pen inks of different brands in an objective manner.
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spelling usm-601372024-04-07T01:11:16Z http://eprints.usm.my/60137/ Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques Razali, Nor Fathin Mohd RA1001 Forensic Medicine. Medical jurisprudence. Legal medicine One of the important areas in forensic questioned document is the ink analysis. It is performs not to identify the writing implement used to write the document under scrutiny but the ink deposited on the document. Through proper analysis, the ink deposited can be linked to the writing implement used to write the document. In ink analysis, techniques such as Thin Layer Chromatography (TLC), Ultra Violet and Visible (UV-Vis) Spectroscopy and direct visual examination are considered as common. These techniques although have helped to solve crimes involving document, their outcomes are very subjective and depend on the knowledge, skill and most important experience of the examiner. This study purposes the use of chemometrics techniques of principle component analysis (PCA) and hierarchical cluster analysis (HCA) for ink analysis in conjunction with UV-Vis spectroscopy to produce more objective outcomes. In this study, twenty four (24) red ballpoint pen inks from four different brands were analysed using TLC and UVVis spectrometer. The thin layer chromatogram and the UV-Vis spectra obtained from the red ballpoint pen inks were manually examined for features that can be used to successfully differentiate and group the inks according to their brands. The manual examinations proved to be a time consuming and daunting task and more importantly were unable to differentiate the red ballpoint pen inks. On the other hand, PCA and HCA had successfully differentiated and grouped the red ballpoint pen inks according to their brands. The results demonstrated the potential use of PCA and HCA to differentiate and group red ballpoint pen inks of different brands in an objective manner. Universiti Sains Malaysia 2015 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/60137/1/NOR%20FATHIN%20BINTI%20MOHD%20RAZALI%20-%20e.pdf Razali, Nor Fathin Mohd (2015) Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques. Project Report. Universiti Sains Malaysia. (Submitted)
spellingShingle RA1001 Forensic Medicine. Medical jurisprudence. Legal medicine
Razali, Nor Fathin Mohd
Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title_full Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title_fullStr Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title_full_unstemmed Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title_short Characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
title_sort characterization of red ballpoint pens using uv-visible spectroscopy and pattern recognition techniques
topic RA1001 Forensic Medicine. Medical jurisprudence. Legal medicine
url http://eprints.usm.my/60137/
http://eprints.usm.my/60137/1/NOR%20FATHIN%20BINTI%20MOHD%20RAZALI%20-%20e.pdf