Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection

A simple, accurate, and reproducible high performance liquid chromatographic method for the separation and simultaneous determination of paracetamol and caffeine in dosage forms is described. The HPLC system consisted of Water Alliance Series 2475 with photo diode array detection. The separations we...

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Main Author: Ismail, Ismazarni
Format: Monograph
Language:English
Published: Pusat Pengajian Sains Kesihatan, Universiti Sains Malaysia 2006
Subjects:
Online Access:http://eprints.usm.my/59440/
http://eprints.usm.my/59440/1/ISMAZARNI%20BINTI%20ISMAIL%20-%20eprints.pdf
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author Ismail, Ismazarni
author_facet Ismail, Ismazarni
author_sort Ismail, Ismazarni
building USM Institutional Repository
collection Online Access
description A simple, accurate, and reproducible high performance liquid chromatographic method for the separation and simultaneous determination of paracetamol and caffeine in dosage forms is described. The HPLC system consisted of Water Alliance Series 2475 with photo diode array detection. The separations were c.arried out at room temperature on a C-8 (5 J.lffi, 250 x 4.6 mm i.d) Luna 5~ C-8 (2) Phenomenax Prodigy} analytical column. A mixture of 0.01 M KH2P04, methanol, acetonitrile, and isopropyl alcohol was used as mobile phase at a flow rate of 0.5 mllmin. Mobile phase solvents were degassed for 30 min. using ultrasonic bath and filtered through a 0.45 J.lm Milipore filter. The wavelength was in range of 210 to 400 nm. The validation validation linearity (r = 0.9998, 0.996 respectively for caffeine and paracetamol). The calculations of the concentration of paracetamol and caffeine were based on peak areas using calibration plots. The retention time of the separation of the mixture of caffeine and paracetamol were recorded as 11.695 min and 9.684 min respectively. This method is successfully applied to the analysis of commercial pharmaceutical preparations, yielding better resolution, sensitivity, and ease of operation as compared to the existing methods.
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format Monograph
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institution Universiti Sains Malaysia
institution_category Local University
language English
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publishDate 2006
publisher Pusat Pengajian Sains Kesihatan, Universiti Sains Malaysia
recordtype eprints
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spelling usm-594402023-11-14T06:14:45Z http://eprints.usm.my/59440/ Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection Ismail, Ismazarni QD71-142 Analytical chemistry A simple, accurate, and reproducible high performance liquid chromatographic method for the separation and simultaneous determination of paracetamol and caffeine in dosage forms is described. The HPLC system consisted of Water Alliance Series 2475 with photo diode array detection. The separations were c.arried out at room temperature on a C-8 (5 J.lffi, 250 x 4.6 mm i.d) Luna 5~ C-8 (2) Phenomenax Prodigy} analytical column. A mixture of 0.01 M KH2P04, methanol, acetonitrile, and isopropyl alcohol was used as mobile phase at a flow rate of 0.5 mllmin. Mobile phase solvents were degassed for 30 min. using ultrasonic bath and filtered through a 0.45 J.lm Milipore filter. The wavelength was in range of 210 to 400 nm. The validation validation linearity (r = 0.9998, 0.996 respectively for caffeine and paracetamol). The calculations of the concentration of paracetamol and caffeine were based on peak areas using calibration plots. The retention time of the separation of the mixture of caffeine and paracetamol were recorded as 11.695 min and 9.684 min respectively. This method is successfully applied to the analysis of commercial pharmaceutical preparations, yielding better resolution, sensitivity, and ease of operation as compared to the existing methods. Pusat Pengajian Sains Kesihatan, Universiti Sains Malaysia 2006 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/59440/1/ISMAZARNI%20BINTI%20ISMAIL%20-%20eprints.pdf Ismail, Ismazarni (2006) Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection. Project Report. Pusat Pengajian Sains Kesihatan, Universiti Sains Malaysia. (Submitted)
spellingShingle QD71-142 Analytical chemistry
Ismail, Ismazarni
Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title_full Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title_fullStr Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title_full_unstemmed Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title_short Determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
title_sort determination of paracetamol and caffeine in dosage forms by high performance liquid chromatography with photo diode array detection
topic QD71-142 Analytical chemistry
url http://eprints.usm.my/59440/
http://eprints.usm.my/59440/1/ISMAZARNI%20BINTI%20ISMAIL%20-%20eprints.pdf