Fluoride Removal Using Alumina Nanoparticles

The presence of fluoride in drinking water, in quantities in excess of permissible limits is a serious matter of concern from a public health point of view. High concentration of fluoride can lead to fluorosis. Various adsorbents for removing fluoride from drinking water have been studied in t...

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Main Author: Lopog, Ecrolien Liberty
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2006
Subjects:
Online Access:http://eprints.usm.my/58395/
http://eprints.usm.my/58395/1/Fluoride%20Removal%20Using%20Alumina%20Nanoparticles_Ecrolien%20Liberty%20Lopog.pdf
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author Lopog, Ecrolien Liberty
author_facet Lopog, Ecrolien Liberty
author_sort Lopog, Ecrolien Liberty
building USM Institutional Repository
collection Online Access
description The presence of fluoride in drinking water, in quantities in excess of permissible limits is a serious matter of concern from a public health point of view. High concentration of fluoride can lead to fluorosis. Various adsorbents for removing fluoride from drinking water have been studied in the past. In this research, alumina nanoparticles was proposed for the removal of fluoride from drinking water. Batch experiments were conducted to determine the efficacy of alumina nanoparticles in fluoride removal from water. The fluoride removal performance was investigated as a function of pH, contact time, initial fluoride concentration and adsorbent dosage. The dependence of the adsorption of fluoride on the pH of the solution has been studied to achieve the optimum pH value. It was found that the maximum adsorption takes place at pH 2.5. Contact time analysis revealed that the percent fluoride removal increases initially as contact time increases, but then it gradually approaches a more or less constant value, indicating that the equilibrium has been attained. The experiments showed that 120 minutes was the suitable contact time. In kinetic study, the Second Order Integral model was found to express the sorption kinetics of fluoride better. Study on the influence of adsorbent dosage showed that the efficiency of the fluoride removal increases with the increase of adsorbent dosage. The removal efficiency for 2, 4, 6, 8, and 10 g/l of alumina nanoparticles is 15, 24.80, 33.87, 41.33, and 48.53 % respectively. Adsorption isotherms have been modeled by Langmuir and Freundlich equations and isotherm constants for both isotherms were calculated. In isotherms studies, both models were found to be suitable to describe the adsorption of fluoride onto the alumina nanoparticles. The capacity of alumina nanoparticles is 4.4033 mg/g which can be obtained from the Langmuir isotherm.
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institution Universiti Sains Malaysia
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language English
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spelling usm-583952023-05-08T10:09:50Z http://eprints.usm.my/58395/ Fluoride Removal Using Alumina Nanoparticles Lopog, Ecrolien Liberty T Technology TA Engineering (General). Civil engineering (General) The presence of fluoride in drinking water, in quantities in excess of permissible limits is a serious matter of concern from a public health point of view. High concentration of fluoride can lead to fluorosis. Various adsorbents for removing fluoride from drinking water have been studied in the past. In this research, alumina nanoparticles was proposed for the removal of fluoride from drinking water. Batch experiments were conducted to determine the efficacy of alumina nanoparticles in fluoride removal from water. The fluoride removal performance was investigated as a function of pH, contact time, initial fluoride concentration and adsorbent dosage. The dependence of the adsorption of fluoride on the pH of the solution has been studied to achieve the optimum pH value. It was found that the maximum adsorption takes place at pH 2.5. Contact time analysis revealed that the percent fluoride removal increases initially as contact time increases, but then it gradually approaches a more or less constant value, indicating that the equilibrium has been attained. The experiments showed that 120 minutes was the suitable contact time. In kinetic study, the Second Order Integral model was found to express the sorption kinetics of fluoride better. Study on the influence of adsorbent dosage showed that the efficiency of the fluoride removal increases with the increase of adsorbent dosage. The removal efficiency for 2, 4, 6, 8, and 10 g/l of alumina nanoparticles is 15, 24.80, 33.87, 41.33, and 48.53 % respectively. Adsorption isotherms have been modeled by Langmuir and Freundlich equations and isotherm constants for both isotherms were calculated. In isotherms studies, both models were found to be suitable to describe the adsorption of fluoride onto the alumina nanoparticles. The capacity of alumina nanoparticles is 4.4033 mg/g which can be obtained from the Langmuir isotherm. Universiti Sains Malaysia 2006-05-01 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/58395/1/Fluoride%20Removal%20Using%20Alumina%20Nanoparticles_Ecrolien%20Liberty%20Lopog.pdf Lopog, Ecrolien Liberty (2006) Fluoride Removal Using Alumina Nanoparticles. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Awam. (Submitted)
spellingShingle T Technology
TA Engineering (General). Civil engineering (General)
Lopog, Ecrolien Liberty
Fluoride Removal Using Alumina Nanoparticles
title Fluoride Removal Using Alumina Nanoparticles
title_full Fluoride Removal Using Alumina Nanoparticles
title_fullStr Fluoride Removal Using Alumina Nanoparticles
title_full_unstemmed Fluoride Removal Using Alumina Nanoparticles
title_short Fluoride Removal Using Alumina Nanoparticles
title_sort fluoride removal using alumina nanoparticles
topic T Technology
TA Engineering (General). Civil engineering (General)
url http://eprints.usm.my/58395/
http://eprints.usm.my/58395/1/Fluoride%20Removal%20Using%20Alumina%20Nanoparticles_Ecrolien%20Liberty%20Lopog.pdf