Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites

In the present study, the water absorption behaviour, mechanical, thermal and morphological properties of poly(lactic acid)/kenaf (PLA/KF) composites with different fiber size were investigated. PLA/KF composites were prepared by using single screw extruder and injection moulding method and followe...

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Main Author: Thian, Yoke Teng
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2022
Subjects:
Online Access:http://eprints.usm.my/56736/
http://eprints.usm.my/56736/1/Water%20Absorption%20And%20Hygrothermal%20Aging%20Behavior%20Of%20Kenaf%20Fiber-Reinforced%20Poly%28Lactic%20Acid%29%20Composites_Thian%20Yoke%20Teng.pdf
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author Thian, Yoke Teng
author_facet Thian, Yoke Teng
author_sort Thian, Yoke Teng
building USM Institutional Repository
collection Online Access
description In the present study, the water absorption behaviour, mechanical, thermal and morphological properties of poly(lactic acid)/kenaf (PLA/KF) composites with different fiber size were investigated. PLA/KF composites were prepared by using single screw extruder and injection moulding method and followed by hygrothermal aging at 60 °C for 4 weeks. The water absorption and mechanical properties of the PLA/KF composites with immersion time were reported and compared to those of neat PLA. PLA/KF composites showed higher water uptake at equilibrium and diffusion coefficients than that of neat PLA, which indicated that the addition of kenaf fiber induced higher water absorption caused by the hydrophilic nature of the fibers. Tensile strength and tensile modulus severely decreased after aging. PLA/KF composite with larger fiber has higher tensile strength and modulus than that with smaller fiber due to its higher aspect ratio. The morphologies of surfaces and fractured surfaces of neat PLA and PLA/KF composites with different immersion time were observed by scanning electronic microscopy. The voids and micro-cracks were found which was due to the degradation of PLA and debonding of PLA and kenaf. FTIR spectrum showed that the number of –OH groups in PLA/KF composite after aging were more than composite before aging due to diffusion of water molecules into the composites. Tg and Tm for PLA/KF composites decrease after aging due to the reduction in molecular weight and plasticization effect of PLA were analysed by differential scanning calorimetry.
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format Monograph
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institution Universiti Sains Malaysia
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language English
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spelling usm-567362023-02-01T09:05:24Z http://eprints.usm.my/56736/ Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites Thian, Yoke Teng T Technology TN Mining Engineering. Metallurgy In the present study, the water absorption behaviour, mechanical, thermal and morphological properties of poly(lactic acid)/kenaf (PLA/KF) composites with different fiber size were investigated. PLA/KF composites were prepared by using single screw extruder and injection moulding method and followed by hygrothermal aging at 60 °C for 4 weeks. The water absorption and mechanical properties of the PLA/KF composites with immersion time were reported and compared to those of neat PLA. PLA/KF composites showed higher water uptake at equilibrium and diffusion coefficients than that of neat PLA, which indicated that the addition of kenaf fiber induced higher water absorption caused by the hydrophilic nature of the fibers. Tensile strength and tensile modulus severely decreased after aging. PLA/KF composite with larger fiber has higher tensile strength and modulus than that with smaller fiber due to its higher aspect ratio. The morphologies of surfaces and fractured surfaces of neat PLA and PLA/KF composites with different immersion time were observed by scanning electronic microscopy. The voids and micro-cracks were found which was due to the degradation of PLA and debonding of PLA and kenaf. FTIR spectrum showed that the number of –OH groups in PLA/KF composite after aging were more than composite before aging due to diffusion of water molecules into the composites. Tg and Tm for PLA/KF composites decrease after aging due to the reduction in molecular weight and plasticization effect of PLA were analysed by differential scanning calorimetry. Universiti Sains Malaysia 2022-08-10 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/56736/1/Water%20Absorption%20And%20Hygrothermal%20Aging%20Behavior%20Of%20Kenaf%20Fiber-Reinforced%20Poly%28Lactic%20Acid%29%20Composites_Thian%20Yoke%20Teng.pdf Thian, Yoke Teng (2022) Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Bahan dan Sumber Mineral. (Submitted)
spellingShingle T Technology
TN Mining Engineering. Metallurgy
Thian, Yoke Teng
Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title_full Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title_fullStr Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title_full_unstemmed Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title_short Water Absorption And Hygrothermal Aging Behavior Of Kenaf Fiber-Reinforced Poly(Lactic Acid) Composites
title_sort water absorption and hygrothermal aging behavior of kenaf fiber-reinforced poly(lactic acid) composites
topic T Technology
TN Mining Engineering. Metallurgy
url http://eprints.usm.my/56736/
http://eprints.usm.my/56736/1/Water%20Absorption%20And%20Hygrothermal%20Aging%20Behavior%20Of%20Kenaf%20Fiber-Reinforced%20Poly%28Lactic%20Acid%29%20Composites_Thian%20Yoke%20Teng.pdf