Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies

Nowadays, textile industry has been recognized as the most significant source of wastewater pollution mostly related to dyes which directly released into water bodies, resulting in various environmental impacts. These dyes are always released in industrial waste, leading to disposal problem. In the...

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Main Author: Mohd Ramli, Mohamad Razif
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2018
Subjects:
Online Access:http://eprints.usm.my/53628/
http://eprints.usm.my/53628/1/Activated%20Carbon%20Adsorbent%20From%20Jengkol%20Peel%20For%20Dye%20Removal%20Equilibrium%2C%20Kinetic%20And%20Thermodynamic%20Studies_Mohamad%20Razif%20Mohd%20Ramli_K4_2018.pdf
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author Mohd Ramli, Mohamad Razif
author_facet Mohd Ramli, Mohamad Razif
author_sort Mohd Ramli, Mohamad Razif
building USM Institutional Repository
collection Online Access
description Nowadays, textile industry has been recognized as the most significant source of wastewater pollution mostly related to dyes which directly released into water bodies, resulting in various environmental impacts. These dyes are always released in industrial waste, leading to disposal problem. In the recent years, growing research interest in conversion of agricultural waste into activated carbon (AC) as adsorbent for treating dyes wastewater. The aim of this research is to study the performance of AC derived from jengkol peel (JP) for removal of Methylene Blue (MB) dye by using physical activation which involves carbon dioxide (CO2) gasification and microwave radiation. Optimum conditions for preparation jengkol peel activated carbon (JPAC) were found at 400 W of radiation power and 4 minute activation time which resulted 92.6% MB removal. Optimized JPAC has Bruneaur-Emmet-Teller (BET) surface area, mesopore surface area, pore volume, fixed carbon content of 474.03 m2/g, 332.64 m2/g, 0.389 cm3/g, and 70.45 % respectively. The pore diameter of JPAC was discovered to be mesoporous at 4.28nm. Adsorption equilibrium of MB on JPAC followed Freundlich isotherm. Kinetic studies of adsorption onto JPAC fit by pseudo-second order kinetic models. Thermodynamic study shows the value of ∆Ho was negative which gave an indication that the adsorption was exothermic process.
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institution Universiti Sains Malaysia
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language English
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publishDate 2018
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spelling usm-536282022-07-27T04:43:40Z http://eprints.usm.my/53628/ Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies Mohd Ramli, Mohamad Razif T Technology TP Chemical Technology Nowadays, textile industry has been recognized as the most significant source of wastewater pollution mostly related to dyes which directly released into water bodies, resulting in various environmental impacts. These dyes are always released in industrial waste, leading to disposal problem. In the recent years, growing research interest in conversion of agricultural waste into activated carbon (AC) as adsorbent for treating dyes wastewater. The aim of this research is to study the performance of AC derived from jengkol peel (JP) for removal of Methylene Blue (MB) dye by using physical activation which involves carbon dioxide (CO2) gasification and microwave radiation. Optimum conditions for preparation jengkol peel activated carbon (JPAC) were found at 400 W of radiation power and 4 minute activation time which resulted 92.6% MB removal. Optimized JPAC has Bruneaur-Emmet-Teller (BET) surface area, mesopore surface area, pore volume, fixed carbon content of 474.03 m2/g, 332.64 m2/g, 0.389 cm3/g, and 70.45 % respectively. The pore diameter of JPAC was discovered to be mesoporous at 4.28nm. Adsorption equilibrium of MB on JPAC followed Freundlich isotherm. Kinetic studies of adsorption onto JPAC fit by pseudo-second order kinetic models. Thermodynamic study shows the value of ∆Ho was negative which gave an indication that the adsorption was exothermic process. Universiti Sains Malaysia 2018-06-01 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/53628/1/Activated%20Carbon%20Adsorbent%20From%20Jengkol%20Peel%20For%20Dye%20Removal%20Equilibrium%2C%20Kinetic%20And%20Thermodynamic%20Studies_Mohamad%20Razif%20Mohd%20Ramli_K4_2018.pdf Mohd Ramli, Mohamad Razif (2018) Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Kimia. (Submitted)
spellingShingle T Technology
TP Chemical Technology
Mohd Ramli, Mohamad Razif
Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title_full Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title_fullStr Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title_full_unstemmed Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title_short Activated Carbon Adsorbent From Jengkol Peel For Dye Removal Equilibrium, Kinetic And Thermodynamic Studies
title_sort activated carbon adsorbent from jengkol peel for dye removal equilibrium, kinetic and thermodynamic studies
topic T Technology
TP Chemical Technology
url http://eprints.usm.my/53628/
http://eprints.usm.my/53628/1/Activated%20Carbon%20Adsorbent%20From%20Jengkol%20Peel%20For%20Dye%20Removal%20Equilibrium%2C%20Kinetic%20And%20Thermodynamic%20Studies_Mohamad%20Razif%20Mohd%20Ramli_K4_2018.pdf