Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)

Heavy metals becoming pollutants due to its non-biodegradable characteristics, toxicity and persistence in the environment where lead is one of it. In this study, Manihot esculenta stem biomass was used in the biosorption process of lead (II) ions in batch. The effects of pretreatment (raw, acid and...

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Main Author: Selvam, Sathiswaran
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2017
Subjects:
Online Access:http://eprints.usm.my/53136/
http://eprints.usm.my/53136/1/Biosorption%20Of%20Lead%20%28Ii%29%20Ions%20By%20Stem%20Of%20Manihot%20Esculenta%20%28Cassava%20Stem%29_Sathiswaran%20Selvam_K4_2017.pdf
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author Selvam, Sathiswaran
author_facet Selvam, Sathiswaran
author_sort Selvam, Sathiswaran
building USM Institutional Repository
collection Online Access
description Heavy metals becoming pollutants due to its non-biodegradable characteristics, toxicity and persistence in the environment where lead is one of it. In this study, Manihot esculenta stem biomass was used in the biosorption process of lead (II) ions in batch. The effects of pretreatment (raw, acid and alkali), pH control (2-6), biomass loading (0.25 g – 1.25 g), contact time (20 minutes – 100 minutes) and initial metal concentration (50 mg/L – 250mg/L) were studied on the removal of lead (II) ions from aqueous solution. Observations stated that the suitable conditions for high biosorption capacity, which is removal up to 99.60% by M. esculenta stem are alkali pretreated biosorbent, at pH 6, biomass loading of 0.75 g, metal concentration of 100 mg/L, in 60 minutes contact time. It is also found that Langmuir isotherm model (R2= 0.9783) fits well for this biosorption process as adsorption isotherm, rather than Freundlich isotherm model (R2= 0.7581). Kinetic data modelling resulted in good fit with the pseudo-second-order model (R2= 1.000) compared to pseudo-first-order model (R2= 0.6244). Overall result shows that M. esculenta stem is a good biosorbent, and can be used as an alternative low-cost biosorbent for removal of lead (II) ions.
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spelling usm-531362022-06-27T10:13:51Z http://eprints.usm.my/53136/ Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem) Selvam, Sathiswaran T Technology TP155-156 Chemical engineering Heavy metals becoming pollutants due to its non-biodegradable characteristics, toxicity and persistence in the environment where lead is one of it. In this study, Manihot esculenta stem biomass was used in the biosorption process of lead (II) ions in batch. The effects of pretreatment (raw, acid and alkali), pH control (2-6), biomass loading (0.25 g – 1.25 g), contact time (20 minutes – 100 minutes) and initial metal concentration (50 mg/L – 250mg/L) were studied on the removal of lead (II) ions from aqueous solution. Observations stated that the suitable conditions for high biosorption capacity, which is removal up to 99.60% by M. esculenta stem are alkali pretreated biosorbent, at pH 6, biomass loading of 0.75 g, metal concentration of 100 mg/L, in 60 minutes contact time. It is also found that Langmuir isotherm model (R2= 0.9783) fits well for this biosorption process as adsorption isotherm, rather than Freundlich isotherm model (R2= 0.7581). Kinetic data modelling resulted in good fit with the pseudo-second-order model (R2= 1.000) compared to pseudo-first-order model (R2= 0.6244). Overall result shows that M. esculenta stem is a good biosorbent, and can be used as an alternative low-cost biosorbent for removal of lead (II) ions. Universiti Sains Malaysia 2017-06-01 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/53136/1/Biosorption%20Of%20Lead%20%28Ii%29%20Ions%20By%20Stem%20Of%20Manihot%20Esculenta%20%28Cassava%20Stem%29_Sathiswaran%20Selvam_K4_2017.pdf Selvam, Sathiswaran (2017) Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem). Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Kimia. (Submitted)
spellingShingle T Technology
TP155-156 Chemical engineering
Selvam, Sathiswaran
Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title_full Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title_fullStr Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title_full_unstemmed Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title_short Biosorption Of Lead (Ii) Ions By Stem Of Manihot Esculenta (Cassava Stem)
title_sort biosorption of lead (ii) ions by stem of manihot esculenta (cassava stem)
topic T Technology
TP155-156 Chemical engineering
url http://eprints.usm.my/53136/
http://eprints.usm.my/53136/1/Biosorption%20Of%20Lead%20%28Ii%29%20Ions%20By%20Stem%20Of%20Manihot%20Esculenta%20%28Cassava%20Stem%29_Sathiswaran%20Selvam_K4_2017.pdf