Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries

The objective of this research is to study the effect of agar binder in lithium vanadium oxide (LiV3O8) anode on electrochemical and physical performance of the electrode. LiV3O8, graphene and agar binder were used to prepare LiV3O8 electrode in 8:1:1 ratio with different percentage of agar binder....

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Main Author: Lease, Jacqueline
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2018
Subjects:
Online Access:http://eprints.usm.my/53099/
http://eprints.usm.my/53099/1/Electrochemical%20Characterization%20Of%20Lithium%20Vanadium%20Oxide%20Anode%20With%20Agar%20Binder%20In%20Aqueous%20Rechargeable%20Lithium%20Ion%20Batteries_Jacqueline%20Lease_B1_2018.pdf
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author Lease, Jacqueline
author_facet Lease, Jacqueline
author_sort Lease, Jacqueline
building USM Institutional Repository
collection Online Access
description The objective of this research is to study the effect of agar binder in lithium vanadium oxide (LiV3O8) anode on electrochemical and physical performance of the electrode. LiV3O8, graphene and agar binder were used to prepare LiV3O8 electrode in 8:1:1 ratio with different percentage of agar binder. The working electrode allowed to be characterized as a half-cell setting for the characterization. The structural analysis confirmed that the layered structure of LiV3O8 and graphene were formed. The binder was also successfully bind the matrix of active material and graphene together based on the morphology analysis. With the optimum scan rate (0.1 mV s-1) in cyclic voltammetry (CV), 8% agar electrode has the best performance. The high coefficient diffusion of lithium ions at 3.046 x 10-6 (anodic) and 1.315 x 10-6 cm2 s-1 (cathodic) for the peaks were also further determined by CV characterization. Low charge transfer resistances from impedance analysis in the anode half-cell showed the stability of the anode. The capacity of the anode fading slowly upon cycling. Best scan rate in charge/discharge has shown to obtain desirable initial specific charge and discharge capacities which are 51.20 mA h g-1 and 76.12 mA h g-1. A good cyclic performance with 84.1% capacity retention was obtained for 10 cycles at charge rate 2 C. Throughout the characterization, the anode will degrade at the initial cycles but return to stable after 25 cycles. LiV3O8 showed promising results when agar binder was added in this study.
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format Monograph
id usm-53099
institution Universiti Sains Malaysia
institution_category Local University
language English
last_indexed 2025-11-15T18:34:49Z
publishDate 2018
publisher Universiti Sains Malaysia
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spelling usm-530992022-06-27T04:19:58Z http://eprints.usm.my/53099/ Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries Lease, Jacqueline T Technology TN Mining Engineering. Metallurgy The objective of this research is to study the effect of agar binder in lithium vanadium oxide (LiV3O8) anode on electrochemical and physical performance of the electrode. LiV3O8, graphene and agar binder were used to prepare LiV3O8 electrode in 8:1:1 ratio with different percentage of agar binder. The working electrode allowed to be characterized as a half-cell setting for the characterization. The structural analysis confirmed that the layered structure of LiV3O8 and graphene were formed. The binder was also successfully bind the matrix of active material and graphene together based on the morphology analysis. With the optimum scan rate (0.1 mV s-1) in cyclic voltammetry (CV), 8% agar electrode has the best performance. The high coefficient diffusion of lithium ions at 3.046 x 10-6 (anodic) and 1.315 x 10-6 cm2 s-1 (cathodic) for the peaks were also further determined by CV characterization. Low charge transfer resistances from impedance analysis in the anode half-cell showed the stability of the anode. The capacity of the anode fading slowly upon cycling. Best scan rate in charge/discharge has shown to obtain desirable initial specific charge and discharge capacities which are 51.20 mA h g-1 and 76.12 mA h g-1. A good cyclic performance with 84.1% capacity retention was obtained for 10 cycles at charge rate 2 C. Throughout the characterization, the anode will degrade at the initial cycles but return to stable after 25 cycles. LiV3O8 showed promising results when agar binder was added in this study. Universiti Sains Malaysia 2018-06-12 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/53099/1/Electrochemical%20Characterization%20Of%20Lithium%20Vanadium%20Oxide%20Anode%20With%20Agar%20Binder%20In%20Aqueous%20Rechargeable%20Lithium%20Ion%20Batteries_Jacqueline%20Lease_B1_2018.pdf Lease, Jacqueline (2018) Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries. Project Report. Universiti Sains Malaysia, Pusat Pengajian Kejuruteraan Bahan dan Sumber Mineral. (Submitted)
spellingShingle T Technology
TN Mining Engineering. Metallurgy
Lease, Jacqueline
Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title_full Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title_fullStr Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title_full_unstemmed Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title_short Electrochemical Characterization Of Lithium Vanadium Oxide Anode With Agar Binder In Aqueous Rechargeable Lithium Ion Batteries
title_sort electrochemical characterization of lithium vanadium oxide anode with agar binder in aqueous rechargeable lithium ion batteries
topic T Technology
TN Mining Engineering. Metallurgy
url http://eprints.usm.my/53099/
http://eprints.usm.my/53099/1/Electrochemical%20Characterization%20Of%20Lithium%20Vanadium%20Oxide%20Anode%20With%20Agar%20Binder%20In%20Aqueous%20Rechargeable%20Lithium%20Ion%20Batteries_Jacqueline%20Lease_B1_2018.pdf