Determination of heavy metals in fish and seafood

The aim of this study was to detennine concentrations level of heavy metals (zinc, copper, cadmium and lead) in edible parts of fish and seafood. The levels of these metals in fish (6) and seafood (4) purchased from the Kelantan markets were measured. The conventional wet acid digestion method wa...

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Main Author: Saim, Hafizah
Format: Thesis
Language:English
Published: 2011
Subjects:
Online Access:http://eprints.usm.my/52250/
http://eprints.usm.my/52250/1/HAFIZAH%20BINTI%20SAIM-24%20pages.pdf
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author Saim, Hafizah
author_facet Saim, Hafizah
author_sort Saim, Hafizah
building USM Institutional Repository
collection Online Access
description The aim of this study was to detennine concentrations level of heavy metals (zinc, copper, cadmium and lead) in edible parts of fish and seafood. The levels of these metals in fish (6) and seafood (4) purchased from the Kelantan markets were measured. The conventional wet acid digestion method was used for the mineralization of these samples prior to the quantitative detennination by graphite furnace atomic absorption spectrometry (AOAC International, 2002). The heavy metal concentrations in the fish ranged from (0.020 ± 0.01 to 0.900 ± 0.12 μg/g ww) for Cu, (2.593 ± 0.36 to 9.610 ± 0.08 μg/g ww) for Zn, (0.025 ± 0.0025 to 0.150 ± 0.0014 μg/g ww) for Cd and (0.004 ± 0.014 to 0.110 ± 0.026 μg/g ww) for Pb. Meanwhile, the heavy metal concentrations in seafood ranged from (0.440 ± 0.06 to 9.300 ± 0.10 μg/g ww) for Cu, (1.669 ± 0.46 to 9.800 ± 0.23 μg/g ww) for Zn, (0.340 ± 0.0032 to 0.930 ± 0.0023 μg/g ww) for Cd and (0.006 ± 0.017 to 0.180 ± 0.029 μg/g ww) for Pb. In average, all heavy metals in seafood were higher than in fish. This study also showed that the heavy metals concentration in demersal fish and seafood were higher compared to pelagic species. The metal concentrations in the pelagic species ranged from (0.020 ± 0.01 to 0.672 ± 0.24 μg/g ww) for Cu, (2.593 ± 0.36 to 5.693 ± 0.16 μg/g ww) for Zn, (0.025 ± 0.0025 to 0.041 ± 0.0023 μg/g ww) for Cd, and (0.004 ± 0.014 to 0.005 ± 0.022 μg/g ww) for Pb. Meanwhile, the metal concentrations in demersal species ranged from (0.440 ± 0.06 to 9.300 ± 0.10 μg/g ww) for Cu, (1.669 ± 0.46 to 9.800 ± 0.23 μg/g ww) for zinc, (0.130 ± 0.0023 to 0.930 1 ± 0.0023 μg/g ww) for Cd and (0.006 ± 0.017 to 0.180 ± 0.029 μg/g ww) for Pb. Comparison of heavy metals concentration between pelagic and demersal species were difficult due to the lack of literature information from other studies at more global scale. However, all the average values of these metals from all populations were lower than guidelines and regulations stipulating maximum permissible levels set by the Malaysian Food Act 1983 and Food Regulations 1985 Fourteen Schedule. These metals concentration found in fish and seafood were also considered to be lower compared with literature in other studies. Thus, these concentration levels should result in no acute toxicities of heavy metals since they are lower than the limit. It was concluded that heavy metals concentration level in commercial fish and seafood must be monitored comprehensively and periodically with respect to the consumer health.
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spelling usm-522502022-04-10T04:45:12Z http://eprints.usm.my/52250/ Determination of heavy metals in fish and seafood Saim, Hafizah R Medicine The aim of this study was to detennine concentrations level of heavy metals (zinc, copper, cadmium and lead) in edible parts of fish and seafood. The levels of these metals in fish (6) and seafood (4) purchased from the Kelantan markets were measured. The conventional wet acid digestion method was used for the mineralization of these samples prior to the quantitative detennination by graphite furnace atomic absorption spectrometry (AOAC International, 2002). The heavy metal concentrations in the fish ranged from (0.020 ± 0.01 to 0.900 ± 0.12 μg/g ww) for Cu, (2.593 ± 0.36 to 9.610 ± 0.08 μg/g ww) for Zn, (0.025 ± 0.0025 to 0.150 ± 0.0014 μg/g ww) for Cd and (0.004 ± 0.014 to 0.110 ± 0.026 μg/g ww) for Pb. Meanwhile, the heavy metal concentrations in seafood ranged from (0.440 ± 0.06 to 9.300 ± 0.10 μg/g ww) for Cu, (1.669 ± 0.46 to 9.800 ± 0.23 μg/g ww) for Zn, (0.340 ± 0.0032 to 0.930 ± 0.0023 μg/g ww) for Cd and (0.006 ± 0.017 to 0.180 ± 0.029 μg/g ww) for Pb. In average, all heavy metals in seafood were higher than in fish. This study also showed that the heavy metals concentration in demersal fish and seafood were higher compared to pelagic species. The metal concentrations in the pelagic species ranged from (0.020 ± 0.01 to 0.672 ± 0.24 μg/g ww) for Cu, (2.593 ± 0.36 to 5.693 ± 0.16 μg/g ww) for Zn, (0.025 ± 0.0025 to 0.041 ± 0.0023 μg/g ww) for Cd, and (0.004 ± 0.014 to 0.005 ± 0.022 μg/g ww) for Pb. Meanwhile, the metal concentrations in demersal species ranged from (0.440 ± 0.06 to 9.300 ± 0.10 μg/g ww) for Cu, (1.669 ± 0.46 to 9.800 ± 0.23 μg/g ww) for zinc, (0.130 ± 0.0023 to 0.930 1 ± 0.0023 μg/g ww) for Cd and (0.006 ± 0.017 to 0.180 ± 0.029 μg/g ww) for Pb. Comparison of heavy metals concentration between pelagic and demersal species were difficult due to the lack of literature information from other studies at more global scale. However, all the average values of these metals from all populations were lower than guidelines and regulations stipulating maximum permissible levels set by the Malaysian Food Act 1983 and Food Regulations 1985 Fourteen Schedule. These metals concentration found in fish and seafood were also considered to be lower compared with literature in other studies. Thus, these concentration levels should result in no acute toxicities of heavy metals since they are lower than the limit. It was concluded that heavy metals concentration level in commercial fish and seafood must be monitored comprehensively and periodically with respect to the consumer health. 2011 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/52250/1/HAFIZAH%20BINTI%20SAIM-24%20pages.pdf Saim, Hafizah (2011) Determination of heavy metals in fish and seafood. Masters thesis, Universiti Sains Malaysia.
spellingShingle R Medicine
Saim, Hafizah
Determination of heavy metals in fish and seafood
title Determination of heavy metals in fish and seafood
title_full Determination of heavy metals in fish and seafood
title_fullStr Determination of heavy metals in fish and seafood
title_full_unstemmed Determination of heavy metals in fish and seafood
title_short Determination of heavy metals in fish and seafood
title_sort determination of heavy metals in fish and seafood
topic R Medicine
url http://eprints.usm.my/52250/
http://eprints.usm.my/52250/1/HAFIZAH%20BINTI%20SAIM-24%20pages.pdf