Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core

In this study, the effect of silane treatment on kenaf core (KC) and KC reinforced polyurethane (KCP) composites were discussed. The composite was prepared using one shot process. Firstly, polyurethane (PU) was prepared from methylene diphenyl diisocyanate (MDI) and glycerol using different NCO/O...

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Main Author: Bakar, Azizah Abu
Format: Thesis
Language:English
Published: 2018
Subjects:
Online Access:http://eprints.usm.my/48551/
http://eprints.usm.my/48551/1/AZIZAH%20BINTI%20ABU%20BAKAR_hj.pdf
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author Bakar, Azizah Abu
author_facet Bakar, Azizah Abu
author_sort Bakar, Azizah Abu
building USM Institutional Repository
collection Online Access
description In this study, the effect of silane treatment on kenaf core (KC) and KC reinforced polyurethane (KCP) composites were discussed. The composite was prepared using one shot process. Firstly, polyurethane (PU) was prepared from methylene diphenyl diisocyanate (MDI) and glycerol using different NCO/OH ratio and KCP composites with different KC loadings were prepared using a suitable NCO/OH ratio. From the mechanical properties measurement, it was found that NCO/OH ratio of 1.5 and KC loadings of 20% were suitable to be studied. In the next phase, KC was treated with different types of silane (1 – 3%); which were vinyltrimethoxysilane (VTMS), trimethoxyphenylsilane (TMPS), and tetramethoxy orthosilicate (TMOS) using hydrolysis method with ethanol/water (80:20 volume) as silanization medium for KC The properties of untreated KC (UKC) and treated KC (TKC) were investigated through filler morphology analysis, Scanning Electron Microscopy – Energy Dispersive X-ray (SEM – EDX) mapping element analysis, Fourier Transform Infrared (FTIR) analysis, and Thermogravimetric Analysis (TGA) analysis. UKC and TKC surface morphology and SEM – EDX mapping analysis showed the presence of Si element on the TKC surface. Thermal analysis revealed that, silane treatment had enhanced the thermal stability. The visco-mechanical properties of kenaf core treated with silane – polyurethane (TKCP) composite were measured by Dynamical Mechanical Analysis (DMA).
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institution Universiti Sains Malaysia
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language English
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publishDate 2018
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spelling usm-485512021-03-08T07:17:04Z http://eprints.usm.my/48551/ Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core Bakar, Azizah Abu T1-995 Technology(General) In this study, the effect of silane treatment on kenaf core (KC) and KC reinforced polyurethane (KCP) composites were discussed. The composite was prepared using one shot process. Firstly, polyurethane (PU) was prepared from methylene diphenyl diisocyanate (MDI) and glycerol using different NCO/OH ratio and KCP composites with different KC loadings were prepared using a suitable NCO/OH ratio. From the mechanical properties measurement, it was found that NCO/OH ratio of 1.5 and KC loadings of 20% were suitable to be studied. In the next phase, KC was treated with different types of silane (1 – 3%); which were vinyltrimethoxysilane (VTMS), trimethoxyphenylsilane (TMPS), and tetramethoxy orthosilicate (TMOS) using hydrolysis method with ethanol/water (80:20 volume) as silanization medium for KC The properties of untreated KC (UKC) and treated KC (TKC) were investigated through filler morphology analysis, Scanning Electron Microscopy – Energy Dispersive X-ray (SEM – EDX) mapping element analysis, Fourier Transform Infrared (FTIR) analysis, and Thermogravimetric Analysis (TGA) analysis. UKC and TKC surface morphology and SEM – EDX mapping analysis showed the presence of Si element on the TKC surface. Thermal analysis revealed that, silane treatment had enhanced the thermal stability. The visco-mechanical properties of kenaf core treated with silane – polyurethane (TKCP) composite were measured by Dynamical Mechanical Analysis (DMA). 2018-07 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/48551/1/AZIZAH%20BINTI%20ABU%20BAKAR_hj.pdf Bakar, Azizah Abu (2018) Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core. PhD thesis, Universiti Sains Malaysia.
spellingShingle T1-995 Technology(General)
Bakar, Azizah Abu
Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title_full Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title_fullStr Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title_full_unstemmed Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title_short Preparation And Characterization Of Polyurethane Composites Reinforced By Kenaf Core
title_sort preparation and characterization of polyurethane composites reinforced by kenaf core
topic T1-995 Technology(General)
url http://eprints.usm.my/48551/
http://eprints.usm.my/48551/1/AZIZAH%20BINTI%20ABU%20BAKAR_hj.pdf