Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production

ABSTRACT This work focuses on producing a novel catalyst to synthesize methyl esters from triglycerides by the reaction with methanol. Firstly, calcium oxide derived from staghorn coral was characterized and applied in the transesterification process of refined, bleached and deodorized, (RBD) palm...

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Main Author: Zul, Nabilah Atiqah
Format: Thesis
Language:English
Published: 2019
Subjects:
Online Access:http://eprints.usm.my/48368/
http://eprints.usm.my/48368/1/THESIS-NABILAH%20ATIQAH%20ZUL%20cut.pdf
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author Zul, Nabilah Atiqah
author_facet Zul, Nabilah Atiqah
author_sort Zul, Nabilah Atiqah
building USM Institutional Repository
collection Online Access
description ABSTRACT This work focuses on producing a novel catalyst to synthesize methyl esters from triglycerides by the reaction with methanol. Firstly, calcium oxide derived from staghorn coral was characterized and applied in the transesterification process of refined, bleached and deodorized, (RBD) palm olein. The reaction only yielded about 62.1 ± 4.3 % methyl esters. Therefore, a catalyst modification was carried out by impregnating the staghorn coral with potassium hydroxide, KOH as an effort to further enhance its catalytic effect. The modified catalyst (K-CSC) was then used as a base catalyst in the methanolysis of RBD palm olein and waste cooking oil. For RBD palm olein transesterification, the best reaction conditions to obtain methyl esters content of 94.8 ± 0.5 % was found to be 4 wt.% catalyst, 4 h reaction time, and 15:1 methanol to oil molar ratio. Besides that, K-CSC catalyst also successfully transesterified waste cooking oil at the reaction conditions of 4 wt.% catalyst, 5 h reaction time and 18:1 methanol to oil molar ratio and produced 89.5 ± 4.8 % biodiesel. The reusability of K-CSC catalyst was also studied and unfortunately,
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language English
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spelling usm-483682021-02-21T07:54:47Z http://eprints.usm.my/48368/ Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production Zul, Nabilah Atiqah QD1-999 Chemistry ABSTRACT This work focuses on producing a novel catalyst to synthesize methyl esters from triglycerides by the reaction with methanol. Firstly, calcium oxide derived from staghorn coral was characterized and applied in the transesterification process of refined, bleached and deodorized, (RBD) palm olein. The reaction only yielded about 62.1 ± 4.3 % methyl esters. Therefore, a catalyst modification was carried out by impregnating the staghorn coral with potassium hydroxide, KOH as an effort to further enhance its catalytic effect. The modified catalyst (K-CSC) was then used as a base catalyst in the methanolysis of RBD palm olein and waste cooking oil. For RBD palm olein transesterification, the best reaction conditions to obtain methyl esters content of 94.8 ± 0.5 % was found to be 4 wt.% catalyst, 4 h reaction time, and 15:1 methanol to oil molar ratio. Besides that, K-CSC catalyst also successfully transesterified waste cooking oil at the reaction conditions of 4 wt.% catalyst, 5 h reaction time and 18:1 methanol to oil molar ratio and produced 89.5 ± 4.8 % biodiesel. The reusability of K-CSC catalyst was also studied and unfortunately, 2019-05 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/48368/1/THESIS-NABILAH%20ATIQAH%20ZUL%20cut.pdf Zul, Nabilah Atiqah (2019) Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production. Masters thesis, Universiti Sains Malaysia.
spellingShingle QD1-999 Chemistry
Zul, Nabilah Atiqah
Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title_full Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title_fullStr Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title_full_unstemmed Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title_short Utilization Of Modified Waste Staghorn Coral As A Base Catalyst In Biodiesel Production
title_sort utilization of modified waste staghorn coral as a base catalyst in biodiesel production
topic QD1-999 Chemistry
url http://eprints.usm.my/48368/
http://eprints.usm.my/48368/1/THESIS-NABILAH%20ATIQAH%20ZUL%20cut.pdf