Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites

The as-prepared multiwalled carbon nanotubes (MWCNTs) consist of high impurities of amorphous carbon, metal catalysts and catalyst support that impeded the MWCNTs applications. The combination of the wet etchant (0.2 M sodium citrate, 0.2 M NTANa3 and 0.1 M NaOH, in the volumetric ratio of 2:2:1) wa...

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Main Author: Cheng, Yoke Kooi
Format: Thesis
Language:English
Published: 2012
Subjects:
Online Access:http://eprints.usm.my/43579/
http://eprints.usm.my/43579/1/Cheng%20Yoke%20Kooi24.pdf
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author Cheng, Yoke Kooi
author_facet Cheng, Yoke Kooi
author_sort Cheng, Yoke Kooi
building USM Institutional Repository
collection Online Access
description The as-prepared multiwalled carbon nanotubes (MWCNTs) consist of high impurities of amorphous carbon, metal catalysts and catalyst support that impeded the MWCNTs applications. The combination of the wet etchant (0.2 M sodium citrate, 0.2 M NTANa3 and 0.1 M NaOH, in the volumetric ratio of 2:2:1) was used to remove the amount of impurities of the raw MWCNTs. Treatment temperature was the key factor for the effectiveness of the wet etchant on the removal of residue but it was not affected by the reaction time. Alumina, the major impurity was reduced from 24.0 wt. % to 9.3 wt. % whereas cobalt and molybdenum were reduced from 9.6 wt. % to 4.4 wt. % and 2.3 wt. % to 0.6 wt. %, respectively at temperature of 138oC in wet etchant treatment. With the aid of the piranha solution treatment, further reduced the impurities; alumina to 6.7 wt. %, cobalt to 0.7 wt. % and molybdenum to 0.1 wt. %. Although MWCNTs able to act as fiber to enhance mechanical properties of the polymer but they are harmful to the living. Hence, The 3R conceptual idea is used to overcome the limitation of the MWCNTs. The chitosan/MWCNTs nanocomposites were prepared by solution processing method.
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institution Universiti Sains Malaysia
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language English
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publishDate 2012
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spelling usm-435792019-04-12T05:26:19Z http://eprints.usm.my/43579/ Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites Cheng, Yoke Kooi TP1-1185 Chemical technology The as-prepared multiwalled carbon nanotubes (MWCNTs) consist of high impurities of amorphous carbon, metal catalysts and catalyst support that impeded the MWCNTs applications. The combination of the wet etchant (0.2 M sodium citrate, 0.2 M NTANa3 and 0.1 M NaOH, in the volumetric ratio of 2:2:1) was used to remove the amount of impurities of the raw MWCNTs. Treatment temperature was the key factor for the effectiveness of the wet etchant on the removal of residue but it was not affected by the reaction time. Alumina, the major impurity was reduced from 24.0 wt. % to 9.3 wt. % whereas cobalt and molybdenum were reduced from 9.6 wt. % to 4.4 wt. % and 2.3 wt. % to 0.6 wt. %, respectively at temperature of 138oC in wet etchant treatment. With the aid of the piranha solution treatment, further reduced the impurities; alumina to 6.7 wt. %, cobalt to 0.7 wt. % and molybdenum to 0.1 wt. %. Although MWCNTs able to act as fiber to enhance mechanical properties of the polymer but they are harmful to the living. Hence, The 3R conceptual idea is used to overcome the limitation of the MWCNTs. The chitosan/MWCNTs nanocomposites were prepared by solution processing method. 2012-12 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/43579/1/Cheng%20Yoke%20Kooi24.pdf Cheng, Yoke Kooi (2012) Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites. Masters thesis, Universiti Sains Malaysia.
spellingShingle TP1-1185 Chemical technology
Cheng, Yoke Kooi
Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title_full Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title_fullStr Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title_full_unstemmed Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title_short Purification Of The Multiwalled Carbon Nanotubes (Mwcnts) And The Application Of The 3r (Reduce, Reuse And Recycle) Concept On The Chitosan/Mwcnts Nanocomposites
title_sort purification of the multiwalled carbon nanotubes (mwcnts) and the application of the 3r (reduce, reuse and recycle) concept on the chitosan/mwcnts nanocomposites
topic TP1-1185 Chemical technology
url http://eprints.usm.my/43579/
http://eprints.usm.my/43579/1/Cheng%20Yoke%20Kooi24.pdf