(E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate

(E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate

The asymmetric unit of the title hydrated salt, C22H25N2 +·C6H4ClO3S−·H2O, comprises two 2-[4-(di­ethyl­amino)­styr­yl]-1-methyl­quinolin-1-ium cations, two 4-chloro­benzene­sul­fon­ate anions and two solvent water mol­ecules. One ethyl group of both cations displays disorder over two positions in a...

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Main Authors: Chantrapromma, Suchada, Kaewmanee, Narissara, Boonnak, Nawong, Ching, Kheng Quah, Fun, Hoong Kun
Format: Article
Language:English
Published: International Union of Crystallography 2014
Subjects:
QC1-999 Physics
Online Access:http://eprints.usm.my/38795/
http://eprints.usm.my/38795/1/E%29-2-%5B4-%28Diethylamino%29styryl%5D-1-methylquinolin-1-ium.pdf
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author Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Ching, Kheng Quah
Fun, Hoong Kun
author_facet Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Ching, Kheng Quah
Fun, Hoong Kun
author_sort Chantrapromma, Suchada
building USM Institutional Repository
collection Online Access
description The asymmetric unit of the title hydrated salt, C22H25N2 +·C6H4ClO3S−·H2O, comprises two 2-[4-(di­ethyl­amino)­styr­yl]-1-methyl­quinolin-1-ium cations, two 4-chloro­benzene­sul­fon­ate anions and two solvent water mol­ecules. One ethyl group of both cations displays disorder over two positions in a 0.659 (2):0.341 (2) ratio in one mol­ecule and in a 0.501 (2):0.499 (2) ratio in the other. The sulfonate group of one anion is also disordered over two positions in a 0.893 (7):0.107 (7) ratio. The dihedral angle between the mean plane of the quinolinium ring system and that of benzene ring is 10.57 (18)° in one cation and 14.4 (2)° in the other. In the crystal, cations, anions and water mol­ecules are linked into chains along the [010] direction by O—H⋯Osulfonate hydrogen bonds, together with weak C—H⋯Osulfonate and C—H⋯Cl inter­actions. The cations are stacked by π–π inter­actions, with centroid–centroid distances in the range 3.675 (2)–4.162 (3) Å.
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institution Universiti Sains Malaysia
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language English
last_indexed 2025-11-15T17:33:24Z
publishDate 2014
publisher International Union of Crystallography
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spelling usm-387952018-02-12T08:20:38Z http://eprints.usm.my/38795/ (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate Chantrapromma, Suchada Kaewmanee, Narissara Boonnak, Nawong Ching, Kheng Quah Fun, Hoong Kun QC1-999 Physics The asymmetric unit of the title hydrated salt, C22H25N2 +·C6H4ClO3S−·H2O, comprises two 2-[4-(di­ethyl­amino)­styr­yl]-1-methyl­quinolin-1-ium cations, two 4-chloro­benzene­sul­fon­ate anions and two solvent water mol­ecules. One ethyl group of both cations displays disorder over two positions in a 0.659 (2):0.341 (2) ratio in one mol­ecule and in a 0.501 (2):0.499 (2) ratio in the other. The sulfonate group of one anion is also disordered over two positions in a 0.893 (7):0.107 (7) ratio. The dihedral angle between the mean plane of the quinolinium ring system and that of benzene ring is 10.57 (18)° in one cation and 14.4 (2)° in the other. In the crystal, cations, anions and water mol­ecules are linked into chains along the [010] direction by O—H⋯Osulfonate hydrogen bonds, together with weak C—H⋯Osulfonate and C—H⋯Cl inter­actions. The cations are stacked by π–π inter­actions, with centroid–centroid distances in the range 3.675 (2)–4.162 (3) Å. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38795/1/E%29-2-%5B4-%28Diethylamino%29styryl%5D-1-methylquinolin-1-ium.pdf Chantrapromma, Suchada and Kaewmanee, Narissara and Boonnak, Nawong and Ching, Kheng Quah and Fun, Hoong Kun (2014) (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 70 (4). 0395-0396. ISSN 1600-5368 https://doi.org/10.1107/S1600536814004577
spellingShingle QC1-999 Physics
Chantrapromma, Suchada
Kaewmanee, Narissara
Boonnak, Nawong
Ching, Kheng Quah
Fun, Hoong Kun
(E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title_full (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title_fullStr (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title_full_unstemmed (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title_short (E)-2-[4-(Diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
title_sort (e)-2-[4-(diethylamino)styryl]-1-methylquinolin- 1-ium 4-chlorobenzenesulfonate monohydrate
topic QC1-999 Physics
url http://eprints.usm.my/38795/
http://eprints.usm.my/38795/
http://eprints.usm.my/38795/1/E%29-2-%5B4-%28Diethylamino%29styryl%5D-1-methylquinolin-1-ium.pdf

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