Crystal structure of N-carbamothioyl-2- methylbenzamide
There are two molecules in the asymmetric unit of the title compound, C9H10N2OS. In one, the dihedral angle between the aromatic ring and the carbamothioyl group is 52.31 (7)� and in the other it is 36.16 (6)�. Each molecule features an intramolecular N—H� � �O hydrogen bond, which generates an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38594/ http://eprints.usm.my/38594/1/Crystal_structure_of_N-carbamothioyl-2-.pdf |
| _version_ | 1848878513468211200 |
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| author | Adam, Farook Ameram, Nadiah Wai, Mun Tan |
| author_facet | Adam, Farook Ameram, Nadiah Wai, Mun Tan |
| author_sort | Adam, Farook |
| building | USM Institutional Repository |
| collection | Online Access |
| description | There are two molecules in the asymmetric unit of the title
compound, C9H10N2OS. In one, the dihedral angle between
the aromatic ring and the carbamothioyl group is 52.31 (7)�
and in the other it is 36.16 (6)�. Each molecule features an
intramolecular N—H� � �O hydrogen bond, which generates an
S(6) ring and the O and S atoms have an anti disposition. In
the crystal, molecules are linked by N—H� � �S and N—H� � �O
hydrogen bonds, generating separate [130] and [130] infinite
chains. Weak C—H� � �O and C—H� � �S interactions are also
observed. |
| first_indexed | 2025-11-15T17:32:32Z |
| format | Article |
| id | usm-38594 |
| institution | Universiti Sains Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T17:32:32Z |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | usm-385942018-01-29T07:48:52Z http://eprints.usm.my/38594/ Crystal structure of N-carbamothioyl-2- methylbenzamide Adam, Farook Ameram, Nadiah Wai, Mun Tan QD1-999 Chemistry There are two molecules in the asymmetric unit of the title compound, C9H10N2OS. In one, the dihedral angle between the aromatic ring and the carbamothioyl group is 52.31 (7)� and in the other it is 36.16 (6)�. Each molecule features an intramolecular N—H� � �O hydrogen bond, which generates an S(6) ring and the O and S atoms have an anti disposition. In the crystal, molecules are linked by N—H� � �S and N—H� � �O hydrogen bonds, generating separate [130] and [130] infinite chains. Weak C—H� � �O and C—H� � �S interactions are also observed. International Union of Crystallography 2015 Article PeerReviewed application/pdf en http://eprints.usm.my/38594/1/Crystal_structure_of_N-carbamothioyl-2-.pdf Adam, Farook and Ameram, Nadiah and Wai, Mun Tan (2015) Crystal structure of N-carbamothioyl-2- methylbenzamide. Acta Crystallographica Section E: Crystallographic Communications, 71. 0425-0425. ISSN 2056-9890 https://doi.org/10.1107/S2056989015009585 |
| spellingShingle | QD1-999 Chemistry Adam, Farook Ameram, Nadiah Wai, Mun Tan Crystal structure of N-carbamothioyl-2- methylbenzamide |
| title | Crystal structure of N-carbamothioyl-2-
methylbenzamide |
| title_full | Crystal structure of N-carbamothioyl-2-
methylbenzamide |
| title_fullStr | Crystal structure of N-carbamothioyl-2-
methylbenzamide |
| title_full_unstemmed | Crystal structure of N-carbamothioyl-2-
methylbenzamide |
| title_short | Crystal structure of N-carbamothioyl-2-
methylbenzamide |
| title_sort | crystal structure of n-carbamothioyl-2-
methylbenzamide |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/38594/ http://eprints.usm.my/38594/ http://eprints.usm.my/38594/1/Crystal_structure_of_N-carbamothioyl-2-.pdf |