Crystal structure of N-carbamothioyl-2- methylbenzamide

There are two molecules in the asymmetric unit of the title compound, C9H10N2OS. In one, the dihedral angle between the aromatic ring and the carbamothioyl group is 52.31 (7)� and in the other it is 36.16 (6)�. Each molecule features an intramolecular N—H� � �O hydrogen bond, which generates an...

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Bibliographic Details
Main Authors: Adam, Farook, Ameram, Nadiah, Wai, Mun Tan
Format: Article
Language:English
Published: International Union of Crystallography 2015
Subjects:
Online Access:http://eprints.usm.my/38594/
http://eprints.usm.my/38594/1/Crystal_structure_of_N-carbamothioyl-2-.pdf
Description
Summary:There are two molecules in the asymmetric unit of the title compound, C9H10N2OS. In one, the dihedral angle between the aromatic ring and the carbamothioyl group is 52.31 (7)� and in the other it is 36.16 (6)�. Each molecule features an intramolecular N—H� � �O hydrogen bond, which generates an S(6) ring and the O and S atoms have an anti disposition. In the crystal, molecules are linked by N—H� � �S and N—H� � �O hydrogen bonds, generating separate [130] and [130] infinite chains. Weak C—H� � �O and C—H� � �S interactions are also observed.