Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)
The asymmetric unit of the title compound, [Ni(C15H14NO2)2], comprises an NiII cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The NiII cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schi...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014
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| Online Access: | http://eprints.usm.my/38591/ http://eprints.usm.my/38591/1/Crystal_structure_of_bis%7B2-%5B%28E%29-%284-methoxylbenzyl%29-.pdf |
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| author | Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Fun, Hoong Kun Chantrapromma, Suchada |
| author_facet | Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Fun, Hoong Kun Chantrapromma, Suchada |
| author_sort | Bahron, Hadariah |
| building | USM Institutional Repository |
| collection | Online Access |
| description | The asymmetric unit of the title compound, [Ni(C15H14NO2)2], comprises an NiII
cation, lying on an inversion centre, and a Schiff base anion that acts as a
bidentate ligand. The NiII cation is in a square-planar coordination environment
binding to the imine N and phenolate O atoms of the two Schiff base ligands.
The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and
Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) A ° , respectively. The plane of
the methoxybenzene ring makes a dihedral angle of 84.92 (6)� with that of the
phenolate ring. In the crystal, molecules are linked into screw chains by weak
C—H� � �O hydrogen bonds. Additional C—H� � �O hydrogen bonds, together
with C—H� � �� contacts, arrange the molecules into sheets parallel to the ac
plane. |
| first_indexed | 2025-11-15T17:32:31Z |
| format | Article |
| id | usm-38591 |
| institution | Universiti Sains Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T17:32:31Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | usm-385912018-01-29T04:34:14Z http://eprints.usm.my/38591/ Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II) Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Fun, Hoong Kun Chantrapromma, Suchada QC1-999 Physics The asymmetric unit of the title compound, [Ni(C15H14NO2)2], comprises an NiII cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The NiII cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) A ° , respectively. The plane of the methoxybenzene ring makes a dihedral angle of 84.92 (6)� with that of the phenolate ring. In the crystal, molecules are linked into screw chains by weak C—H� � �O hydrogen bonds. Additional C—H� � �O hydrogen bonds, together with C—H� � �� contacts, arrange the molecules into sheets parallel to the ac plane. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38591/1/Crystal_structure_of_bis%7B2-%5B%28E%29-%284-methoxylbenzyl%29-.pdf Bahron, Hadariah and Mohd Tajuddin, Amalina and Wan Ibrahim, Wan Nazihah and Fun, Hoong Kun and Chantrapromma, Suchada (2014) Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II). Acta Crystallographica Section E: Structure Reports Online, 70. pp. 104-106. ISSN 1600-5368 https://doi.org/10.1107/S160053681401650X |
| spellingShingle | QC1-999 Physics Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Fun, Hoong Kun Chantrapromma, Suchada Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II) |
| title | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2N,O1}nickel(II) |
| title_full | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2N,O1}nickel(II) |
| title_fullStr | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2N,O1}nickel(II) |
| title_full_unstemmed | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2N,O1}nickel(II) |
| title_short | Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2N,O1}nickel(II) |
| title_sort | crystal structure of bis{2-[(e)-(4-methoxylbenzyl)-
iminomethyl]phenolato-j2n,o1}nickel(ii) |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/38591/ http://eprints.usm.my/38591/ http://eprints.usm.my/38591/1/Crystal_structure_of_bis%7B2-%5B%28E%29-%284-methoxylbenzyl%29-.pdf |