Crystal structure of 4-({(1E,2E)-3-[3-(4-fluorophenyl)- 1-isopropyl-1H-indol-2-yl]allylidene}amino)-5- methyl-1H-1,2,4-triazole-5(4H)-thione
The title compound, C23H22FN5S, exists in a trans conformation with respect to the methene C C and the acyclic N C bonds. The 1,2,4-triazole-5(4H)-thione ring makes dihedral angles of 88.66 (9) and 84.51 (10)�, respectively, with the indole and benzene rings. In the crystal, molecules are linked...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38586/ http://eprints.usm.my/38586/1/Crystal_structure_of_4-%28%7B%281E%2C2E%29-3-%5B3-%284-fluorophenyl%29-1-isopropyl-1H-indol-2-yl%5Dallylidene%7Damino%29-5-.pdf |
| Summary: | The title compound, C23H22FN5S, exists in a trans conformation with respect to
the methene C C and the acyclic N C bonds. The 1,2,4-triazole-5(4H)-thione
ring makes dihedral angles of 88.66 (9) and 84.51 (10)�, respectively, with the
indole and benzene rings. In the crystal, molecules are linked by pairs of N—
H� � �S hydrogen bonds, forming inversion dimers with an R2
2(8) ring motif. The
dimers are linked via C—H� � �� interactions, forming chains along [110]. The
chains are linked via �—� interactions involving inversion-related triazole rings
[centroid–centroid distance = 3.4340 (13) A ° ], forming layers parallel to the ab
plane. |
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