Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38405/ http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf |
| _version_ | 1848878460170141696 |
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| author | Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Suchada, Chantrapromma Fun, Hoong Kun |
| author_facet | Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Suchada, Chantrapromma Fun, Hoong Kun |
| author_sort | Bahron, Hadariah |
| building | USM Institutional Repository |
| collection | Online Access |
| description | In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation
lies on an inversion center. One Cl atom of the CHCl3 solvent
molecule lies on a twofold axis and the C—H group is
disordered with equal occupancies about this axis with the
other Cl atom in a general position with full occupancy. The
PdII cation is four-coordinate and adopts a square-planar
geometry via coordination of the imine N and phenolic O
atoms of the two bidentate Schiff base anions. The N and O
atoms of these ligands are mutually trans. The plane of the
benzene ring makes a dihedral angle of 73.52 (10)� with that of
the methoxyphenolate ring. In the crystal, molecules of the
PdII complex are arranged into sheets parallel to the ac plane,
and the chloroform solvent molecules are located in the
interstitial areas between the complex molecules. Weak
intermolecular C—H� � �O and C—H� � �� interactions stabilize
the packing. |
| first_indexed | 2025-11-15T17:31:41Z |
| format | Article |
| id | usm-38405 |
| institution | Universiti Sains Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T17:31:41Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | usm-384052018-01-17T04:35:59Z http://eprints.usm.my/38405/ Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Suchada, Chantrapromma Fun, Hoong Kun QC1-999 Physics In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The PdII cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)� with that of the methoxyphenolate ring. In the crystal, molecules of the PdII complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H� � �O and C—H� � �� interactions stabilize the packing. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf Bahron, Hadariah and Mohd Tajuddin, Amalina and Wan Ibrahim, Wan Nazihah and Suchada, Chantrapromma and Fun, Hoong Kun (2014) Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 2014 (70). pp. 289-290. ISSN 1600-5368 https://doi.org/10.1107/S1600536814015025 |
| spellingShingle | QC1-999 Physics Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Suchada, Chantrapromma Fun, Hoong Kun Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title_full | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title_fullStr | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title_full_unstemmed | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title_short | Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate |
| title_sort | bis{2-methoxy-6-[(e)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(ii) chloroform monosolvate |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/38405/ http://eprints.usm.my/38405/ http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf |