A Heterobimetallic 2-D Coordination Polymer [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (2pyCOO
A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI
2016
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38027/ http://eprints.usm.my/38027/1/A_Heterobimetallic_2-D_Coordination_Polymer_%5BNa2%28Cu2I2%282pyCOO%294%29.pdf |
| Summary: | A heterobimetallic 2-D coordination polymer, [Na2(Cu2I2(2pyCOO)4)(H2O)4]n (1) (2pyCOO=picolinate) was synthesized and characterized. The complex was also structurally characterized using single X-ray diffraction studies that revealed the complex 1 having a vertex symbol of 4.82 which corresponds to fes topology. Together with hydrogen bonds and interdigitating n...n interactions, these thus facilitate the formation of 3-D supramolecular network. The nitrogen gas absorption amount of 1 at 77 K shows a small volume of N2 sorption isotherm with a small Langmuir and a Brunauer-Emmett-Teller (BET) surface area indicating that the heterobimetallic 3-D supramolecular of 1 exhibits a very weak ability of adsorbing gas. |
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