2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene
The asymmetric unit of the title salt, C36H32N2 2+�- 2C6H4ClO3S�, consists of one anion and one half-cation, the other half being generated by inversion symmetry. The dihedral angle between the pyridinium ring and the napthalene ring system in the asymmetric unit is 42.86 (6)�. In the crystal,...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/37939/ http://eprints.usm.my/37939/1/2%2C2%27-%5B2%2C4-Bis%28naphthalen-1-yl%29cyclobutane-1%2C3-diyl%5Dbis%281-methylpyridinium%29.pdf |
| _version_ | 1848878328699682816 |
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| author | Chantrapromma, Suchada Chanawanno, Kullapa Boonnak, Nawong Hoong, Kun Fun |
| author_facet | Chantrapromma, Suchada Chanawanno, Kullapa Boonnak, Nawong Hoong, Kun Fun |
| author_sort | Chantrapromma, Suchada |
| building | USM Institutional Repository |
| collection | Online Access |
| description | The asymmetric unit of the title salt, C36H32N2
2+�-
2C6H4ClO3S�, consists of one anion and one half-cation, the
other half being generated by inversion symmetry. The
dihedral angle between the pyridinium ring and the napthalene
ring system in the asymmetric unit is 42.86 (6)�. In the
crystal, cations and anions are linked by weak C—H...O
interactions into chains along [010]. Adjacent chains are
further arranged in an antiparallel manner into sheets parallel
to the bc plane. �–� interactions are observed involving the
cations, with centroid–centroid distances of 3.7664 (8) and
3.8553 (8) A ° . |
| first_indexed | 2025-11-15T17:29:36Z |
| format | Article |
| id | usm-37939 |
| institution | Universiti Sains Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T17:29:36Z |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | usm-379392017-12-15T08:24:39Z http://eprints.usm.my/37939/ 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene Chantrapromma, Suchada Chanawanno, Kullapa Boonnak, Nawong Hoong, Kun Fun QC1-999 Physics The asymmetric unit of the title salt, C36H32N2 2+�- 2C6H4ClO3S�, consists of one anion and one half-cation, the other half being generated by inversion symmetry. The dihedral angle between the pyridinium ring and the napthalene ring system in the asymmetric unit is 42.86 (6)�. In the crystal, cations and anions are linked by weak C—H...O interactions into chains along [010]. Adjacent chains are further arranged in an antiparallel manner into sheets parallel to the bc plane. �–� interactions are observed involving the cations, with centroid–centroid distances of 3.7664 (8) and 3.8553 (8) A ° . International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/37939/1/2%2C2%27-%5B2%2C4-Bis%28naphthalen-1-yl%29cyclobutane-1%2C3-diyl%5Dbis%281-methylpyridinium%29.pdf Chantrapromma, Suchada and Chanawanno, Kullapa and Boonnak, Nawong and Hoong, Kun Fun (2014) 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene. Acta Crystallographica Section E, 2014 (70). 0510-0519. ISSN 1600-5368 https://doi.org/10.1107/S160053681400645X |
| spellingShingle | QC1-999 Physics Chantrapromma, Suchada Chanawanno, Kullapa Boonnak, Nawong Hoong, Kun Fun 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane- 1,3-diyl]bis(1-methylpyridinium) bis(4-chlorobenzenesulfonate): thermalinduced [2 + 2] cycloaddition reaction of a heterostilbene |
| title | 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| title_full | 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| title_fullStr | 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| title_full_unstemmed | 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| title_short | 2,2'-[2,4-Bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| title_sort | 2,2'-[2,4-bis(naphthalen-1-yl)cyclobutane-
1,3-diyl]bis(1-methylpyridinium)
bis(4-chlorobenzenesulfonate): thermalinduced
[2 + 2] cycloaddition reaction of
a heterostilbene |
| topic | QC1-999 Physics |
| url | http://eprints.usm.my/37939/ http://eprints.usm.my/37939/ http://eprints.usm.my/37939/1/2%2C2%27-%5B2%2C4-Bis%28naphthalen-1-yl%29cyclobutane-1%2C3-diyl%5Dbis%281-methylpyridinium%29.pdf |