1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)

“Oxazepine” refers to any seven-membered ring containing an oxygen and nitrogen atom. The 1,3-oxazepine is a branch of many types of the heterocyclic oxazepine [1–7]. The core structure of 1,3-oxazepane-4,7diones consists of a sevenmemebred ring along with two carbonyl group. Over the years, th...

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Main Authors: Abdul Karim , Talaq Mohammad, Osman, Hasnah, Guan, Yeow Yeap
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2011
Subjects:
Online Access:http://eprints.usm.my/37934/
http://eprints.usm.my/37934/1/1%2C3-Oxazepane-4%2C7-Diones_Compounds.pdf
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author Abdul Karim , Talaq Mohammad
Osman, Hasnah
Guan, Yeow Yeap
author_facet Abdul Karim , Talaq Mohammad
Osman, Hasnah
Guan, Yeow Yeap
author_sort Abdul Karim , Talaq Mohammad
building USM Institutional Repository
collection Online Access
description “Oxazepine” refers to any seven-membered ring containing an oxygen and nitrogen atom. The 1,3-oxazepine is a branch of many types of the heterocyclic oxazepine [1–7]. The core structure of 1,3-oxazepane-4,7diones consists of a sevenmemebred ring along with two carbonyl group. Over the years, the syntheses of oxazepine derivatives have been investigated and documented. The result is important of heterocyclic compounds having significant biological uses [8– 13]. Recently, we prepared a variety of 1,3-oxazepinediones in order to study the spectroscopic and liquid crystal properties [14]. In this paper, we present the structural elucidation by 1D and 2D NMR experiments of 3-alkyl- 2-(3-hydroxyphenyl)-1,3-oxazepane-4,7-diones with general formula(HOC6H4)CONCnH2n+1CH-CH(CO)2 (where n = 2, 4, 6, 8, 10, 12, 14, 16, and 18). Here, the hydroxyphenyl and the terminal alkyl chain are attached to the oxazepane ring.
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spelling usm-379342017-12-15T02:33:40Z http://eprints.usm.my/37934/ 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D) Abdul Karim , Talaq Mohammad Osman, Hasnah Guan, Yeow Yeap QD1-999 Chemistry “Oxazepine” refers to any seven-membered ring containing an oxygen and nitrogen atom. The 1,3-oxazepine is a branch of many types of the heterocyclic oxazepine [1–7]. The core structure of 1,3-oxazepane-4,7diones consists of a sevenmemebred ring along with two carbonyl group. Over the years, the syntheses of oxazepine derivatives have been investigated and documented. The result is important of heterocyclic compounds having significant biological uses [8– 13]. Recently, we prepared a variety of 1,3-oxazepinediones in order to study the spectroscopic and liquid crystal properties [14]. In this paper, we present the structural elucidation by 1D and 2D NMR experiments of 3-alkyl- 2-(3-hydroxyphenyl)-1,3-oxazepane-4,7-diones with general formula(HOC6H4)CONCnH2n+1CH-CH(CO)2 (where n = 2, 4, 6, 8, 10, 12, 14, 16, and 18). Here, the hydroxyphenyl and the terminal alkyl chain are attached to the oxazepane ring. Hindawi Publishing Corporation 2011 Article PeerReviewed application/pdf en http://eprints.usm.my/37934/1/1%2C3-Oxazepane-4%2C7-Diones_Compounds.pdf Abdul Karim , Talaq Mohammad and Osman, Hasnah and Guan, Yeow Yeap (2011) 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D). International Journal of Spectroscopy, 2011 (945216). pp. 1-7. ISSN 1687-9449 http://dx.doi.org/10.1155/2011/945216
spellingShingle QD1-999 Chemistry
Abdul Karim , Talaq Mohammad
Osman, Hasnah
Guan, Yeow Yeap
1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title_full 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title_fullStr 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title_full_unstemmed 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title_short 1,3-Oxazepane-4,7-Diones Compounds: 1Hand 13CNMR High-Resolution Spectroscopy (1D and 2D)
title_sort 1,3-oxazepane-4,7-diones compounds: 1hand 13cnmr high-resolution spectroscopy (1d and 2d)
topic QD1-999 Chemistry
url http://eprints.usm.my/37934/
http://eprints.usm.my/37934/
http://eprints.usm.my/37934/1/1%2C3-Oxazepane-4%2C7-Diones_Compounds.pdf