Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films

This paper demonstrated the applicability of electrospun P(3HB) film as a dye adsorbent agent.Malachite green (MG) was used as the model dye in this study. Interestingly, the electrospun P(3HB) film exhibited excellent dye adsorption capacity whereby 78% of dye was adsorbed from a 30 μMsolution of...

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Main Authors: Nanthini Sridewi, Nanthini Sridewi, Lee, Yan Fen, Sudesh, Kumar
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2011
Subjects:
Online Access:http://eprints.usm.my/37291/
http://eprints.usm.my/37291/1/Simultaneous_Adsorption_and_Photocatalytic.pdf
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author Nanthini Sridewi, Nanthini Sridewi
Lee, Yan Fen
Sudesh, Kumar
author_facet Nanthini Sridewi, Nanthini Sridewi
Lee, Yan Fen
Sudesh, Kumar
author_sort Nanthini Sridewi, Nanthini Sridewi
building USM Institutional Repository
collection Online Access
description This paper demonstrated the applicability of electrospun P(3HB) film as a dye adsorbent agent.Malachite green (MG) was used as the model dye in this study. Interestingly, the electrospun P(3HB) film exhibited excellent dye adsorption capacity whereby 78% of dye was adsorbed from a 30 μMsolution ofMG. The film was further improvised by incorporating titanium dioxide photocatalysts to form a dual dye treatment system employing adsorption and photocatalytic degradation techniques. The resultant electrospun P(3HB)-50wt% TiO2 was capable of completely decolorizingMGin 45 min under solar irradiation, which corresponded to 58.7% COD removal. The fully decolorizedMG solution also proved to be nontoxic against A. aegypti mosquito larvae. The reapplicability of this film was possible as it induced a decolorization rate of 98% or more at every usage for ten consequent usages. EDX analysis suggested that there were no significant changes in the concentration of titanium (Ti) in the film before and after ten times of usage. The concentration of Ti in cast P(3HB)-50wt%TiO2 film was found to decrease significantly during the repeated usage. The electrospun P(3HB)-50wt%TiO2 film has high potency as an efficient and inexpensive yet simple method for the dye effluent decolorization, degradation, and detoxification.
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spelling usm-372912017-10-31T08:15:11Z http://eprints.usm.my/37291/ Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films Nanthini Sridewi, Nanthini Sridewi Lee, Yan Fen Sudesh, Kumar QH1 Natural history (General - Including nature conservation, geographical distribution) This paper demonstrated the applicability of electrospun P(3HB) film as a dye adsorbent agent.Malachite green (MG) was used as the model dye in this study. Interestingly, the electrospun P(3HB) film exhibited excellent dye adsorption capacity whereby 78% of dye was adsorbed from a 30 μMsolution ofMG. The film was further improvised by incorporating titanium dioxide photocatalysts to form a dual dye treatment system employing adsorption and photocatalytic degradation techniques. The resultant electrospun P(3HB)-50wt% TiO2 was capable of completely decolorizingMGin 45 min under solar irradiation, which corresponded to 58.7% COD removal. The fully decolorizedMG solution also proved to be nontoxic against A. aegypti mosquito larvae. The reapplicability of this film was possible as it induced a decolorization rate of 98% or more at every usage for ten consequent usages. EDX analysis suggested that there were no significant changes in the concentration of titanium (Ti) in the film before and after ten times of usage. The concentration of Ti in cast P(3HB)-50wt%TiO2 film was found to decrease significantly during the repeated usage. The electrospun P(3HB)-50wt%TiO2 film has high potency as an efficient and inexpensive yet simple method for the dye effluent decolorization, degradation, and detoxification. Hindawi Publishing Corporation 2011 Article PeerReviewed application/pdf en http://eprints.usm.my/37291/1/Simultaneous_Adsorption_and_Photocatalytic.pdf Nanthini Sridewi, Nanthini Sridewi and Lee, Yan Fen and Sudesh, Kumar (2011) Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films. International Journal of Photoenergy, 2011 (59785). pp. 1-11. ISSN 1110-662X http://dx.doi.org/10.1155/2011/597854
spellingShingle QH1 Natural history (General - Including nature conservation, geographical distribution)
Nanthini Sridewi, Nanthini Sridewi
Lee, Yan Fen
Sudesh, Kumar
Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title_full Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title_fullStr Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title_full_unstemmed Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title_short Simultaneous Adsorption and Photocatalytic Degradation of Malachite Green Using Electrospun P(3HB)-TiO2 Nanocomposite Fibers and Films
title_sort simultaneous adsorption and photocatalytic degradation of malachite green using electrospun p(3hb)-tio2 nanocomposite fibers and films
topic QH1 Natural history (General - Including nature conservation, geographical distribution)
url http://eprints.usm.my/37291/
http://eprints.usm.my/37291/
http://eprints.usm.my/37291/1/Simultaneous_Adsorption_and_Photocatalytic.pdf