A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.

Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesiz...

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Main Author: S.M Anwarul Haque, Rosenani
Format: Monograph
Language:English
Published: Universiti Sains Malaysia 2015
Subjects:
Online Access:http://eprints.usm.my/36945/
http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf
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author S.M Anwarul Haque, Rosenani
author_facet S.M Anwarul Haque, Rosenani
author_sort S.M Anwarul Haque, Rosenani
building USM Institutional Repository
collection Online Access
description Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesized compounds were characterized by various spectroscopic and analytical techniques. X-ray crystallographic technique was used to determine the structural orientations of the molecules. The compounds were tested for possible biological and catalytic behavior. Silver(l) and palladium(lI) complexes showed excellent antibacterial and anticancer results.
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spelling usm-369452022-12-14T02:06:38Z http://eprints.usm.my/36945/ A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. S.M Anwarul Haque, Rosenani QD1-999 Chemistry Novel silver(I)- and Mercury(II)-N-Heterocyclic Carbene (NHC) Complexes of pincer ligands were successfully synthesized in good yields. The prepared complexes were then used for the transmetallation reactions to synthesize the required Nickel(II)- and Palladium(II)-NHC complexes. All the synthesized compounds were characterized by various spectroscopic and analytical techniques. X-ray crystallographic technique was used to determine the structural orientations of the molecules. The compounds were tested for possible biological and catalytic behavior. Silver(l) and palladium(lI) complexes showed excellent antibacterial and anticancer results. Universiti Sains Malaysia 2015 Monograph NonPeerReviewed application/pdf en http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf S.M Anwarul Haque, Rosenani (2015) A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies. Technical Report. Universiti Sains Malaysia.
spellingShingle QD1-999 Chemistry
S.M Anwarul Haque, Rosenani
A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title_full A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title_fullStr A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title_full_unstemmed A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title_short A green approach towards synthesis and characterization of Ni(II)- and Pd(II)-N- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
title_sort green approach towards synthesis and characterization of ni(ii)- and pd(ii)-n- heterocyclic carbene complexes of pincer ligands: their application in catalytic olefin oxidation studies.
topic QD1-999 Chemistry
url http://eprints.usm.my/36945/
http://eprints.usm.my/36945/1/216e%20A%20green%20approach%20towards%20synthesis%20and%20characterization%20of%20Ni%28II%29-%20and%20Pd%28II%29-N-%20heterocyclic%20carbene%20complexes%20of%20pincer%20ligands%20their%20application%20in%20catalytic%20olefin%20oxidation%20studies..pdf