(E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide
In the title compound, C 14 H 18 ClN 3 OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E . In the crystal, molecules are linked by N—H...O an...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017
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| Subjects: | |
| Online Access: | http://eprints.usm.my/36908/ http://eprints.usm.my/36908/1/%28E-2-%285-Chloro-2-hydroxybenzylidene%29__su4104.pdf |
| _version_ | 1848878043620179968 |
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| author | Arafath, Md. Azharul Adam, Farook Razali, Mohd Rizal |
| author_facet | Arafath, Md. Azharul Adam, Farook Razali, Mohd Rizal |
| author_sort | Arafath, Md. Azharul |
| building | USM Institutional Repository |
| collection | Online Access |
| description | In the title compound, C 14 H 18 ClN 3 OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E . In the crystal, molecules are linked by N—H...O and O—H...S hydrogen bonds, forming inversion dimers with an R2² (14) ring motif flanked by two R2² (6) ring motifs. The dimers are linked by short Cl...Cl interactions, forming layers parallel to the ab plane.
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| first_indexed | 2025-11-15T17:25:04Z |
| format | Article |
| id | usm-36908 |
| institution | Universiti Sains Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T17:25:04Z |
| publishDate | 2017 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | usm-369082017-10-03T09:56:10Z http://eprints.usm.my/36908/ (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide Arafath, Md. Azharul Adam, Farook Razali, Mohd Rizal QD1-999 Chemistry In the title compound, C 14 H 18 ClN 3 OS, the phenol ring is almost coplanar with the hydrazinecarbothioamide moiety, making a dihedral angle of 6.92 (8)°. The cyclohexane ring has a chair conformation and the conformation about the C=N bond is E . In the crystal, molecules are linked by N—H...O and O—H...S hydrogen bonds, forming inversion dimers with an R2² (14) ring motif flanked by two R2² (6) ring motifs. The dimers are linked by short Cl...Cl interactions, forming layers parallel to the ab plane. International Union of Crystallography 2017-01 Article PeerReviewed application/pdf en http://eprints.usm.my/36908/1/%28E-2-%285-Chloro-2-hydroxybenzylidene%29__su4104.pdf Arafath, Md. Azharul and Adam, Farook and Razali, Mohd Rizal (2017) (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide. IUCrData , 2 (1). pp. 1-3. ISSN 2414-3146 https://doi.org/10.1107/S2414314616019970 |
| spellingShingle | QD1-999 Chemistry Arafath, Md. Azharul Adam, Farook Razali, Mohd Rizal (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine- 1-carbothioamide |
| title | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_full | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_fullStr | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_full_unstemmed | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_short | (E)-2-(5-Chloro-2-hydroxybenzylidene)-N-cyclohexylhydrazine-
1-carbothioamide |
| title_sort | (e)-2-(5-chloro-2-hydroxybenzylidene)-n-cyclohexylhydrazine-
1-carbothioamide |
| topic | QD1-999 Chemistry |
| url | http://eprints.usm.my/36908/ http://eprints.usm.my/36908/ http://eprints.usm.my/36908/1/%28E-2-%285-Chloro-2-hydroxybenzylidene%29__su4104.pdf |