(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis

In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via pair...

Full description

Bibliographic Details
Main Authors:	Abdullah, Amzar Ahlami, Hassan, Nur Hafiq Hanif, Arshad, Suhana, Che Khalib, Nuridayanti, Razak, Ibrahim Abdul
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016
Subjects:	QC1-999 Physics
Online Access:	http://eprints.usm.my/36907/ http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf

_version_	1848878043308752896
author	Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Che Khalib, Nuridayanti Razak, Ibrahim Abdul
author_facet	Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Che Khalib, Nuridayanti Razak, Ibrahim Abdul
author_sort	Abdullah, Amzar Ahlami
building	USM Institutional Repository
collection	Online Access
description	In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π interactions. Hirshfeld surface analysis was used to confirm the existence of intermolecular interactions.
first_indexed	2025-11-15T17:25:04Z
format	Article
id	usm-36907
institution	Universiti Sains Malaysia
institution_category	Local University
language	English
last_indexed	2025-11-15T17:25:04Z
publishDate	2016
publisher	International Union of Crystallography
recordtype	eprints
repository_type	Digital Repository
spelling	usm-369072018-08-15T04:19:01Z http://eprints.usm.my/36907/ (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Che Khalib, Nuridayanti Razak, Ibrahim Abdul QC1-999 Physics In the title compound, C23H14ClFO, the enone moiety adopts an E conformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H⋯F hydrogen bond generates an S(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimers via pairs of C—H⋯F hydrogen bonds. The crystal structure also features C—H⋯π and π–π interactions. Hirshfeld surface analysis was used to confirm the existence of intermolecular interactions. International Union of Crystallography 2016-05 Article PeerReviewed application/pdf en http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf Abdullah, Amzar Ahlami and Hassan, Nur Hafiq Hanif and Arshad, Suhana and Che Khalib, Nuridayanti and Razak, Ibrahim Abdul (2016) (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E: Crystallographic Communications, 72 (5). pp. 648-651. ISSN 2056-9890 https://doi.org/10.1107/S2056989016005028
spellingShingle	QC1-999 Physics Abdullah, Amzar Ahlami Hassan, Nur Hafiq Hanif Arshad, Suhana Che Khalib, Nuridayanti Razak, Ibrahim Abdul (E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title	(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_full	(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_fullStr	(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_full_unstemmed	(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_short	(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis
title_sort	(e)-1-(anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and hirshfeld surface analysis
topic	QC1-999 Physics
url	http://eprints.usm.my/36907/ http://eprints.usm.my/36907/ http://eprints.usm.my/36907/1/%28E-1-%28Anthracen-9-yl%29-3-%282-chloro-6-fluoro%C2%ADphen%C2%ADyl%29_hb7569.pdf

(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)- prop-2-en-1-one: crystal structure and Hirshfeld surface analysis

Similar Items