6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)

6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)

In the title molecular salt, C5H9N4 + C13H10NO2 C5H8N4, the asymmetric unit consists of a 6-amino-3,4-dimethyl-1,2,4-triazin-1-ium cation, a 2-anilinobenzoate anion and a neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecule. The typical intramolecular NH—O hydrogen bond is observed in the 2-anilin...

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Main Authors: Sangeetha, Ramalingam, Balasubramani, Kasthuri, Thanigaimani, Kaliyaperumal, Razak, Ibrahim Abdul
Format: Article
Language:English
Published: International Union of Crystallography 2017
Subjects:
QC Physics
Online Access:http://eprints.usm.my/36671/
http://eprints.usm.my/36671/1/%286-Amino-3%2C%29_su4153.pdf
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author Sangeetha, Ramalingam
Balasubramani, Kasthuri
Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
author_facet Sangeetha, Ramalingam
Balasubramani, Kasthuri
Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
author_sort Sangeetha, Ramalingam
building USM Institutional Repository
collection Online Access
description In the title molecular salt, C5H9N4 + C13H10NO2 C5H8N4, the asymmetric unit consists of a 6-amino-3,4-dimethyl-1,2,4-triazin-1-ium cation, a 2-anilinobenzoate anion and a neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecule. The typical intramolecular NH—O hydrogen bond is observed in the 2-anilinobenzoate anion. In the crystal, the protonated N atom and the 3-amino group are hydrogen bonded to the carboxylate oxygen atoms via a pair of N—HO hydrogen bonds, forming an R2 2 (8) ring motif. These motifs are further linked with adjacent neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecules by N—HO and N—HN hydrogen bonds to produce centrosymmetric sixmembered units, enclosing R2 2(8) and R3 4(9) ring motifs. They are reinforced by a C—HN hydrogen bond and stack up the b-axis direction.
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institution Universiti Sains Malaysia
institution_category Local University
language English
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publishDate 2017
publisher International Union of Crystallography
recordtype eprints
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spelling usm-366712018-08-15T04:11:32Z http://eprints.usm.my/36671/ 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1) Sangeetha, Ramalingam Balasubramani, Kasthuri Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul QC Physics In the title molecular salt, C5H9N4 + C13H10NO2 C5H8N4, the asymmetric unit consists of a 6-amino-3,4-dimethyl-1,2,4-triazin-1-ium cation, a 2-anilinobenzoate anion and a neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecule. The typical intramolecular NH—O hydrogen bond is observed in the 2-anilinobenzoate anion. In the crystal, the protonated N atom and the 3-amino group are hydrogen bonded to the carboxylate oxygen atoms via a pair of N—HO hydrogen bonds, forming an R2 2 (8) ring motif. These motifs are further linked with adjacent neutral 3-amino-5,6-dimethyl-1,2,4-triazine molecules by N—HO and N—HN hydrogen bonds to produce centrosymmetric sixmembered units, enclosing R2 2(8) and R3 4(9) ring motifs. They are reinforced by a C—HN hydrogen bond and stack up the b-axis direction. International Union of Crystallography 2017 Article PeerReviewed application/pdf en http://eprints.usm.my/36671/1/%286-Amino-3%2C%29_su4153.pdf Sangeetha, Ramalingam and Balasubramani, Kasthuri and Thanigaimani, Kaliyaperumal and Razak, Ibrahim Abdul (2017) 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1). IUCrData, 2 (x17082). pp. 1-9. ISSN 2414-3146 https://doi.org/10.1107/S241431461700829X
spellingShingle QC Physics
Sangeetha, Ramalingam
Balasubramani, Kasthuri
Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title_full 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title_fullStr 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title_full_unstemmed 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title_short 6-Amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
title_sort 6-amino-3,4-dimethyl-1,2,4-triazin-1-ium 2-anilinobenzoate–3-amino-5,6-dimethyl-1,2,4- triazine (1/1)
topic QC Physics
url http://eprints.usm.my/36671/
http://eprints.usm.my/36671/
http://eprints.usm.my/36671/1/%286-Amino-3%2C%29_su4153.pdf

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