Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review

Over the past decades, imidazolium-based ionic liquids (ILs) have been studied extensively in numerous previous experimental and analysis works to produce ILs with tunable physicochemical properties. Imidazolium-based ILs is one of the most studied ionic liquid in the literature, and the number of p...

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Main Authors: Noorhisham, Nur Athirah, Amri, Deana, Mohamed, Ahmad Husaini, Yahaya, Noorfatimah, Ahmad, Nor Monica, Mohamad, Sharifah, Kamaruzaman, Sazlinda, Osman, Hasnah
Format: Article
Published: Elsevier 2021
Online Access:http://psasir.upm.edu.my/id/eprint/96343/
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author Noorhisham, Nur Athirah
Amri, Deana
Mohamed, Ahmad Husaini
Yahaya, Noorfatimah
Ahmad, Nor Monica
Mohamad, Sharifah
Kamaruzaman, Sazlinda
Osman, Hasnah
author_facet Noorhisham, Nur Athirah
Amri, Deana
Mohamed, Ahmad Husaini
Yahaya, Noorfatimah
Ahmad, Nor Monica
Mohamad, Sharifah
Kamaruzaman, Sazlinda
Osman, Hasnah
author_sort Noorhisham, Nur Athirah
building UPM Institutional Repository
collection Online Access
description Over the past decades, imidazolium-based ionic liquids (ILs) have been studied extensively in numerous previous experimental and analysis works to produce ILs with tunable physicochemical properties. Imidazolium-based ILs is one of the most studied ionic liquid in the literature, and the number of published papers related to ILs have also been rising exponentially. It can be used in polymer synthesis due to its intrinsically low viscosity, low melting points, simplicity of preparation, and high stability toward oxidative and reductive conditions. However, very limited information on characterisation of imidazolium-based ILs was available in the literature. Thus, this paper provides a comprehensive review of the characterisation analysis of imidazolium-based ILs. The characterisation of imidazolium-based ILs via spectrochemical methods (FTIR, 1H and 13C NMR, and UV-Vis), CHNSO elemental analysis, thermal stability analysis (TGA and DSC) and crystallinity analysis using XRD were thoroughly discussed herein. Moreover, this review also presents the cutting-edge-knowledge of different synthesis method of imidazolium-based ILs and its potential applications in polymer preparation.
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institution Universiti Putra Malaysia
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publishDate 2021
publisher Elsevier
recordtype eprints
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spelling upm-963432023-01-30T06:52:07Z http://psasir.upm.edu.my/id/eprint/96343/ Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review Noorhisham, Nur Athirah Amri, Deana Mohamed, Ahmad Husaini Yahaya, Noorfatimah Ahmad, Nor Monica Mohamad, Sharifah Kamaruzaman, Sazlinda Osman, Hasnah Over the past decades, imidazolium-based ionic liquids (ILs) have been studied extensively in numerous previous experimental and analysis works to produce ILs with tunable physicochemical properties. Imidazolium-based ILs is one of the most studied ionic liquid in the literature, and the number of published papers related to ILs have also been rising exponentially. It can be used in polymer synthesis due to its intrinsically low viscosity, low melting points, simplicity of preparation, and high stability toward oxidative and reductive conditions. However, very limited information on characterisation of imidazolium-based ILs was available in the literature. Thus, this paper provides a comprehensive review of the characterisation analysis of imidazolium-based ILs. The characterisation of imidazolium-based ILs via spectrochemical methods (FTIR, 1H and 13C NMR, and UV-Vis), CHNSO elemental analysis, thermal stability analysis (TGA and DSC) and crystallinity analysis using XRD were thoroughly discussed herein. Moreover, this review also presents the cutting-edge-knowledge of different synthesis method of imidazolium-based ILs and its potential applications in polymer preparation. Elsevier 2021 Article PeerReviewed Noorhisham, Nur Athirah and Amri, Deana and Mohamed, Ahmad Husaini and Yahaya, Noorfatimah and Ahmad, Nor Monica and Mohamad, Sharifah and Kamaruzaman, Sazlinda and Osman, Hasnah (2021) Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review. Journal of Molecular Liquids, 326. art. no. 115340. pp. 1-24. ISSN 0167-7322; ESSN: 1873-3166 https://www.sciencedirect.com/science/article/pii/S0167732221000660 10.1016/j.molliq.2021.115340
spellingShingle Noorhisham, Nur Athirah
Amri, Deana
Mohamed, Ahmad Husaini
Yahaya, Noorfatimah
Ahmad, Nor Monica
Mohamad, Sharifah
Kamaruzaman, Sazlinda
Osman, Hasnah
Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title_full Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title_fullStr Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title_full_unstemmed Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title_short Characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
title_sort characterisation techniques for analysis of imidazolium-based ionic liquids and application in polymer preparation: a review
url http://psasir.upm.edu.my/id/eprint/96343/
http://psasir.upm.edu.my/id/eprint/96343/
http://psasir.upm.edu.my/id/eprint/96343/