Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials

Arecanut husk (AH) was selected as a material for silica replacement in the synthesis process of glass-ceramics zinc silicate and also the fact that it has no traditional use and often being dumped and results in environmental issues. The process of pyrolysis was carried out at temperature 700 °C an...

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Main Authors: Anuar, Muhammad Fahmi, Yap, Wing Fen, Azizan, Muhammad Zakwan, Rahmat, Fida’i, Mohd Zaid, Mohd Hafiz, Mohamed Khaidir, Rahayu Emilia, Sheh Omar, Nur Alia
Format: Article
Published: MDPI AG 2021
Online Access:http://psasir.upm.edu.my/id/eprint/95235/
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author Anuar, Muhammad Fahmi
Yap, Wing Fen
Azizan, Muhammad Zakwan
Rahmat, Fida’i
Mohd Zaid, Mohd Hafiz
Mohamed Khaidir, Rahayu Emilia
Sheh Omar, Nur Alia
author_facet Anuar, Muhammad Fahmi
Yap, Wing Fen
Azizan, Muhammad Zakwan
Rahmat, Fida’i
Mohd Zaid, Mohd Hafiz
Mohamed Khaidir, Rahayu Emilia
Sheh Omar, Nur Alia
author_sort Anuar, Muhammad Fahmi
building UPM Institutional Repository
collection Online Access
description Arecanut husk (AH) was selected as a material for silica replacement in the synthesis process of glass-ceramics zinc silicate and also the fact that it has no traditional use and often being dumped and results in environmental issues. The process of pyrolysis was carried out at temperature 700 °C and above based on thermogravimetric analysis to produce arecanut husk ash (AHA). The average purity of the silica content in AHA ranged from 29.17% to 45.43%. Furthermore, zinc oxide was introduced to AHA and zinc silicate started to form at sintering temperature 700 °C and showed increased diffraction intensity upon higher sintering temperature of 600 °C to 1000 °C based on X-ray diffraction (XRD) analysis. The grain sizes of the zinc silicate increased from 1011 nm to 3518 nm based on the morphological studies carried out by field emission scanning electron microscopy (FESEM). In addition, the optical band gap of the sample was measured to be in the range from 2.410 eV to 2.697 eV after sintering temperature. From the data, it is believed that a cleaner production of low-cost zinc silicate can be achieved by using arecanut husk and have the potential to be used as phosphors materials.
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institution Universiti Putra Malaysia
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spelling upm-952352023-02-16T07:29:38Z http://psasir.upm.edu.my/id/eprint/95235/ Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials Anuar, Muhammad Fahmi Yap, Wing Fen Azizan, Muhammad Zakwan Rahmat, Fida’i Mohd Zaid, Mohd Hafiz Mohamed Khaidir, Rahayu Emilia Sheh Omar, Nur Alia Arecanut husk (AH) was selected as a material for silica replacement in the synthesis process of glass-ceramics zinc silicate and also the fact that it has no traditional use and often being dumped and results in environmental issues. The process of pyrolysis was carried out at temperature 700 °C and above based on thermogravimetric analysis to produce arecanut husk ash (AHA). The average purity of the silica content in AHA ranged from 29.17% to 45.43%. Furthermore, zinc oxide was introduced to AHA and zinc silicate started to form at sintering temperature 700 °C and showed increased diffraction intensity upon higher sintering temperature of 600 °C to 1000 °C based on X-ray diffraction (XRD) analysis. The grain sizes of the zinc silicate increased from 1011 nm to 3518 nm based on the morphological studies carried out by field emission scanning electron microscopy (FESEM). In addition, the optical band gap of the sample was measured to be in the range from 2.410 eV to 2.697 eV after sintering temperature. From the data, it is believed that a cleaner production of low-cost zinc silicate can be achieved by using arecanut husk and have the potential to be used as phosphors materials. MDPI AG 2021-02-28 Article PeerReviewed Anuar, Muhammad Fahmi and Yap, Wing Fen and Azizan, Muhammad Zakwan and Rahmat, Fida’i and Mohd Zaid, Mohd Hafiz and Mohamed Khaidir, Rahayu Emilia and Sheh Omar, Nur Alia (2021) Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials. Materials, 14 (5). art. no. 1141. pp. 1-12. ISSN 1996-1944 https://www.mdpi.com/1996-1944/14/5/1141 10.3390/ma14051141
spellingShingle Anuar, Muhammad Fahmi
Yap, Wing Fen
Azizan, Muhammad Zakwan
Rahmat, Fida’i
Mohd Zaid, Mohd Hafiz
Mohamed Khaidir, Rahayu Emilia
Sheh Omar, Nur Alia
Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title_full Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title_fullStr Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title_full_unstemmed Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title_short Sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
title_sort sustainable production of arecanut husk ash as potential silica replacement for synthesis of silicate-based glass-ceramics materials
url http://psasir.upm.edu.my/id/eprint/95235/
http://psasir.upm.edu.my/id/eprint/95235/
http://psasir.upm.edu.my/id/eprint/95235/