Lipase catalysed synthesis of adipate wax esters in ionic liquid
Adipate wax ester shows excellent properties such as its low toxicity, good thermal stability, low volatility and high biodegradability, which made it as a very useful compound and significant to various industrial applications including pharmaceutical, food and coating. Green route organic synthesi...
| Main Authors: | , , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
2008
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| Online Access: | http://psasir.upm.edu.my/id/eprint/8877/ http://psasir.upm.edu.my/id/eprint/8877/1/Lipase%20catalysed%20synthesis%20of%20adipate%20wax%20esters%20in%20ionic%20liquid.pdf |
| _version_ | 1848840993831387136 |
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| author | Abdul Rahman, Mohd Basyaruddin Basri, Mahiran Raja Abdul Rahman, Raja Noor Zaliha Salleh, Abu Bakar |
| author_facet | Abdul Rahman, Mohd Basyaruddin Basri, Mahiran Raja Abdul Rahman, Raja Noor Zaliha Salleh, Abu Bakar |
| author_sort | Abdul Rahman, Mohd Basyaruddin |
| building | UPM Institutional Repository |
| collection | Online Access |
| description | Adipate wax ester shows excellent properties such as its low toxicity, good thermal stability, low volatility and high biodegradability, which made it as a very useful compound and significant to various industrial applications including pharmaceutical, food and coating. Green route organic synthesis via enzymatic synthesis, offers clean and mild reaction conditions provides an opportunity to increase productivity, efficiency and quality output. Considering the industrial importance of the ester, the optimal conditions for upscaling process was performed using Response Surface Methodology (RSM). Ionic liquid of [bmim]PF6 was used as a solvent in the esterification of different chain length of alcohol with adipic acid, and Novozyme as a biocatalyst. Higher percentage of yield (>80%) was obtained for longer alcohol chain (dioleyl adipate) but slightly lower yields were found for medium alcohol chain than in hexane. Ionic liquid become the major interest as it can recycled and remained the efficiency once compared to conventional organic solvent. |
| first_indexed | 2025-11-15T07:36:10Z |
| format | Conference or Workshop Item |
| id | upm-8877 |
| institution | Universiti Putra Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-15T07:36:10Z |
| publishDate | 2008 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | upm-88772016-09-27T07:11:25Z http://psasir.upm.edu.my/id/eprint/8877/ Lipase catalysed synthesis of adipate wax esters in ionic liquid Abdul Rahman, Mohd Basyaruddin Basri, Mahiran Raja Abdul Rahman, Raja Noor Zaliha Salleh, Abu Bakar Adipate wax ester shows excellent properties such as its low toxicity, good thermal stability, low volatility and high biodegradability, which made it as a very useful compound and significant to various industrial applications including pharmaceutical, food and coating. Green route organic synthesis via enzymatic synthesis, offers clean and mild reaction conditions provides an opportunity to increase productivity, efficiency and quality output. Considering the industrial importance of the ester, the optimal conditions for upscaling process was performed using Response Surface Methodology (RSM). Ionic liquid of [bmim]PF6 was used as a solvent in the esterification of different chain length of alcohol with adipic acid, and Novozyme as a biocatalyst. Higher percentage of yield (>80%) was obtained for longer alcohol chain (dioleyl adipate) but slightly lower yields were found for medium alcohol chain than in hexane. Ionic liquid become the major interest as it can recycled and remained the efficiency once compared to conventional organic solvent. 2008-08-24 Conference or Workshop Item NonPeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/8877/1/Lipase%20catalysed%20synthesis%20of%20adipate%20wax%20esters%20in%20ionic%20liquid.pdf Abdul Rahman, Mohd Basyaruddin and Basri, Mahiran and Raja Abdul Rahman, Raja Noor Zaliha and Salleh, Abu Bakar (2008) Lipase catalysed synthesis of adipate wax esters in ionic liquid. In: EUCHEM 2008 Conference on Molten Salts and Ionic Liquids, 24-29 Aug. 2008, Copenhagen, Denmark. . |
| spellingShingle | Abdul Rahman, Mohd Basyaruddin Basri, Mahiran Raja Abdul Rahman, Raja Noor Zaliha Salleh, Abu Bakar Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title | Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title_full | Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title_fullStr | Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title_full_unstemmed | Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title_short | Lipase catalysed synthesis of adipate wax esters in ionic liquid |
| title_sort | lipase catalysed synthesis of adipate wax esters in ionic liquid |
| url | http://psasir.upm.edu.my/id/eprint/8877/ http://psasir.upm.edu.my/id/eprint/8877/1/Lipase%20catalysed%20synthesis%20of%20adipate%20wax%20esters%20in%20ionic%20liquid.pdf |