Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor

A cauliflower-like ternary nanocomposite of poly(3,4-ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide (PEDOT/NCC/MnO2) was synthesized using one-step electropolymerization technique. The effect of manganese (Mn) concentration on the supercapacitive performance was investigated. The...

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Main Authors: Ravit, Radha, Azman, Nur Hawa Nabilah, Kulandaivalu, Shalini, Abdullah, Jaafar, Ahmad, Ishak, Sulaiman, Yusran
Format: Article
Language:English
Published: John Wiley and Sons 2020
Online Access:http://psasir.upm.edu.my/id/eprint/88099/
http://psasir.upm.edu.my/id/eprint/88099/1/ABSTRACT.pdf
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author Ravit, Radha
Azman, Nur Hawa Nabilah
Kulandaivalu, Shalini
Abdullah, Jaafar
Ahmad, Ishak
Sulaiman, Yusran
author_facet Ravit, Radha
Azman, Nur Hawa Nabilah
Kulandaivalu, Shalini
Abdullah, Jaafar
Ahmad, Ishak
Sulaiman, Yusran
author_sort Ravit, Radha
building UPM Institutional Repository
collection Online Access
description A cauliflower-like ternary nanocomposite of poly(3,4-ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide (PEDOT/NCC/MnO2) was synthesized using one-step electropolymerization technique. The effect of manganese (Mn) concentration on the supercapacitive performance was investigated. The structural and morphology studies were conducted using field emission scanning electron microscope, Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray diffraction. The morphology of ternary nanocomposite at an optimized concentration of Mn resembles the cauliflower-like structure. The two-electrode electrochemical analysis of a ternary nanocomposite PEDOT/NCC/MnO2 exhibited a higher specific capacitance of 144.69 F/g at 25 mV/s in 1.0 M potassium chloride compared to PEDOT/NCC(63.57 F/g). PEDOT/NCC/MnO2 ternary nanocomposite was able to deliver a specific power of 494.9 W/kg and 10.3 Wh/kg of specific energy at 1 A g−1 and retained 83% of initial capacitance after 2,000 cycles. These promising results from the incorporation of Mn displayed great prospective in developing PEDOT/NCC/MnO2 as an electrode material for supercapacitor.
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spelling upm-880992022-05-18T06:59:02Z http://psasir.upm.edu.my/id/eprint/88099/ Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor Ravit, Radha Azman, Nur Hawa Nabilah Kulandaivalu, Shalini Abdullah, Jaafar Ahmad, Ishak Sulaiman, Yusran A cauliflower-like ternary nanocomposite of poly(3,4-ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide (PEDOT/NCC/MnO2) was synthesized using one-step electropolymerization technique. The effect of manganese (Mn) concentration on the supercapacitive performance was investigated. The structural and morphology studies were conducted using field emission scanning electron microscope, Fourier transform infrared spectroscopy, Raman spectroscopy, and X-ray diffraction. The morphology of ternary nanocomposite at an optimized concentration of Mn resembles the cauliflower-like structure. The two-electrode electrochemical analysis of a ternary nanocomposite PEDOT/NCC/MnO2 exhibited a higher specific capacitance of 144.69 F/g at 25 mV/s in 1.0 M potassium chloride compared to PEDOT/NCC(63.57 F/g). PEDOT/NCC/MnO2 ternary nanocomposite was able to deliver a specific power of 494.9 W/kg and 10.3 Wh/kg of specific energy at 1 A g−1 and retained 83% of initial capacitance after 2,000 cycles. These promising results from the incorporation of Mn displayed great prospective in developing PEDOT/NCC/MnO2 as an electrode material for supercapacitor. John Wiley and Sons 2020 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/88099/1/ABSTRACT.pdf Ravit, Radha and Azman, Nur Hawa Nabilah and Kulandaivalu, Shalini and Abdullah, Jaafar and Ahmad, Ishak and Sulaiman, Yusran (2020) Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor. Journal of Applied Polymer Science, 137 (39). art. no. 49162. pp. 1-11. ISSN 1097-462 https://onlinelibrary.wiley.com/doi/full/10.1002/app.49162 10.1002/app.49162
spellingShingle Ravit, Radha
Azman, Nur Hawa Nabilah
Kulandaivalu, Shalini
Abdullah, Jaafar
Ahmad, Ishak
Sulaiman, Yusran
Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title_full Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title_fullStr Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title_full_unstemmed Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title_short Cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
title_sort cauliflower-like poly(3,4 ethylenedioxythipohene)/nanocrystalline cellulose/manganese oxide ternary nanocomposite for supercapacitor
url http://psasir.upm.edu.my/id/eprint/88099/
http://psasir.upm.edu.my/id/eprint/88099/
http://psasir.upm.edu.my/id/eprint/88099/
http://psasir.upm.edu.my/id/eprint/88099/1/ABSTRACT.pdf